Formation of iron sulfide nodules during anaerobic oxidation of methane

The biomarker compositions of iron sulfide nodules (ISNs; upper Pliocene Valle Ricca section near Rome, Italy) that contain the ferrimagnetic mineral greigite (Fe₃S₄) were examined. In addition to the presence of specific terrestrial and marine biomarkers, consistent with formation in coastal marine sediments, these ISNs contain compounds thought to originate from sulfate reducing bacteria (SRB). These compounds include a variety of low-molecular-weight and branched alkanols and several non-isoprenoidal dialkyl glycerol diethers (DGDs). In addition, archaeal biomarkers, including archaeol, macrocyclic isoprenoidal DGDs and isoprenoidal glycerol dialkyl glycerol tetraethers are also present. Both SRB and archaeal lipid δ¹³C values are depleted in ¹³C (δ¹³C values are typically less than −50‰), which suggests that the SRB and archaea consumed ¹³C depleted methane. These biomarker and isotopic signatures are similar to those found in cold seeps and marine sediments where anaerobic oxidation of methane (AOM) occurs with sulfate serving as the terminal electron acceptor. Association of AOM with formation of greigite-containing ISNs could provide an explanation for documented remagnetization of the Valle Ricca sediments. Upward migration of methane, subsequent AOM and associated authigenic greigite formation are widespread processes in the geological record that have considerable potential to compromise paleomagnetic records.     

Grounding the virtual: The material effects of electronic grocery shopping

This paper addresses the materiality of computer-mediated retailing. The paper uncovers the “hidden geography” of e-commerce, considering how the seemingly simple act of doorstep food delivery is explicated in urban form, and in transportation and communication infrastructures. The paper categorises electronic grocery shopping (EGS) enterprises into three types: “bricks and clicks”, “pure-play” and the “infomediary”, and examines how each type of operation has been materialised in the urban landscape, and the infrastructure upon which each draws. The paper then considers the strategies EGS operations have used to offset the “killer costs” of logistics for electronic commerce. The paper concludes by considering how electronic grocery shopping is embedded within broader trends in consumer behaviour, and how these trends are manifested in the materiality of urban life. The paper argues that online grocers are in the vanguard of ventures habituating customers to the remote ordering and delayed delivery of products to the home. Through controlling this “last mile”, online retailers hope to extend the product offer to higher-margin and more problematic products, which are in themselves unprofitable to distribute direct to the customer, but which can be profitably combined with a grocery shop.     

Raman microspectroscopy: A non-destructive tool for routine calibration of apatite crystallographic structure for fission-track analyses

Compositional control on the annealing kinetics of fission-tracks (FT) in apatite requires routine measurement of sample grain composition. However, for practical reasons the bulk composition of analysed grains is not routinely measured and instead grain chlorine content or etch-pit dimensions are used to characterise a samples annealing behaviour. A more desirable approach is to measure crystallographic parameters (i.e. unit cell dimension) of a grain as these represent the summed effect of all substitutions and crystal defects. We show how Raman microspectrometry can be used as a routine non-destructive tool to obtain rapid measurement of the crystallographic structure of apatite grains etched for FT analysis. Variations of unit cell parameter a are found to correspond to a systematic variation of Raman shift in the range of 452–440 cm^− 1 for measurements made on c-parallel sections of apatite where the direction of the polarized incident beam is parallel to the c axis.     

作为赋存于花岗岩中钨锡矿化勘探指南的流体包裹体异常——前景展望

Studies of the distribution and abundance of fluid inclusions in granitic quartz associated with granite-hosted Sn-W mineralization of the British Isles reveal local and regional scale anomalies.At a sampling interval of c.5～50m,inclusion abundances increase towards zones of vein and stockwork mineralization exemplified by case history examples from exploration prospects in the Mourne Mountains of Northern Ireland and the Carrock Fell mining district of northwestern England.These steam aureoles provide a greater exploration target than the zone of visible alteration and mineralization and the lithogeochemical halo.But it is important to link them to geochemical data on fluid inclusion compositions,such as the semi-quantitative data from decrepitation-linked,ICP-AES (D-ICP)analysis,to optimize their exploration potential.Regional scale fluid inclusion anomalies,based on sampling intervals of c. 2km from the Sn-W mineralized granites of southwest England also broadly correlate with zones of intense mineralization in some areas. Regional-scale D-ICP analyses of quartz from SW England granites did not provide any convincing regional scale anomalies linked to mineralization except for positive boron anomalies around the centrally-mineralized Birch Tor area of the Dartmoor granite.Follow-up D-ICP analysis of quartz from stream sediments from this area,however,could be used to discriminate between samples related to mineralization from those draining unmineralized areas,using multivariate statistical analysis.At the present stage of development, the main contribution of fluid inclusion studies to mineral exploration is mostly limited to the conceptual stage where they continue to contribute to ore genetic theory and models.Costs and lack of knowledge transfer between research scientists and mineral explorationists limit their direct use during regional and target selection stages of exploration.Analysis of steam sediment quartz,using the more sensitive ICP-MS technique as a variant of the D-ICP method,appears to offer the greatest potential for future development as an exploration tool.     

Geographic and temporal trends in proboscidean and human radiocarbon histories during the late Pleistocene

The causes of large animal extinctions at the end of the Pleistocene remain a hotly debated topic focused primarily on the effects of human over hunting and climate change. Here we examine multiple, large radiocarbon data sets for humans and extinct proboscideans and explore how variation in their temporal and geographic distributions were related prior to proboscidean extinction. These data include 4532 archaeological determinations from Europe and Siberia and 1177 mammoth and mastodont determinations from Europe, Siberia, and North America. All span the period from 45,000 to 12,000 calendar years BP. We show that while the geographic ranges of dated human occupations and proboscidean remains overlap across the terminal Pleistocene of the Old World, the two groups remain largely segregated and increases in the frequency of human occupations do not coincide with declines in proboscidean remains. Prior to the Last Glacial Maximum (LGM; ca 21,000 years BP), archaeological ¹⁴C determinations increase slightly in frequency worldwide while the frequency of dated proboscidean remains varies depending on taxon and location. After the LGM, both sympatric and allopatric groups of humans and proboscideans increase sharply as climatic conditions ameliorate. Post-LGM radiocarbon frequencies among proboscideans peak at different times, also depending upon taxon and location. Woolly mammoths in Beringia reach a maximum and then decline beginning between 16,000 and 15,500 years BP, woolly mammoths in Europe and Siberia ca 14,500 and 13,500 BP, and Columbian mammoth and American mastodont only after 13,000 BP. Declines among woolly mammoths appear to coincide with the restructuring of biotic communities following the Pleistocene–Holocene transition.     

The ortho- to para- ratio of H2 in the starburst of NGC 253

We present measurements of several near-infrared emission lines from the nearby galaxy NGC 253. We have been able to measure four H₂ lines across the circumnuclear starburst, from which we estimate the ortho- to para- ratio of excited H₂ to be ∼2. This indicates that the bulk of the H₂ emission arises from photodissociation regions (PDRs), rather than from shocks. This is the case across the entire region of active star formation.
As the H₂ emission arises from PDRs, it is likely that the ratio of H₂ to Brγ (the bright hydrogen recombination line) is a measure of the relative geometry of O and B stars and PDRs. Towards the nucleus of NGC 253 the geometry is deduced to be tightly clustered O and B stars in a few giant H  II regions that are encompassed by PDRs. Away from the nuclear region, the geometry becomes that of PDRs bathed in a relatively diffuse ultraviolet radiation field.
The rotation curves of 1–0 S(1) and Brγ suggest that the ionized gas is tracing a kinetic system different from that of the molecular gas in NGC 253, particularly away from the nucleus.     

Aliphatic and aromatic hydrocarbons in benthic invertebrates from two sites in Antarctica

Samples of marine benthic invertebrates collected from two sites in the Antarctic have been analysed for both aliphatic and aromatic hydrocarbons in order to establish baseline concentrations for some classes of hydrocarbons.Samples from Signy Island, a pristine site, contained low concentrations of the hydrocarbons determined, whereas those from King Edward Cove, South Georgia, contained significantly higher concentrations. King Edward Cove has a known history of pollution from whaling operations.Platt & Mackie (1979) have suggested that the hydrocarbons in sediments from King Edward Cove are a result of the world-wide dissemination of the pyrolysis products of fossil fuels. Our work suggests, in contrast, that the hydrocarbons in the benthos are derived from local sources.     

Leachable trace elements in San Francisco bay sediments: Indicators of sources and estuarine processes

Geographic variations of leachable Fe, Mn, Cu, Zn, Co, and Ni in San Francisco Bay sediments indicate that Fe, Mn, Co, and Ni are all predominantly supplied to bay sediments from the San Joaquin-Sacramento River system, with little evidence for direct contributions from municipal and industrial sources. In contrast, both Cu and Zn have significant sources within the Bay system, probably municipal and industrial discharges. Precipitation and coagulation of Fe oxides in the low-salinity region of the estuary results in significantly greater concentrations of that element in the most landward portion of the estuary. Co and Ni appear to be actively coprecipitating with Fe but their distributions are also influenced by other factors. Mn is not a major geochemical agent in this system. Its pattern is different from the other elements and it does not account for any of the other elemental variance. The behavior of Cu and Zn is affected not only by the presence of nonriverine sources but also through surface-active processes and organic complexing, coupled with the transportation of fine-grained sediment.     

Atmospheric response to deep-sea injections of fossil-fuel carbon dioxide

The possibility of controlling atmospheric carbon dioxide accumulation and attendant climatic effects from fossil-fuel burning by diverting a fraction of the combustion product and injecting it into the deep-ocean, as proposed by Marchetti, is analyzed using an atmosphere/mixed layer/diffusive deep-ocean model for the carbon cycle. The model includes the nonlinear buffering of CO₂ at the air/sea interface, and considers the long term trends associated with consuming an assumed fossil-fuel reserve equivalent to 7.09 × 10¹⁵ kg carbon as a logistic function of time as in the projections of Siegenthaler and Oeschger, except that atmospheric carbon dioxide levels are computed for five alternate strategies: (a) 100% injected into atmosphere, (b) 50% injected at oceanic depth of 1500 m and 50% into atmosphere, (c) 50% injected at sea floor (4000 m) and 50% into atmosphere, (d) 100% at 1500 m depth and (e) 100% at sea floor. Since no carbon leaves the system, all runs approached the same post-fossil fuel equilibrium after several thousand years, C _a - 1150 ppm, almost four times the pre-fossil fuel value (- 300 ppm). But the transient response of these cases showed a marked variation ranging from a peak overshoot value of 2800 ppm in the year 2130 for 100% atmospheric injection to a slight decrease to the pre-fossil fuel 300 ppm lasting till 2300 with a subsequent slow approach to equilibrium for the 100% deep-ocean injection. The implications of these results for an oceanic injection strategy to mitigate the climatic impact of fossil-fuel CO₂ is discussed, as are the ingredients of a second generation carbon cycle model for carrying out such forecasts on an engineering design basis.     

A geochemical study of magmatism associated with the initial stages of back-arc spreading

Bransfield Strait is a narrow basin separating the South Shetland Islands from the Antarctic Peninsula and is attributed to recent back-arc extension behind the South Shetland volcanic arc. The volcanic islands of Deception and Bridgeman are situated close to the axis of spreading, whereas Penguin Island lies slightly to the north of this axis. The mineralogy, petrology and geochemistry of the lavas of the three volcanoes have been studied in order to provide information on the nature of magmatism associated with the initial stages of back-arc spreading.Deception Island lavas range from olivine basalt to dacite, and all are highly sodic, with high Na/K, K/Rb, Ba/Rb and Zr/Nb ratios and with Ce_N/Yb_N = 2. Incompatible elements increase systematically between basalt and rhyodacite, while Sr decreases, suggesting that fractional crystallisation is the dominant process relating lava compositions. The rhyodacites have high concentrations of Zr, Y and the REE and negative Eu anomalies and are compositionally similar to oceanic plagiogranite. Bridgeman Island lavas are mostly basaltic andesites, but the levels of many incompatible elements, including REE, are significantly lower than those of Deception lavas, although Ce_N/Yb_N ratios and ⁸⁷Sr/⁸⁶Sr ratios (0.7035) are the same. Penguin Island lavas are magnesian, mildly alkaline olivine basalts with a small range of composition that can be accommodated by fractional crystallisation of olivine, clinopyroxene and/or chromite. Penguin lavas have higher ⁸⁷Sr/⁸⁶Sr (0.7039) and Ce_N/ Yb_N (4) ratios than Deception and Bridgeman lavas. The Rb/Sr ratios of Deception and Penguin basalts (ca. 0.01) are much too low to account for their present ⁸⁷Sr/⁸⁶Sr ratios.Modelling suggests that the source regions of the lavas of the three volcanoes share many geochemical features, but there are also some significant differences, which probably reflects the complex nature of the mantle under an active island arc combined with complex melting relationships attending the initial stages of back-arc spreading. Favoured models suggest that Bridgeman lavas represent 10–20% melting and the more primitive Deception lavas 5–10% melting of spinel-peridotite, whereas Penguin lavas represent less then 5% melting of a garnet-peridotite source. The mantle source for Bridgeman lavas seems to have undergone short-term enrichment in K, Rb and Ba, possibly resulting from dewatering of the subducted slab. Hydrous melting conditions may also account for the more siliceous, high-alumina nature and low trace element contents of Bridgeman lavas.