Role of superoxide in the photochemical reduction of iron in seawater

We have conducted a series of laboratory studies to investigate the generation of ferrous iron and reactive oxygen species when solutions of seawater containing natural organic matter (NOM) and ferric iron are exposed to simulated sunlight. Total ferrous iron and hydrogen peroxide were measured at nanomolar concentrations with high temporal resolution using chemiluminescence-based methods. In all cases, ferrous iron concentrations rapidly peaked at several nanomoles per litre after a few minutes, and then declined over time, while hydrogen peroxide concentrations increased in a non-linear manner. Although concentrations of both species depended on the concentration of NOM, hydrogen peroxide concentrations were only minimally affected by the presence of iron. Increasing the NOM concentration while the total iron concentration was maintained constant led to an increase in the maximum ferrous iron concentration, suggesting that superoxide-mediated reduction of iron may be a major pathway for ferrous iron formation. This was supported by measurements of superoxide production from irradiation of NOM in the absence of iron and kinetic calculations, as well as an experiment in which superoxide dismutase was added. Further analysis of the data suggested that dissolved oxygen and photo-produced hydrogen peroxide were the primary oxidants of the Fe(II) formed. Thus we propose that superoxide and ferrous iron may be intricately coupled in the system, and that their generation is determined by the supply of NOM available to harvest light and donate electrons.     

Collisional evolution of the asteroid belt

A new synthesis of asteroid collisional evolution is motivated by the question of whether most asteroids larger than ∼1 km size are strengthless gravitational aggregates (rubble piles). NEAR found Eros not to be a rubble pile, but a shattered collisional fragment, with a through-going fracture system, and an average of about 20 m regolith cover. Of four asteroids visited by spacecraft, none appears likely to be a rubble pile, except perhaps Mathilde. Nevertheless, current understanding of asteroid collisions and size-dependent strength, and the observed distribution of rotation rates versus size, have led to a theoretical consensus that many or most asteroids larger than 1 km should be rubble piles. Is Eros, the best-observed asteroid, highly unusual because it is not a rubble pile? Is Mathilde, if it is a rubble pile, like most asteroids? What would be expected for the small asteroid Itokawa, the MUSES-C sample return target? An asteroid size distribution is synthesized from the Minor Planet Center listing and results of the Sloan Digital Sky Survey, an Infrared Space Observatory survey, the Small Main-belt Asteroid Spectroscopic Survey and the Infrared Astronomical Satellite survey. A new picture emerges of asteroid collisional evolution, in which the well-known Dohnanyi result, that the size distribution tends toward a self-similar form with a 2.5-index power law, is overturned because of scale-dependent collision physics. Survival of a basaltic crust on Vesta can be accommodated, together with formation of many exposed metal cores. The lifetimes against destruction are estimated as 3 Gyr at the size of Eros, 10 Gyr at ten times that size, and 40 Gyr at the size of Vesta. Eros as a shattered collisional fragment is not highly unusual. The new picture reveals the new possibility of a transition size in the collisional state, where asteroids below 5 km size would be primarily collisional breakup fragments whereas much larger asteroids are mostly eroded or shattered survivors of collisions. In this case, well-defined families would be found in asteroids larger than about 5 km size, but for smaller asteroids, families may no longer be readily separated from a background population. Moreover, the measured boulder size distribution on Eros is re-interpreted as a sample of impactor size distributions in the asteroid belt. The regolith on Eros may result largely from the last giant impact, and the same may be true of Itokawa, in which case about a meter of regolith would be expected there. Even a small asteroid like Itokawa may be a shattered object with regolith cover.     

An avalanche photodiode photon counting camera for high-resolution astronomy

A system is described which makes best use of the high quantum efficiency and high count rate capability of avalanche photodiodes for high time resolution observations of optical pulsars. The use of three APDs allows simultaneous photometry of the target and a reference star, and the monitoring of the sky background. By minimising the optical components in the light path the optical efficiency of the system is maximised. The TRIFFID (Shearer, A., Stappers, B., O'Connor, P., Golden, A., Strom, R., Redfern, M., Ryan, O.: Science 301, 493–495 (2003)) and OPTIMA (Straubmeier, C., Kanbach, G., Schrey, F.: Exp. Astron. 11, 157–170 (2001)) have shown that fibre-fed APD arrays can produce excellent results. This, new, system was used on the 6m BTA in November 2003 – results on the Crab pulsar are presented.     

Studies of the solar chromosphere from millimetre and sub-millimetre observations

A compilation of brightness temperature data in the millimetre and sub-millimetre wavelength ranges is used to obtain an empirical relation T _B = C ⁿ between brightness temperature and wavelength, valid between 1 mm and 1 cm. An analytically soluble model, giving electron temperatures and densities between 1500 km and 4000 km above the photosphere is derived from this relationship, and eclipse data of Thomas and Athay, of the emission at the head of the Balmer continuum. Although this over-simplified model lacks precision in the height co-ordinate, it allows a scale height of around 1000 km for electrons to be deduced, and supplies a convincing test for the absence of hydrostatic equilibrium throughout the region. A more comprehensive and reliable though still simplified numerical model is then presented, being a modification of previous models accounting only for millimetre data. It shows marked departure from UV derived models in this region, and an explanation for the discrepancy is proposed in terms of thermal inhomogeneities on the scale of the chromospheric supergranulation. The stratified model is then geometrically modified to account for observed centrelimb profiles of the Sun measured throughout the sub-millimetre and millimetre region. The scale of any roughness thus introduced is related to the notable lack of millimetric limb brightening, and observational tests for that scale are suggested here. A qualitative picture of this part of the chromosphere is proposed, consistent with existing observations in the millimetre, visible and UV regions of the spectrum.     

Lateral inhomogeneities in the Venus atmosphere: Analysis of thermal infrared maps

The thermal infrared maps of Venus published by Murray, Wildey, and Westphal (1963) and Westphal, Wildey, and Murray (1965) have been analyzed systematically in order to separate the observed intensity into a limb-darkening component and a solar-associated component representing fixed patterns of intensity corotating with the earth and sun, respectively. Interesting new results are obtained for the solar-associated component. Regions near the subsolar point and the poles are not covered in the original maps or in the analysis.The solar-associated pattern of intensity is very nearly symmetric about the equator. In both northern and southern hemispheres, an intensity minimum seems to occur near the morning terminator at middle to high latitudes, slightly beyond the limit of the maps. An intensity maximum occurs on the equator slightly to the east of the antisolar point. Three broad ridges of relatively high intensity radiate away from this point, one pointing to the west along the equator, the others pointing to the northeast and southeast, respectively. The eastward tilt of the latter two ridges may indicate that horizontal exchange is important in maintaining the equatorial maximum of zonal momentum which is associated with the 4-day circulation of the Venus atmosphere.