Biomediation of calcrete at the gold anomaly of the Barns prospect,Gawler Craton,South Australia

Anomalously high Au concentrations (2.5 to 50 ppb) in regolith carbonate accumulations, such as calcrete and calcareous sands in aeolian sand dunes overlying Au mineralisation of the Gawler Craton, South Australia, show a marked covariance of Au with K, Mg and most notably Ca. This relationship appears to be linked to the authigenic formation of smectites and carbonates within the aeolian dunes in the region. However, little is known about the processes involved in the formation of carbonates under semi-arid and arid conditions. In this study the geochemical properties of aeolian dunes along several depth profiles of 2 to 4 m are investigated in order to assess the relationship between Au mobility and calcrete formation. In the profiles a strongly systematic relationship between Au and the increasing Ca–Mg contents at depth highlights the close association between the enrichment of Au in the calcrete and the underlying hydrothermal mineralisation. Intense calcrete formation and concurrent Au enrichment also occurs in the vicinity of roots penetrating the dune. Thin section petrography and cathodoluminescence show that most of the calcrete in the regolith profiles is micritic; some sparic crystallites have also been identified. To demonstrate the presence of microbial processes that may mediate the formation of calcrete, samples from a depth profile in the dune were taken under sterile conditions. After amendment with urea and incubation of up to 24 h, up to 18 mg/l of NH₄⁺ were detected in near surface samples. At depth of 2.3 m 1 mg/l NH₄⁺ were detected compared to a control that contained below 0.05 mg/l NH₄⁺. These results suggest that the genesis of calcrete and pedogenic carbonate in the area may be partly biologically mediated via processes such as the metabolic breakdown of urea by resident microbiota which generates a pH and pCO₂ environment conducive to the precipitation of carbonate. In the process of urea breakdown organic Au complexes such as Au-amino acid complexes may become destabilised in solution and Au may be co-precipitated, resulting in the fine, non-particulate distribution of Au throughout the micritic calcrete carbonate. In conclusion, this study suggests a coupled mechanism of biologically mediated and inorganic mechanisms that lead to the formation of Au-in-calcrete anomalies.     

On the robustness of ENSO teleconnections

Using observations covering the last 128 years we show that apparent changes in El Niño-Southern Oscillation (ENSO) teleconnections can be explained by chance and stem from sampling variability. This result is backed by experiments in which an atmosphere model is driven by 123 years of observed sea surface temperature. The possibility of ENSO teleconnection changes in a warming climate is further investigated using coupled GCMs driven by past and projected future greenhouse gas concentrations. These runs do not exclude physical changes in the teleconnection strength but do not agree on their magnitude and location. If existing at all, changes in the strength of ENSO teleconnection, other than obtained by chance, are small and will only be detectable on centennial time scales.     

Dynamic simulation of littoral zone habitats in low Chesapeake Bay. II. Seagrass habitat primary production and water quality relationships

Seagrasses are indicators of ecosystem state because they are sensitive to variations in water composition and clarity resulting from watershed-level impacts. A simulation model designed to studyZostera marina (eelgrass) habitat dynamics in a variable littoral zone environment was used to address the potential ecological responses to eutrophication in lower Chesapeake Bay. The adjacent channel boundary environment is a source of dissolved and particulate materials to the littoral zone. In the simulations, concentrations of key water quality variables in the adjacent estuarine channel boundary were either halved or doubled relative to the base case to investigate light versus nitrogen effects. The role of the seagrass meadow in littoral zone carbon and nitrogen dynamics was evaluated when meadow size was changed in the model. Particulate and dissolved organic carbon accounted for 83% of the submarine light attenuation in the seagrass meadow. In all model runs, the water column concentrations of chlorophylla and dissolved inorganic nitrogen (DIN) were below the habitat criteria proposed as critical to seagrass survival. Eelgrass community production was carefully regulated by the interactive effects of light, nitrogen, and grazing on epiphyte growth. Increased eelgrass coverage in the littoral zone led to a simulated doubling of ecosystem primary production but reduced the fraction of production by planktonic and sediment microalgae. The simulation model presented here demonstrated the importance of material input from the channel in littoral zone biogeochemical dynamics. Submarine ligh regulated primary production more strongly than inorganic nitrogen concentrations in the model. External DIN concentrations influenced seagrass survival indirectly: enrichment stimulated growth of epiphytes and phytoplankton and promoted shading of the seagras leaf. The model was based upon a unimpacted ecosystem and deteriorated water quality negatively influenced primary production greater than the increases triggered by improved condition. Increased material loading to the littoral zone reduced submarine light availability, increased phytoplankton production, lowered ecosystem production, and reduced subtidal vegetated habitat. This simulation model of the estuarine littoral zone model combines hydrodynamics, biogeochemical sources and sinks, and living resources in order to better understand structure, function, and change in aquatic ecosystems.     

Deformation microstructures in experimentally deformed Maryland diabase

Experimentally deformed Maryland diabase has been examined using the transmission electron microscope in order to determine the mechanisms of deformation operative over a range of temperatures and pressures and thereby aid in the interpretation of polyphase flow data. Deformation mechanisms within the plagioclase and clinopyroxene of the diabase have been compared to those within monomineralic aggregates of these phases deformed at the same conditions. Both phases deform by microfracturing, mechanical twinning, and intracrystalline slip.Data for the monomineralic aggregates show that plagioclase is stronger than clinopyroxene at <800°C, but weaker at ≥ 800°C, for a pressure of 15 kbar and strain rate of 10^?6/sec. Observations of the diabase are consistent with this result: at < 800°C, the plagioclase and pyroxene grains are about equally strained, whereas at ≥ 800°C, almost all of the sample strain is accommodated by the plagioclase, the more continuous phase.     

Altersbeziehungen zwischen Metamorphosen,mechanischen Deformationen und Intrusionen am Südrand des Rhodope-Massivs (Makedonien,Griechenland)

Zusammenfassung Ausgedehnte Granodiorit- und Granitmagmen intrudierten am Südrand des Rhodope-Massivs (Symvolongebirge und Kavala-Gebiet, Nordgriechenland) syntektonisch in bezug auf eine Formung, die durch überwiegend flach nach NE bis ENE tauchende Faltungs- und Scherungsachsen gekennzeichnet ist (B₂-Tektonik). Die metamorphen Hüllgesteine wurden von der B₂-Tektonik ebenfalls kräftig erfaßt. Ihr älteres Gefüge, das durch mittelsteil nach NNW tauchende B₁-Achsen bestimmt war, kommt daher nur noch reliktisch vor. Der Mineralbestand sowohl der Magmatite als auch ihres metamorphen Rahmens wurde im Zuge der B₂-Tektonik retrograd metamorph umgewandelt.Radiometrische Altersbestimmungen lassen erkennen, daß die magmatischen Gesteine spätestens im Oberkarbon kristallisierten, anschließend jedoch wiederholt aufgewärmt wurden. Das Alter der prämagmatischen Metamorphose der Hüllgesteine und der mit dieser in Zusammenhang stehenden B₁-Tektonik kann demnach nicht jünger als kaledonisch sein.

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Extensive granodioritic and granitic magmas were intruded in the southern margin of the Rhodope-Massif (Symvolon mountains and Kavala region, northern Greece). The intrusions took place syntectonically to a deformation which is characterized by predominantly gently NE to ENE plunging fold- and shear-axes (B₂-folding). The mantling rocks, which have been metamorphosed long before this B₂-folding have an older structure which is characterized by mediumly NNW plunging B₁-axes, visible only in relicts. During the B₂-folding the mineral contents of the igneous rocks and their metamorphic mantling rocks have been metamorphosed retrogressively.Radiometric dating indicates that the crystallization of the magmatic rocks have a minimum age of Upper-Carboniferous, but subsequently these rocks were reheated repeatedly. The age of the premagmatic metamorphism of the mantling rocks and that of the related B₁-foldnig, therefore, cannot be younger than Caledonic.

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Résumé Dans la partie sud du massif du Rhodope (montagnes du Symvolon et région de Kavala, Grèce du Nord) existent de grandes intrusions de magmas granodioritiques et granitiques. Les intrusions eurent lieu syntectoniquement au cours d'une phase de déformation caractérisée par des axes de plis et de cisaillement, généralement à plongement faible vers le NE à ENE (tectonique B₂). Les roches encaissantes, qui furent métamorphisées longtemps avant cette phase de tectonique B₂, ont une structure plus ancienne, caractérisée par des axes B₁ plongeant moyennement vers le NNW. Cette structure est reconnaissable seulement dans des parties réiduelles. Durant la tectonique B₂ les roches éruptives et les roches encaissantes métamorphisées subirent un métamorphisme rétrograde.Des datations radiométriques indiquent, pour la cristallisation des roches magmatiques, au minimum un âge Carbonifère supérieur. Dans la suite ces roches furent réchauffées â plusieures reprises. Le métamorphisme plus ancien des roches encaissantes et la tectonique B₁ associée à ce métamorphisme ne peuvent donc pas Être plus récents que l'époque calédonienne.

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Rhodope ( Symrolon Kavala, ) - . , , , , NE ENE (B₂- ). ₂. , B₁ NNW, . , , . , , , , . , - B₁ .

     

A Linked Physical and Biological Framework to Assess Biogeochemical Dynamics in a Shallow Estuarine Ecosystem

The littoral zone of Chesapeake Bay contains a mosaic of shallow vegetated and nonvegetated habitats with biotic components that are sensitive to changes in biological and physical driving factors. Static and dynamic modelling frameworks provide an integrative way to study complex hydrodynamic and biogeochemical processes in linked estuarine habitats. In this study we describe a spatial simulation model developed and calibrated relative to a specific littoral zone, estuarine ecosystem. The model consisted of four distinct habitats that contained phytoplankton, sediment microalgae, Zostera marina (eelgrass), and Spartina alterniflora. There was tidal exchange of phytoplankton, particulate and dissolved organic carbon and dissolved inorganic nitrogen between the littoral zone ecosystem and the offshore channel. Physical exchange and biogeochemical transformations within the habitats determined water column concentrations in each habitat. Predicted subtidal water column concentrations and Z. marina and S. alterniflora biomass were within the variability of validation data and the predicted annual rates of net primary production were similar to measured rates. Phytoplankton accounted for 17%, sediment microalgae 46%, the Z. marina community 24% and S. alterniflora 13% of the annual littoral zone primary production. The linked habitat model provided insights into producer, habitat and ecosystem carbon and nitrogen properties that might not have been evident with stand-alone models. Although it was an intra-ecosystem sink for particulate carbon, the seagrass habitat was a DOC source and responsible for over 30% of the littoral zone carbon and nitrogen primary production. The model predicted that the Goodwin Islands littoral zone was a sink of channel derived POC, but a source of DOC to the surrounding estuary. The framework created in this study of estuarine ecosystem dynamics is applicable to many different aquatic systems over a range of spatial and temporal scales.     

Snow accumulation distribution inferred from time‐lapse photography and simple modelling

The spatial and temporal distribution of snow accumulation is complex and significantly influences the hydrological characteristics of mountain catchments. Many snow redistribution processes, such as avalanching, slushflow or wind drift, are controlled by topography, but their modelling remains challenging. In situ measurements of snow accumulation are laborious and generally have a coarse spatial or temporal resolution. In this respect, time‐lapse photography shows itself as a powerful tool for collecting information at relatively low cost and without the need for direct field access. In this paper, the snow accumulation distribution of an Alpine catchment is inferred by adjusting a simple snow accumulation model combined with a temperature index melt model to match the modelled melt‐out pattern evolution to the pattern monitored during an ablation season through terrestrial oblique photography. The comparison of the resulting end‐of‐winter snow water equivalent distribution with direct measurements shows that the achieved accuracy is comparable with that obtained with an inverse distance interpolation of the point measurements. On average over the ablation season, the observed melt‐out pattern can be reproduced correctly in 93% of the area visible from the fixed camera. The relations between inferred snow accumulation distribution and topographic variables indicate large scatter. However, a significant correlation with local slope is found and terrain curvature is detected as a factor limiting the maximal snow accumulation. Copyright © 2010 John Wiley & Sons, Ltd.     

Vegetation history and environmental development since ca 6000 cal yr BP in and around Ispani 2 (Kolkheti lowlands,Georgia)

The Kolkheti lowlands of western Georgia have a unique vegetation and a rich cultural history. Palynological and macrofossil analysis accompanied by AMS ¹⁴C-dates of the deposits of the Ispani 2 mire near Kobuleti allow the reconstruction of regional vegetation, environmental history and local peatland development within the context of Black Sea level and cultural changes. Comparison of two adjacent peatland cores confirms spatial differences in wetland development. Prior to 5400 cal yr BP, the Ispani basin was a floodplain of an active river system where overbank deposits with fluvially transported Castanea pollen were deposited. Subsequently, a lake or lagoon developed in which reeds expanded. These were succeeded by herb-rich open alder carrs. After 1900 cal yr BP, Carpinus and Fagus expanded on the dry grounds, where formerly Quercus was more abundant. Also Castanea declined. Local reedbeds, that burned regularly, succeeded the alder carr. After 1000 cal yr BP, a percolation bog developed resulting in the formation of 4 m of loose, porous, and largely undecomposed Sphagnum austinii peat with Molinia roots. The upper 50 cm of the analysed section show extensive human impact on the landscape during the 20th century.     

The concentration–velocity dispersion relation in galaxy groups

Based on results from cold dark matter N -body simulations, we develop a dynamical model for the evolution of subhaloes within group-sized host haloes. Only subhaloes more massive than 5 × 10⁸ M_⊙ are considered, because they are massive enough to possibly host luminous galaxies. On their orbits within a growing host potential the subhaloes are subject to tidal stripping and dynamical friction. At the present time  ( z = 0)  , all model hosts have equal mass  ( M _vir= 3.9 × 10¹³ M_⊙)  but different concentrations associated with different formation times. We investigate the variation of subhalo (or satellite galaxy) velocity dispersion with host concentration and/or formation time. In agreement with the Jeans equation, the velocity dispersion of subhaloes increases with the host concentration. Between concentrations of ∼5 and ∼20, the subhalo velocity dispersions increase by a factor of ∼1.25. By applying a simplified tidal disruption criterion, that is, rejection of all subhaloes with a tidal truncation radius below 3  kpc at   z = 0  , the central velocity dispersion of the 'surviving' subhalo sample increases substantially for all concentrations. The enhanced central velocity dispersions in the surviving subhalo samples are caused by a lack of slow tangential motions. Additionally, we present a fitting formula for the anisotropy parameter which does not depend on concentration if the group-centric distances are scaled by r _s, the characteristic radius of the Navarro, Frenk & White profile. Since the expected loss of subhaloes and galaxies due to tidal disruption increases the velocity dispersion of surviving galaxies, the observed galaxy velocity dispersion can substantially overestimate the virial mass.     

The sediment load and deposition by river discharge and their relation to organochlorine pesticides pollutants in the sediment bottom of Nha Trang Bay,Vietnam

Ocean Science Journal - Based on previous results from the “River reef impact studies project that was carried out as a co-operation programme between ZMT (Germany) and NIO (Vietnam) from...