A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.     

Characterization of seafloor pockmark seepage of hydrocarbons employing fractal: A case study from the western continental margin of India

Here we apply quantitative technique to describe the seafloor seepages based on the multi-beam backscatter and bathymetric investigations to characterize the pockmark morphology. The variable seafloor backscatter strength for coarser seafloor sediments are related to the diagenesis derived from biodegraded seepages. In this regard, box counting method is used to estimate ‘fractal dimension’ for backscatter imagery data of 398 blocks. These blocks are further sub-grouped into six classes depending on the spread of pockmark related seepages. The study area lies 102 km west off Marmagao along the central west coast of India which contains pre-dominantly (70%) gas-charged sediments. Comparison between the estimated self-similar fractals reveals that there is approximately 97% correlation between the box (D_box) and information (D_info) dimensions. Box dimension–derived fractal dimension values, suggest that the seepages are more along the fault trace in deeper waters, in comparison to sparsely distributed shallow water seepages. Besides, this poor seepage is confined within the smooth to moderately rough seafloor. It is established that the high backscatter strength along the upper slope of the pockmark region having higher fractal dimensions reflects multifractal behavior of seepage distribution. Entire area indicates patchy seepage patterns as supported by estimated fractal values showing intermittent fluctuations, which emphasizes non-linear behavior. Estimated self organizing criticality (SOC) parameters for six representative blocks reveal that the nature of pockmark, fault trace, sediment nature coupled with slumping of pockmark’s wall, sediment movement due to bottom currents are controlling the dynamic balance in the area seepage system. Further, our study emphasizing the multifractal behavior of seepage blocks, clearly depicts the drift in the seepage pattern.     

Structural controls on the formation of BSR over a diapiric anticline from a dense MCS survey offshore southwestern Taiwan

A dense seismic reflection survey with up to 250-m line-spacing has been conducted in a 15 × 15 km wide area offshore southwestern Taiwan where Bottom Simulating Reflector is highly concentrated and geochemical signals for the presence of gas hydrate are strong. A complex interplay between north–south trending thrust faults and northwest–southeast oblique ramps exists in this region, leading to the formation of 3 plunging anticlines arranged in a relay pattern. Landward in the slope basin, a north–south trending diapiric fold, accompanied by bright reflections and numerous diffractions on the seismic profiles, extends across the entire survey area. This fold is bounded to the west by a minor east-verging back-thrust and assumes a symmetric shape, except at the northern and southern edges of this area, where it actively overrides the anticlines along a west-verging thrust, forming a duplex structure. A clear BSR is observed along 67% of the acquired profiles. The BSR is almost continuous in the slope basin but poorly imaged near the crest of the anticlines. Local geothermal gradient values estimated from BSR sub-bottom depths are low along the western limb and crest of the anticlines ranging from 40 to 50 °C/km, increase toward 50–60 °C/km in the slope basin and 55–65 °C/km along the diapiric fold, and reach maximum values of 70 °C/km at the southern tip of the Good Weather Ridge. Furthermore, the local dips of BSR and sedimentary strata that crosscut the BSR at intersections of any 2 seismic profiles have been computed. The stratigraphic dips indicated a dominant east–west shortening in the study area, but strata near the crest of the plunging anticlines generally strike to southwest almost perpendicular to the direction of plate convergence. The intensity of the estimated bedding-guided fluid and gas flux into the hydrate stability zone is weaker than 2 in the slope basin and the south-central half of the diapiric fold, increases to 7 in the northern half of the diapiric fold and plunging anticlines, and reaches a maximum of 16 at the western frontal thrust system. Rapid sedimentation, active tectonics and fluid migration paths with significant dissolved gas content impact on the mechanism for BSR formation and gas hydrate accumulation. As we begin to integrate the results from these studies, we are able to outline the regional variations, and discuss the importance of structural controls in the mechanisms leading to the gas hydrate emplacements.     

Large-scale laboratory experiment on erosion of sand beds by moving circular vertical jets

This study investigates the topographic deformation due to the erosion of a sand bed impinged by a moving submerged turbulent round jet in a large-scale laboratory. The test conditions represent the case of discharges beneath a vessel while operating in water with a limited clearance such as a shallow navigation channel. The jet moves horizontally and discharges water vertically downward towards the bed. The distance between the jet nozzle and the bed equals six times the jet diameter so the jet flow is in the potential core region. The speed of the jet horizontal motion was varied to examine its effect on the scour profile. The characteristic lengths of the scour profile in the asymptotic state were determined by modifying the empirical formulas in Aderibigbe and Rajaratnam [1996. Erosion of loose beds by submerged circular impinging vertical turbulent jets. Journal of Hydraulic Research 34(1), 19–33]. The maximum scour depth, the scour hole radius, and the ridge height were found to be a function of the ratio of the jet exit to jet translation velocities and were modeled using a hyperbolic function. Empirical equations describing the scour profile were developed and the scour profile was found to be self-similar when normalized by appropriate length scales.     

Particle–water interactions of 2,2′,5,5′-tetrachlorobiphenyl under simulated estuarine conditions

A batch sorption technique for the determination of particle–water interactions of hydrophobic organic micropollutants under simulated estuarine conditions is described. Results are presented for the behaviour of 2,2′,5,5′-tetrachlorobiphenyl (2,2′,5,5′-TCB) in river and sea waters, both in the presence and absence of estuarine suspended particles. Adsorption onto particles in sea water was enhanced compared with adsorption in river water owing to salting out of the compound, and possibly of the particulate organic matter, in the presence of high concentrations of dissolved ions. The particle–water distribution coefficient, K_D, decreased from about 120×10³ to 10×10³ ml g⁻¹, and from about 150×10³ to 20×10³ ml g⁻¹, in river water and sea water, respectively, over a particle concentration range of 10–1000 mg l⁻¹. Incomplete recovery of compound from the reactor walls is partly responsible for a particle concentration effect, while artefacts relating to inadequate sediment and water phase separation were ruled out following further experiments. The particle concentration effect, which is replicated in many field studies of hydrophobic organic micropollutants, including 2,2′,5,5′-TCB, is incorporated into a simple partitioning model and is discussed in the context of the likely estuarine behaviour of such compounds.     

The next few years of the ICES Journal of Marine Science

This issue marks a change in the editorial team of the ICESJournal of Marine Science, in that we have bid farewell to ourformer Editor-in-Chief, Niels Daan, after six years of sterlingservice, and to our Elsevier Publishing Editor, Andrew Richford,after an even longer period of years. Both deserve credit fortheir energy and vision that has left us the legacy of a journalas widely read and cited as the ICES Journal now is, but theyleave a gap that will be a huge challenge for us to meet. However,in my new capacity as Editor-in-Chief and in Els Bosma's capacityas Elsevier's Publishing Editor, I     

The contribution of atmospheric acid deposition to ocean acidification in the subtropical North Atlantic Ocean

The absorption of anthropogenic CO₂ and atmospheric deposition of acidity can both contribute to the acidification of the global ocean. Rainfall pH measurements and chemical compositions monitored on the island of Bermuda since 1980, and a long-term seawater CO₂ time-series (1983–2005) in the subtropical North Atlantic Ocean near Bermuda were used to evaluate the influence of acidic deposition on the acidification of oligotrophic waters of the North Atlantic Ocean and coastal waters of the coral reef ecosystem of Bermuda. Since the early 1980's, the average annual wet deposition of acidity at Bermuda was 15 ± 14 mmol m^− 2 year^− 1, while surface seawater pH decreased by 0.0017 ± 0.0001 pH units each year. The gradual acidification of subtropical gyre waters was primarily due to uptake of anthropogenic CO₂. We estimate that direct atmospheric acid deposition contributed 2% to the acidification of surface waters in the subtropical North Atlantic Ocean, although this value likely represents an upper limit. Acidifying deposition had negligible influence on seawater CO₂ chemistry of the Bermuda coral reef, with no evident impact on hard coral calcification.     

Response of a climate model to tidal mixing parameterization under present day and last glacial maximum conditions

Experiments with a climate model were conducted under present day and last glacial maximum conditions in order to examine the model’s response to a vertical mixing scheme based on internal tide energy dissipation. The increase in internal tide energy flux caused by a 120 m reduction in sea level had the expected effect on diffusivity values, which were higher under lower sea level conditions. The impact of this vertical diffusivity change on the Atlantic meridional overturning is not straightforward and no clear relationship between diffusivity and overturning is found. There exists a weak positive correlation between overturning and changes to the power consumed by vertical mixing. Most of the climatic response generated by sea level change was not related to alterations in the internal tide energy flux but rather to the direct change in sea level itself.