Analyses of the chondritic meteorite Orvinio (H6): Insight into the origins and evolution of shocked H chondrite material

Abstract— We have studied the petrography, reflectance spectra, and Ar‐Ar systematics of the Orivinio meteorite. Orvinio is an H chondrite not an L chondrite as sometimes reported. The material in the meteorite was involved in several impact events. One impact event produced large swaths of impact melt from H chondrite material surrounding relict clasts of chondrule‐bearing material. Not only were portions of a bulk H chondrite planestesimal melted during the impact event, but shock redistribution of metal and sulfide phases in the meteorite dramatically altered its reflectance spectra. Both the melt and relict clasts are darker than unshocked H chondrite material, bearing spectral similarities to some C‐class asteroids. Such shock metamorphism, which lowers the albedo of an object without increasing its spectral slope, may partially explain some of the variation among S‐class asteroids and some of the trends seen on asteroid 433 Eros. Noble gases record the evidence of at least two, and perhaps three, impact events in the meteorite and its predecessor rocks. The most significant evidence is for an event that occurred 600 Ma ago or less, perhaps ?325 Ma ago or less. There is also a signature of 4.2 Ga in the Ar‐Ar systematics, which could either reflect complete degassing of the rock at that time or partial degassing of even the most retentive sites in the more recent event.     

Measurement requirements for a Near-Earth Asteroid impact mitigation demonstration mission

A concept for an Impact Mitigation Preparation Mission, called Don Quijote, is to send two spacecrafts to a Near-Earth Asteroid (NEA): an Orbiter and an Impactor. The Impactor collides with the asteroid while the Orbiter measures the resulting change in the asteroid's orbit, by means of a Radio Science Experiment (RSE) carried out before and after the impact. Three parallel Phase A studies on Don Quijote were carried out for the European Space Agency: the research presented here reflects the outcomes of the study by QinetiQ. We discuss the mission objectives with regard to the prioritisation of payload instruments, with emphasis on the interpretation of the impact. The Radio Science Experiment is described and it is examined how solar radiation pressure may increase the uncertainty in measuring the orbit of the target asteroid. It is determined that to measure the change in orbit accurately a thermal IR spectrometer is mandatory, to measure the Yarkovsky effect. The advantages of having a laser altimeter are discussed. The advantages of a dedicated wide-angle impact camera are discussed and the field-of-view is initially sized through a simple model of the impact.     

Carbon-14 production compared to oxygen isotope records from Camp Century,Greenland and Devon Island,Canada

Carbon-14 production rate variations that are not explainable by geomagnetic changes are thought to be in antiphase with solar activity and as such should be in antiphase with paleotemperature records or proxy temperature histories such as those obtainable from oxygen isotope analyses of ice cores. Oxygen isotope records from Camp Century, Greenland and Devon Island Ice Cap are in phase with each other over thousands of years and in antiphase to the ¹⁴C production rate residuals.     

Crystallisation of sodium sulfate: supersaturation and metastable phases

Crystallisation of sodium sulfate solutions by evaporation under controlled climatic conditions has revealed the existence of crystalline hydrated sodium sulfate salts not previously reported. The sodium sulfate phase crystallising and the concentration of the solution at the point of crystallisation depends on the climatic conditions (temperature and evaporation rate). During the rehydration of the anhydrous sodium sulfate phase, thenardite, another previously unreported phase was formed prior to the nucleation of the stable phase, mirabilite Na₂SO₄ · 10H₂O. The addition of organic inhibitors changes both the crystallisation and the rehydration behavior in this system.     

Hydrogeology of northern Sierra de Chiapas,Mexico: a conceptual model based on a geochemical characterization of sulfide-rich karst brackish springs

Conspicuous sulfide-rich karst springs flow from Cretaceous carbonates in northern Sierra de Chiapas, Mexico. This is a geologically complex, tropical karst area. The physical, geologic, hydrologic and chemical attributes of these springs were determined and integrated into a conceptual hydrogeologic model. A meteoric source and a recharge elevation below 1,500 m are estimated from the spring-water isotopic signature regardless of their chemical composition. Brackish spring water flows at a maximum depth of 2,000 m, as inferred from similar chemical attributes to the produced water from a nearby oil well. Oil reservoirs may be found at depths below 2,000 m. Three subsurface environments or aquifers are identified based on the B, Li⁺, K⁺ and SiO₂ concentrations, spring water temperatures, and CO₂ pressures. There is mixing between these aquifers. The aquifer designated Local is shallow and contains potable water vulnerable to pollution. The aquifer named Northern receives some brackish produced water. The composition of the Southern aquifer is influenced by halite dissolution enhanced at fault detachment surfaces. Epigenic speleogenesis is associated with the Local springs. In contrast, hypogenic speleogenesis is associated with the brackish sulfidic springs from the Northern and the Southern environments.     

Theoretical issues in the ‘food desert’ debate and ways forward

Food is essential to life—yet the spatial and economic configuration of the conventional food system does not meet nutritional needs and exacerbates issues of food insecurity. Relevant options for policy change have been explored in light of evaluations of geographic disparities in food access, but the dominant ‘food desert’ discourse often focuses uncritically on insufficient conceptions of access. Understanding the complexity of food deserts is important for moving into meaningful policy action. We present a theoretical position to inspire future empirical research. The ecological model recognizes both endogenous and built environment factors in shaping health. Interventions in the food environment, however, often concentrate exclusively on structural determinants of health (e.g. retail-based initiatives). Yet retail-based interventions are difficult to implement due to governance systems which limit the ability of government bodies to influence private retail development. As well, recognizing the complexity of debates over the influence of structure and agency, we apply structuration theory to food deserts. Behavioral economics further informs both structural and behavioral determinants of health. This approach sidesteps the issue of victim-blaming, as all consumers are viewed as ‘predictably irrational’ in decision-making. In combining these theories, we challenge methodological and theoretical assumptions by showing the complexity of food desert interventions. Policy recommendations focus on behavioral determinants of health and the opportunities for empowerment through local food systems. These recommendations recognize the limits of translating research into policy and in devising effective food based interventions, and are sensitive to social, economic, and political constraints uncovered throughout the paper.     

Remote sensing of rivers: the emergence of a subdiscipline in the river sciences

This article reports on the special issue of Earth Surface Processes and Landforms dedicated to remote sensing of rivers. This emerging subdiscipline of river science has grown at a rapid rate in recent years because of: (a) the growing desire and need for data to document and explore the full range of spatial and temporal variations in river systems; (b) evolving technologies that enable lower cost data acquisition, processing and analysis at reach to catchment to continental scales; and (c) the increasing engagement of river scientists with GIScience. The convergence of these factors and the ever growing number of practitioners speaks to the need for more communication among researchers, a major reason for creating this special issue. The 12 articles in the volume cover a broad spectrum of applications that use a variety of platforms and sensors, ranging from photogrammetric mapping of riffle‐pool morphology beneath forest canopy using a camera mounted on a hand held pole to satellite‐based synthetic radar mapping of subcontinental scale hydrology of large rivers. In this overview each of the 12 articles is briefly summarized. Based on these works and other research, it is concluded that the time for more widespread application of river remote sensing techniques is now. To promote more widespread use of remote sensing techniques for river science and management, the following are advocated: (a) developing stand alone or plug‐in software products that enable non‐expert users to implement these new methods, (b) incorporating remote sensing of rivers training into classes, workshops, and on‐line tutorials; and (c) promoting more intentional and formal collaboration among members of the river remote sensing community. Copyright © 2010 John Wiley & Sons, Ltd.     

Comparative Evaluation of Single‐Well LNAPL Tracer Testing at Five Sites

Light nonaqueous phase liquid (LNAPL) tracer testing is a technique used to directly measure LNAPL flow in situ and evaluate LNAPL mobility and recoverability. The test method consists of adding a fluorescent oil‐soluble tracer to LNAPL within a well, isolating small volumes of LNAPL with known tracer concentrations for use as in‐well calibration standards, and measuring the rate of tracer concentration decline in the well over time. The test measures LNAPL flux through the well, which is directly related to LNAPL mobility and recoverability in the surrounding formation. Test results for a total of 29 wells at five sites are presented. Results from LNAPL tracer testing were comparable to results obtained through other methods, and the method offers a time‐averaged result measured over a relatively long period, in ambient conditions, and reflects the influences of heterogeneity and hydraulic changes. In some cases, tracer concentration decline followed unexpected patterns, and these data have led to a better understanding of test assumptions, mechanisms influencing tracer distribution, and options to improve test execution and data interpretation. Method improvements developed over the course of the field studies included refinement of pre‐test screening of LNAPL fluorescence and improvements to measurement equipment. Overall, the field studies confirmed the technical validity and usefulness of the LNAPL tracing technique to support LNAPL mobility and recoverability assessments.     

Contesting Domestic Ideals: queering the Australian home

The Australian home is a crucial site for both normalising and contesting acceptable modes of sexual identity, desire and behaviour. Social norms and government policies have imbricated the detached suburban dwelling with the heterosexual nuclear family form, consequently heterosexualising the ideal Australian home. But this discourse is simultaneously challenged by the domestic practices of gay men and lesbians, who use their homes to consolidate gay/lesbian identities, relationships and communities. As such, they unsettle the normative heterosexuality underpinning dominant, ideal conceptions of home. In this paper I present four vignettes which illustrate how some gay men and lesbians queer the ideal Australian home, generating domestic spaces which affirm sexual difference. In doing so, I highlight two key ways in which this process of ‘queering home’ works. First, through certain uses of home—activities taking place within domestic space. Second, through changes to the materiality of domestic space itself wrought by some homemaking practices, effectively embedding gay/lesbian identities and relationships within the physical environment of the home.