Methods for reactive oxygen species (ROS) detection in aqueous environments

This review summarizes direct and indirect analytical methods for the detection and quantification of the reactive oxygen species (ROS): ¹O₂, O ₂ ^·? /HOO·, H₂O₂, HO·, and CO ₃ ^·? in aqueous solution. Each section briefly describes the chemical properties of a specific ROS followed by a table (organized alphabetically by detection method, i.e., absorbance, chemiluminescence, etc.) summarizing the nature of the observable (associated analytical signal) for each method, limit of detection, application notes, and reaction of the probe molecule with the particular ROS.     

Comparative Evaluation of Single‐Well LNAPL Tracer Testing at Five Sites

Light nonaqueous phase liquid (LNAPL) tracer testing is a technique used to directly measure LNAPL flow in situ and evaluate LNAPL mobility and recoverability. The test method consists of adding a fluorescent oil‐soluble tracer to LNAPL within a well, isolating small volumes of LNAPL with known tracer concentrations for use as in‐well calibration standards, and measuring the rate of tracer concentration decline in the well over time. The test measures LNAPL flux through the well, which is directly related to LNAPL mobility and recoverability in the surrounding formation. Test results for a total of 29 wells at five sites are presented. Results from LNAPL tracer testing were comparable to results obtained through other methods, and the method offers a time‐averaged result measured over a relatively long period, in ambient conditions, and reflects the influences of heterogeneity and hydraulic changes. In some cases, tracer concentration decline followed unexpected patterns, and these data have led to a better understanding of test assumptions, mechanisms influencing tracer distribution, and options to improve test execution and data interpretation. Method improvements developed over the course of the field studies included refinement of pre‐test screening of LNAPL fluorescence and improvements to measurement equipment. Overall, the field studies confirmed the technical validity and usefulness of the LNAPL tracing technique to support LNAPL mobility and recoverability assessments.     

Satellite imaging coral reef resilience at regional scale. A case-study from Saudi Arabia

We propose a framework for spatially estimating a proxy for coral reef resilience using remote sensing. Data spanning large areas of coral reef habitat were obtained using the commercial QuickBird satellite, and freely available imagery (NASA, Google Earth). Principles of coral reef ecology, field observation, and remote observations, were combined to devise mapped indices. These capture important and accessible components of coral reef resilience. Indices are divided between factors known to stress corals, and factors incorporating properties of the reef landscape that resist stress or promote coral growth. The first-basis for a remote sensed resilience index (RSRI), an estimate of expected reef resilience, is proposed. Developed for the Red Sea, the framework of our analysis is flexible and with minimal adaptation, could be extended to other reef regions. We aim to stimulate discussion as to use of remote sensing to do more than simply deliver habitat maps of coral reefs.     

Rapid evaluation and damage assessment of instrumented highway bridges

This study focuses on the use of strong motion data recorded during earthquakes and aftershocks to provide a preliminary assessment of the structural integrity and possible damage in bridges. A system identification technique is used to determine dynamical characteristics and high‐fidelity first‐order linear models of a bridge from low level earthquake excitations. A finite element model is developed and updated using a genetic algorithm optimization scheme to match the frequencies identified and to simulate data from a damaging earthquake for the bridge. Here, two criteria are used to determine the state of the structure. The first criteria uses the error between the data recorded or simulated by the calibrated nonlinear finite element model and the data predicted by the linear model. The second criteria compares relative displacements of the structure with displacement thresholds identified using a pushover analysis. The use of this technique can provide an almost immediate, yet reliable, assessment of the structural health of an instrumented bridge after a seismic event. Copyright © 2011 John Wiley & Sons, Ltd.     

Seismic records of late Pleistocene aridity in Lake Tanganyika,tropical East Africa

New intermediate-resolution, normal-incidence seismic reflection profiles from Lake Tanganyika’s central basin capture dramatic evidence of base-level change during two intervals of the late Pleistocene. Four seismically-defined stratigraphic sequences (A–D) tied to radiocarbon-dated sediment cores provide a chronology for fluctuating environmental conditions along the Kalya Platform. Stacked, oblique clinoforms in Sequence C are interpreted as prograding siliciclastic deltas deposited during a major regression that shifted the paleo-lake shore ∼21 km towards the west prior to ∼106 ka. The topset-to-foreset transitions in these deltas suggest lake level was reduced by ∼435 m during the period of deposition. Mounded reflections in the overlying sequence are interpreted as the backstepping remnants of the delta system, deposited during the termination of the lowstand and the onset of transgressive conditions in the basin. The youngest depositional sequence reflects the onset of profundal sedimentation during the lake level highstand. High amplitude reflections and deeply incised channels suggest a short-lived desiccation event that reduced lake level by ∼260 m, interpreted as a product of Last Glacial Maximum (32–14 ka) aridity. Paleobathymetric maps constructed for the two interpreted regressions reveal that despite the positive lake-floor topography created by the Kavala Island Ridge Accommodation Zone, Lake Tanganyika remained a large, mostly connected water body throughout the late Pleistocene. The results of this analysis further imply that Lake Tanganyika is the most drought resistant water body in the East African tropics, and may have acted as a refuge for local and migrating fauna during periods of prolonged aridity.     

Calcium levels in <Emphasis Type="Italic">Daphnia</Emphasis> ephippia cannot provide a useful paleolimnological indicator of historical lakewater Ca concentrations

Despite reductions in atmospheric sulphur emissions and the resulting decline in acidic deposition, many lakes on the Canadian Shield that have experienced acidification are either recovering at a rate slower than expected or not recovering at all. This lack of recovery is believed to be partly the consequence of the depletion of exchangeable base cations (principally calcium, Ca) from watershed soils. Although the implications of reduced Ca availability for biological communities remain poorly understood, the effects on crustacean zooplankton populations may be severe, as Ca is the primary structural component of the crustacean zooplankton exoskeleton. Because the daphniid resting egg is protected by a modified portion of the exoskeleton (ephippia) and because these ephippia are well preserved in lake sediments, we investigated whether inter-specific differences in Ca content are recoverable from Daphnia ephippia. However, using two methods, we did not find a recoverable Ca signal in the ephippia, indicating that future efforts should be focused upon sedimentary taxonomic assemblage differences, not differences in ephippial Ca levels.     

Rates of fluvial bedrock incision within an actively uplifting orogen: Central Karakoram Mountains, northern Pakistan

Terrestrial cosmogenic nuclide (TCN) ¹⁰Be surface exposure ages for strath terraces along the Braldu River in the Central Karakoram Mountains range from 0.8 to 11 ka. This indicates that strath terrace formation began to occur rapidly upon deglaciation of the Braldu valley at  11 ka. Fluvial incision rates for the Braldu River based on the TCN ages for strath terraces range from 2 to 29 mm/a. The fluvial incision rates for the central gorged section of the Braldu River are an order of magnitude greater than those for the upper and lower reaches. This difference is reflected in the modern stream gradient and valley morphology. The higher incision rates in the gorged central reach of the Braldu River likely reflect differential uplift above the Main Karakoram Thrust that has resulted in the presence of a knickpoint and more rapid fluvial incision. The postglacial fluvial incision rate (2–3 mm/a) for the upper and lower reaches are of the same order of magnitude as the exhumation rates estimated from previously published thermochronological data for the Baltoro granite in the upper catchment region and for the adjacent Himalayan regions.     

A review of penetrometers for subsurface access on comets and asteroids

Abstract— The characterization of comet and asteroid interiors will eventually require in situ exploration with drills, penetrators/penetrometers, hypervelocity impactors, excavators or other devices. Because they offer desirable scientific capabilities and relative mechanical simplicity, penetrators and penetrometers, which use only axial force to push beneath the surface, are a good choice for near‐term missions. Penetrometers are instruments, generally deployed from a larger vehicle, that measure subsurface mechanical properties and may also contain additional scientific instruments. There are three basic types: “fast” penetrometers are released from above and plunge into the surface. Static and dynamic (collectively referred to as “slow”) penetrometers use, respectively, a constant slow penetration speed and periodic hammering impulses. The low gravity environment of asteroids and comets presents a key challenge to instrument deployment and also greatly affects the mechanical properties of surface materials, and in turn penetrometer performance. The Rosetta mission, currently en route to comet 67P/Churyumov‐Gerasimenko, will be the next mission to try both fast and slow, dynamic penetrometry, when it arrives in 2014. We present some new concepts of static penetrometers for small body exploration that are adapted to the low gravity environment. The low gravity environment also presents challenges for the testing of penetrometers on Earth and a number of previous solutions are described and new methods suggested. In the next generation of missions to study comets and asteroids, penetrometers could provide important data on their mechanical, seismic, thermal, electromagnetic, and chemical characteristics, as well as sample collection.     

Hyperaccretion

I briefly review the physics of accretion at rates well above the Eddington value. In stellar-mass systems, the result is generally an ultraluminous X-ray binary, and I show how SS433 fits into this picture. Conditions are relatively less extreme in active galactic nuclei, as the greatest likely accretion rates are not far above the electron-scattering Eddington value. However, even quite modest mass inflow rates exceed the corresponding value for dust opacity. I show that the obscuring torus invoked in unified AGN schemes is the probable result, and note that the matter in the torus probably does not supply the matter accreting on to the central black hole and thus powering the AGN.