Al,Si ordering in cordierite using “magic angle spinning” NMR

A method of determining the number of Al-O-Al bonds per unit cell from ²⁹Si nuclear magnetic resonance (NMR) data of synthetic cordierites with increasing Si, Al order is described. The number of Al-O-Al bonds is found to vary linearly with the logarithm of the annealing time. This may be correlated with previously published heat of solution data on similar samples (Carpenter et al. 1983) to determine the enthalpy change Δh, associated with a single Al?Si interchange in cordierite. Δh is found to be 8.1 kcal/mole. The NMR data show that the short range Al, Si order cannot be described in terms of twin domains of ordered orthorhombic cordierite. An ordering model derived from group theoretical constraints on possible Al, Si distributions within the hexagonal symmetry of the cordierite is found to provide a better fit to the NMR data.     

The structure of the mid- and high-latitude ionosphere during the November 2004 storm event obtained from GPS observations

GPS data from the International GNSS Service (IGS) network were used to study the development of the severe geomagnetic storm of November 7–12, 2004, in the total electron content (TEC) on a global scale. The TEC maps were produced for analyzing the storm. For producing the maps over European and North American sectors, GPS measurements from more than 100 stations were used. The dense network of GPS stations provided TEC measurements with a high temporal and spatial resolution. To present the temporal and spatial variation of TEC during the storm, differential TEC maps relative to a quiet day (November 6, 2004) were created. The features of geomagnetic storm attributed to the complex development of ionospheric storm depend on latitude, longitude and local time. The positive, as well as negative effects were detected in TEC variations as a consequence of the evolution of the geomagnetic storm. The maximal effect was registered in the subauroral/auroral ionosphere during substorm activity in the evening and night period. The latitudinal profiles obtained from TEC maps for Europe gave rise to the storm-time dynamic of the ionospheric trough, which was detected on November 7 and 9 at latitudes below 50°N. In the report, features of the response of TEC to the storm for European and North American sectors are analyzed.     

Lateral tidal mixing in the Antarctic marginal seas

Tidal mixing plays an important role in the modification of dense water masses around the Antarctic continent. In addition to the vertical (diapycnal) mixing in the near-bottom layers, lateral mixing can also be of relevance in some areas. A numerical tide simulation shows that lateral tidal mixing is not uniformly distributed along the shelf break. In particular, strong mixing occurs all along the Ross Sea and Southern Weddell Sea shelf breaks, while other regions (e.g., the western Weddell Sea) are relatively quiet. The latter regions correspond surprisingly well to areas where indications for cross-shelf exchange of dense water masses have been found. The results suggest that lateral tidal mixing may account for the relatively small contribution of Ross Sea dense water masses to Antarctic Bottom Water.     

The first field-based descriptions of pumping-induced saltwater intrusion and upconing

Development of the ideas about the equilibrium between freshwater and saline water has received considerable attention in the literature, but little has been written so far about the earliest scientific works about well salinization. Based on a review of the literature from the second half of the 19th century and the early 20th century, this historical note explores how insights into groundwater abstraction and saltwater intrusion developed, and examples of the earliest field studies are provided. Fundamental research was driven by the need for increasing water supply, but the progress of science did not lead to sustainable management practices everywhere. Research outcomes were shared between scientists of different countries, marking the beginning of coastal hydrogeology as a scientific specialization in the first decade of the 20th century.     

PLL Tracking Performance in the Presence of Oscillator Phase Noise

The tracking performance of a Phase Lock Loop (PLL) is affected by the influence of several error sources. In addition to thermal noise and dynamic stress error, oscillator phase noise can cause significant phase jitter which degrades the tracking performance. Oscillator phase noise is usually caused by two different effects: Allan deviation phase noise is caused by frequency instabilities of the receiver's reference oscillator and the satellite's frequency standard. It can be termed as system-inherent phase noise and is relevant for both static and dynamic applications. “External” phase noise, however, is caused by vibration and is a major problem for dynamic applications. In the context of this paper, both types of phase noise will be modeled and the resulting integrals will be evaluated for PLLs up to the third order. Besides, phase jitter induced by thermal noise and signal dynamics will also be discussed, thus providing all necessary formulas for analyzing the performance of a phase lock loop in case of different forms of stress. Since the main focus is centered on the effects of oscillator phase noise, the overall PLL performance is graphically illustrated with and without consideration of oscillator phase noise. © 2002 Wiley Periodicals, Inc.     

Experimental study of the mechanical properties of expansive soil with added nanomaterials

The main purpose of this paper is to describe ways to improve the microstructure of expansive soil by adding nanomaterials. Mechanical tests were done to explore the changes in shear strength and compression index of expansive soil that was modified by adding different amounts of two kinds of nanomaterials (nano-alumina and nano-silica). The test results show that adding 1.2% nano-alumina and about 2% nano-silica to expansive soil provides the optimal compression index. The test results show that adding 1.2% nano-alumina and about 1.5% nano-silica to expansive soil provides the optimal unconfined compression stress. Scanning electron microscopy of the microstructure of expansive soil modified by nanomaterials provided a deeper understanding of the effects of nanomaterials on improving expansive soil.     

Climate change and local adaptation strategies in the middle Inner Mongolia,northern China

According to records of 17 meteorological stations distributed in the study area, climate change of the middle Inner Mongolia in northern China was analyzed in this paper. Based on SPOT VGT data, combined with field investigation, local vegetation change was detected in the last 10 years. The results show that annual mean air temperature obviously rose, while precipitation slightly decreased in fluctuation in the study area during the last 50 years. Air temperature increasing rates are +0.318°C 10 year⁻¹ during 1960-2009 and +0.423°C 10 year⁻¹ during 1980–2009, while precipitation decreasing rates are −2.91 mm 10 year⁻¹ during 1960–2009. There were five different dry or wet periods from the 1960s to the 2000s in order, and the wetter 1990s and the drier 2000s changed dramatically in the study area. Local climate totally tend to warm–dry conditions during the last 50 years. According to coefficient of variation (Cv) of yearly growing-season cumulative NDVI value and yearly NDVI maximum in pixel scale, vegetation had experienced huge temporal and spatial variation during the last 10 years. Recently, frequent droughts and dust storms seriously affected local agriculture and grazing activities, and resulted in heavy economic loss, especially over the drought period of 1999–2001. Faced with those drought disasters accompanied with strong dust storms, the local authorities proposed the enclosing-transferring strategy and made great efforts to adapt overt climate change and improve environment, including making selective emigration, decreasing livestock numbers, fencing grasslands and building forage production bases with irrigation instruments and actively adjusting industry structure. However, some effects and potential problems of this adaptation strategy still need to be comprehensively assessed further in longer time scales and aimed at different sub-regions.     

Output-only identification of the modal and physical properties of structures using free vibration response

The viability of a complete structural characterization of civil structures is explored and discussed. In particular, the identification of modal (i.e. natural frequencies, damping ratios and modal shapes) and physical properties (i.e. mass and stiffness) using only the structure’s free decay response is studied. To accomplish this, modal analysis from free vibration response only (MAFVRO) and mass modification (MM) methodologies are engaged along with Wavelet based techniques for optimal signal processing and modal reconstruction. The methodologies are evaluated using simulated and experimental data. The simulated data are extracted from a simple elastic model of a 5 story shear building and from a more realistic nonlinear model of a RC frame structure. The experimental data are gathered from shake table test of a 2-story scaled shear building. Guidelines for the reconstruction procedure from the data are proposed as the quality of the identified properties is shown to be governed by adequate selection of the frequency bands and optimal modal shape reconstruction. Moreover, in cases where the structure has undergone damage, the proposed identification scheme can also be applied for preliminary assessment of structural health.     

Selection of hazardous waste dumpsites based on parameters effecting soil adsorption capacity – a case study

A careful selection of waste dumpsites, particularly hazardous ones, is very important for sustainable water resources management. Several laboratory experiments were carried out on the field samples to study adsorption capacity using p-dichlorobenzene (a solvent used in various industrial processes) as the test contaminant. The effect of parameters such as organic matter, clay, and iron and aluminium oxides, which are known to influence the soil adsorption capacity, are studied in the present work. Several soil samples from the Patancheru Industrial Area (Hyderabad, India) were collected and characterized. Only three soils, which had a comparatively high percentage of organic matter, clay, iron and aluminium oxide contents were used for the adsorption studies. The results clearly indicated a decrease in the adsorption capacity of the soils by as much as 75% when organic matter was removed. The other parameters such as clay and iron and aluminium oxides also play an important role in adsorption (57 and 39.8% reduction respectively). It was observed that out of the selected factors organic matter in the soils has the maximum effect regarding the adsorption of p-dichlorobenzene. Since the selected soils contain comparatively more organic matter, clay and iron and aluminium oxides in the selected industrial area, these can be used as sites for dumping hazardous waste, which can be further treated by methods like bioremediation.