The Tauern Window (Eastern Alps, Austria): a new tectonic map, with cross-sections and a tectonometamorphic synthesis

We present a tectonic map of the Tauern Window and surrounding units (Eastern Alps, Austria), combined with a series of crustal-scale cross-sections parallel and perpendicular to the Alpine orogen. This compilation, largely based on literature data and completed by own investigations, reveals that the present-day structure of the Tauern Window is primarily characterized by a crustal-scale duplex, the Venediger Duplex (Venediger Nappe system), formed during the Oligocene, and overprinted by doming and lateral extrusion during the Miocene. This severe Miocene overprint was most probably triggered by the indentation of the Southalpine Units east of the Giudicarie Belt, initiating at 23–21 Ma and linked to a lithosphere-scale reorganization of the geometry of mantle slabs. A kinematic reconstruction shows that accretion of European lithosphere and oceanic domains to the Adriatic (Austroalpine) upper plate, accompanied by high-pressure overprint of some of the units of the Tauern Window, has a long history, starting in Turonian time (around 90 Ma) and culminating in Lutetian to Bartonian time (45–37 Ma).     

Correction to: Leveraging HPC accelerator architectures with modern techniques — hydrologic modeling on GPUs with ParFlow

Computational Geosciences - A Correction to this paper has been published: https://doi.org/10.1007/s10596-021-10065-y     

Tier-based approaches for landslide susceptibility assessment in Europe

In the framework of the European Soil Thematic Strategy and the associated proposal of a Framework Directive on the protection and sustainable use of soil, landslides were recognised as a soil threat requiring specific strategies for priority area identification, spatial hazard assessment and management. This contribution outlines the general specifications for nested, Tier-based geographical landslide zonings at small spatial scales to identify priority areas susceptible to landslides (Tier 1) and to perform quantitative susceptibility evaluations within these (Tier 2). A heuristic, synoptic-scale Tier 1 assessment exploiting a reduced set of geoenvironmental factors derived from common pan-European data sources is proposed for the European Union and adjacent countries. Evaluation of the susceptibility estimate with national-level landslide inventory data suggests that a zonation of Europe according to, e.g. morphology and climate, and performing separate susceptibility assessments per zone could give more reliable results. To improve the Tier 1 assessment, a geomorphological terrain zoning and landslide typology differentiation are then applied for France. A multivariate landslide susceptibility assessment using additional information on landslide conditioning and triggering factors, together with a historical catalogue of landslides, is proposed for Tier 2 analysis. An approach is tested for priority areas in Italy using small administrative mapping units, allowing for relating socioeconomic census data with landslide susceptibility, which is mandatory for decision making regarding the adoption of landslide prevention and mitigation measures. The paper concludes with recommendations on further work to harmonise European landslide susceptibility assessments in the context of the European Soil Thematic Strategy.     

Origin of chondritic forsterite grains

Iron-poor and refractory lithophile element (RLE) rich forsterite grains occur in all major types of unequilibrated chondrites. In our laser ablation inductively coupled mass spectrometry (LA-ICPMS) minor and trace element study we show that refractory forsterites (RF) from carbonaceous (CC), unequilibrated ordinary (UOC) and a Rumuruti chondrite (RC) have similar chemical compositions with high RLE concentrations and low concentrations of Mn, Fe, Co and Ni. Fractionation of RLEs and rare earth elements (REEs) is in agreement with formation by crystallization from a RLE rich silicate melt. Low concentrations and the fractionation of moderately siderophile elements (Fe, Co, Ni) in RFs suggests formation at low oxygen fugacity, possibly in equilibrium with primitive Fe,Ni metal condensates in a gas of solar composition. Anomalously high Ti in the parental melt can be explained by Ti³⁺/Ti⁴⁺ ∼1.5, supporting formation of RF in highly reducing conditions. Low Mn concentrations indicate formation at high temperatures (>∼1160 K). The model of formation of RFs and the accompanying physico-chemical conditions during their formation as well as their relation to non refractory olivine are discussed.     

Deformation microstructures in experimentally deformed Maryland diabase

Experimentally deformed Maryland diabase has been examined using the transmission electron microscope in order to determine the mechanisms of deformation operative over a range of temperatures and pressures and thereby aid in the interpretation of polyphase flow data. Deformation mechanisms within the plagioclase and clinopyroxene of the diabase have been compared to those within monomineralic aggregates of these phases deformed at the same conditions. Both phases deform by microfracturing, mechanical twinning, and intracrystalline slip.Data for the monomineralic aggregates show that plagioclase is stronger than clinopyroxene at <800°C, but weaker at ≥ 800°C, for a pressure of 15 kbar and strain rate of 10^?6/sec. Observations of the diabase are consistent with this result: at < 800°C, the plagioclase and pyroxene grains are about equally strained, whereas at ≥ 800°C, almost all of the sample strain is accommodated by the plagioclase, the more continuous phase.     

http://www.sciencedirect.com/science/article/pii/S1674987114000395

The study of fluid inclusions in high-grade rocks is especially challenging as the host minerals have been normally subjected to deformation, recrystallization and fluid-rock interaction so that primary in- clusions, formed at the peak of metamorphism are rare. The larger part of the fluid inclusions found in metamorphic minerals is typically modified during uplift. These late processes may strongly disguise the characteristics of the ＂original＂ peak metamorphic fluid. A detailed microstructural analysis of the host minerals, notably quartz, is therefore indispensable for a proper interpretation of fluid inclusions. Cathodoluminescence （CL） techniques combined with trace element analysis of quartz （EPMA, LA- [CPMS） have shown to be very helpful in deciphering the rock-fluid evolution. Whereas high-grade metamorphic quartz may have relatively high contents of trace elements like Ti and A1, low- temperature re-equilibrated quartz typically shows reduced trace element concentrations. The result- ing microstructures in CL can be basically distinguished in diffusion patterns （along microfractures and grain boundaries）, and secondary quartz formed by dissolution-reprecipitation. Most of these textures are formed during retrograde fluid-controlled processes between ca. 220 and 500 ℃, i.e. the range of semi-brittle deformation （greenschist-facies） and can be correlated with the fluid inclusions. In this way modified and re-trapped fluids can be identified, even when there are no optical features observed under the microscope.     

Ductile deformation of garnet in mylonitic gneisses from the Münchberg Massif (Germany)

Mylonitic gneisses from the Münchberg Massif contain single grains (type I) and polycrystalline aggregates (type II) of garnet displaying a distinct elongation parallel to a macroscopic lineation which is interpreted as the result of ductile deformation. Lattice-preferred orientations of quartz (textures) symmetrical to the macroscopic foliation and lineation and the lack of rotational microfabrics indicate that the bulk deformation was pure shear at least during the latest strain increments. Garnet textures measured by EBSD together with microprobe analyses demonstrate that these two structural types of garnet can be related to two different processes of ductile deformation: (1) For the single grains stretching can be attributed to diffusion creep along grain boundary zones (Coble creep). The related mass transfer is indicated by the fact that primary growth zones are cut off at the long faces of the grains while the related strain shadow domains do not show comparable chemical zoning. Pressure solution and precipitation suitable to produce similar structures can be largely ruled out because retrogressive reactions pointing to the presence of free hydrous fluids are missing. (2) For the polycrystalline garnet aggregates consisting of cores grading into fine-grained mantles, dislocation creep and associated rotation recrystallization can be assumed. Continuous lattice rotation from the core to the outer polycrystalline rim allow a determination of the related dominant slip systems which are {100}<010> and equivalent systems according to the cubic lattice symmetry. The same holds for garnets which appear to be completely recrystallized. For this type of fine-grained aggregates an alternative nucleation model is discussed. Due to penetrative dislocation glide in connection with short range diffusion and the resulting lattice rotation, primary growth zones are strongly disturbed.Since for the considered rock unit of the Münchberg Massif peak metamorphic temperatures between 630 and 670 °C can be assumed, this study clearly demonstrates that the inferred processes of ductile garnet deformation can occur not only in HT regimes as often suggested in the literature even if embedded within a matrix of “low-strength” minerals like quartz, feldspars and micas.     

Transfer and early diagenesis of biogenic silica oxygen isotope signals during settling and sedimentation of diatoms in a temperate freshwater lake (Lake Holzmaar, Germany)

We have investigated the transfer of oxygen isotope signals of diatomaceous silica (δ¹⁸O_diatom) from the epilimnion (0-7 m) through the hypolimnion to the lake bottom (∼20 m) in freshwater Lake Holzmaar, Germany. Sediment-traps were deployed in 2001 at depths of 7 and 16 m to harvest fresh diatoms every 28 days. The 7 m trap collected diatoms from the epilimnion being the main zone of primary production, while the 16 m trap collected material already settled through the hypolimnion. Also a bottom sediment sample was taken containing diatom frustules from approximately the last 25 years. The δ¹⁸O_diatom values of the 7 m trap varied from 29.4‰ in spring/autumn to 26.2‰ in summer according to the temperature dependence of oxygen isotope fractionation and represent the initial isotope signal in this study. Remarkably, despite the short settling distance δ¹⁸O_diatom values of the 7 and the 16 m trap were identical only during spring and autumn seasons while from April to September δ¹⁸O_diatom values of the 16 m trap were roughly ∼1.5‰ enriched in ¹⁸O compared to those of the 7 m trap. Isotopic exchange with the isotopically lighter water of the hypolimnion would shift the δ¹⁸O_diatom value to lower values during settling from 7 to 16 m excluding this process as a cause for the deviation. Dissolution of opal during settling with intact organic coatings of the diatom cells and near neutral pH of the water should only cause a minor enrichment of the 16 m values. Nevertheless, opal from the bottom sediment was found to be 2.5‰ enriched in ¹⁸O compared to the weighted average of the opal from the 7 m trap. Thus, resuspension of bottom material must have contributed to the intermediate δ¹⁸O_diatom signal of the 16 m trap during summer. Dissolution experiments allowed further investigation of the cause for the remarkably enriched δ¹⁸O_diatom value of the bottom sediment. Experiments with different fresh diatomaceous materials show an increase of opaline ¹⁸O at high pH values which is remarkably reduced when organic coatings of the cells still exist or at near neutral pH. In contrast, high pH conditions do not affect the δ¹⁸O_diatom values of sub-fossil and even fossil opal. IR analyses show that the ¹⁸O enrichment of the sedimentary silica is associated with a decrease in Si-OH groups and the formation of Si-O-Si linkages. This indicates a silica dehydroxylation process as cause for the isotopic enrichment of the bottom sediment. Silica dissolution and dehydroxylation clearly induce a maturation process of the diatom oxygen isotope signal presumably following an exponential behaviour with a rapid initial phase of signal alteration. The dynamics of this process is of particular importance for the quantitative interpretation of sedimentary δ¹⁸O_diatom values in terms of palaeothermometry.