Sub-surface precipitation of salts in supercritical seawater

Extremely low solubility of typical seawater salts within certain supercritical sections of their pressure–temperature composition space is a proven experimental fact. Its consequences are often referred to as either 'shock crystallization' or 'out-salting'. Our alternative model for the formation of salt deposits hypothesizes that high temperatures and pressures characteristic for the high heat-flow zones of tectonically active basins may bring submarine brines into the out-salting regions and result in the accumulation of geological-scale salt depositions.
To confirm the laboratory observations, molecular-scale simulations (molecular dynamics) have been employed to study structural changes in a model seawater system where temperature increased from ambient to near-critical and supercritical. Fluid properties and phase transition regions extracted from the simulations were then used as input parameters for a reservoir simulator program to model out-salting in a simple hydrothermal geological system. Both numerical simulations and laboratory experiments confirm that supercritical out-salting is a viable process of geological significance for the formation and accumulation of evaporites. We suggest two regions where hydrothermally associated salts may be depositing today: Atlantis II Deep, in the Red Sea, and Lake Asale, Ethiopia.     

Optical dating of Holocene lake sediments: Elimination of the feldspar component in fine silt quartz samples

Optically stimulated luminescence of fine silt quartz was investigated to establish chronologies for lake sediments from the British Isles. Feldspar contamination and its potential effects on equivalent dose (D_e) determination were examined. A new feldspar contamination test based on the thermal quenching of quartz OSL and thermal assistance of feldspar OSL identified feldspar contamination in samples being treated for 20 min in 20% hydrofluoric acid. Feldspar component monitoring based on the post-IR OSL/OSL ratio was not sufficiently sensitive to monitor a feldspar component, but is a good indicator whether a standard SAR procedure can be applied successfully, despite the presence of feldspar. Based on these results we used a modified SAR protocol including a 100 s IRSL stimulation at 50 °C before OSL readout. This protocol could overcome any malign effects of feldspar even for a feldspar bearing polymineral sub-sample.     

Morphological development of the retention basin “Hartheim”: A case study

Flow in rivers and on floodplains is complex as it is affected by several interconnected factors such as topography, sediment transport and vegetation characteristics. The resulting processes are explained by the measure “Hartheim” planned for retention purposes at the Upper Rhine river. On the basis of existing formulas and instruments it is demonstrated that a good estimation of the development of the measure is possible. The proposed procedure is a useful tool for estimating morphological developments of restored river sections.     

Palisa catena: Small volcano chains in the western part of the central highlands

The morphology of a series of highland volcanoes found on the floor of the crater Palisa is similar to that of mare volcanoes. The superposition of the cones and craters indicate that this volcano complex had a complex, multiphase history of development. A blanket of relatively dark ash, which is between 4 and 13 km wide, is observed surrounding these volcanoes.     

Seafloor classification of the mound and channel provinces of the Porcupine Seabight: an application of the multibeam angular backscatter data

In this study multibeam angular backscatter data acquired in the eastern slope of the Porcupine Seabight are analysed. Processing of the angular backscatter data using the ‘NRGCOR’ software was made for 29 locations comprising different geological provinces like: carbonate mounds, buried mounds, seafloor channels, and inter-channel areas. A detailed methodology is developed to produce a map of angle-invariant (normalized) backscatter data by correcting the local angular backscatter values. The present paper involves detailed processing steps and related technical aspects of the normalization approach. The presented angle-invariant backscatter map possesses 12 dB dynamic range in terms of grey scale. A clear distinction is seen between the mound dominated northern area (Belgica province) and the Gollum channel seafloor at the southern end of the site. Qualitative analyses of the calculated mean backscatter values i.e., grey scale levels, utilizing angle-invariant backscatter data generally indicate backscatter values are highest (lighter grey scale) in the mound areas followed by buried mounds. The backscatter values are lowest in the inter-channel areas (lowest grey scale level). Moderate backscatter values (medium grey level) are observed from the Gollum and Kings channel data, and significant variability within the channel seafloor provinces. The segmentation of the channel seafloor provinces are made based on the computed grey scale levels for further analyses based on the angular backscatter strength. Three major parameters are utilized to classify four different seafloor provinces of the Porcupine Seabight by employing a semi-empirical method to analyse multibeam angular backscatter data. The predicted backscatter response which has been computed at 20° is the highest for the mound areas. The coefficient of variation (CV) of the mean backscatter response is also the highest for the mound areas. Interestingly, the slope value of the buried mound areas are found to be the highest. However, the channel seafloor of moderate backscatter response presents the lowest slope and CV values. A critical examination of the inter-channel areas indicates less variability within the estimated three parameters. Financial support of this study was granted by the European Commission Fifth Framework Project GEOMOUND (contract no. EVK3-CT-1999-00016).     

Transient simulations,empirical reconstructions and forcing mechanisms for the Mid-holocene hydrological climate in southern Patagonia

This study investigates the atmospheric circulation in transient climate simulations with a coupled atmosphere–ocean general circulation model (GCM) for the mid-Holocene (MH) period 7–4.5 ka BP driven with combinations of orbital, solar and greenhouse gas forcings. The focus is on southern South America. Statistical downscaling models are derived from observational data and applied to the simulations to estimate precipitation in south-eastern Patagonia during the MH. These estimates are compared with lake level estimates for Laguna Potrok Aike (LPA) from sediments. Relative to pre-industrial conditions (i.e. 1550–1850), which show extraordinarily high lake levels, the proxy-based reconstructed lake levels during the MH are lower. The downscaled simulated circulation differences indicate higher LPA precipitation during the MH from March to August, higher annual means, and reduced precipitation from September to February. Thus the reconstructed lower LPA lake levels can not be explained solely by the simulated precipitation changes. Possible reasons for this discrepancy are discussed. Based on proxy data from southern South America hypotheses have also been proposed on the latitudinal position of the southern hemispheric westerlies (SHWs). In agreement with some of these hypotheses our simulations show an increased seasonal cycle of the latitudinal position of the SHWs during the MH, which can be explained by the orbital forcing. The simulations also show stronger SHWs over southern Patagonia during austral summer and weaker SHWs during winter. The downscaling model associates weaker SHWs with increased precipitation in the LPA region. However, this relationship is only moderate, and therefore the downscaling model does not support the assumption of a strong link between mean SHWs and precipitation over south-eastern Patagonia, which is the basis of many proxy-based hypotheses about the SHWs.     

The surface energy balance and the mixing height in urban areas—activities and recommendations of COST-Action 715

The specific problems of determining and simulating the surface energy balance (SEB) and the mixing height (MH) over urban areas are examined. The SEB and MH are critical components of algorithms and numerical models for the urban boundary layer, though the constituent parts of the SEB and the MH are not routinely measured by national weather services. Parameterisations are thus needed in applications. In this investigation, several recently developed algorithms and models for estimating the SEB and MH were applied to new datasets and assessed. Results are discussed in terms of the need for spatial resolution and the parameters needed to describe the urban atmosphere. Limitations of models are identified and recommendations for further development and observations are given. Having identified gaps in knowledge, key findings from new urban experiments and numerical modelling for the SEB and MH are given. The diurnal cycle for the SEB is significantly different from rural conditions—urban heat storage is needed in urban parameterisations. The urban MH is increased over the rural MH, as shown by several numerical schemes and careful sodar analyses. This work has been carried out within the COST-715 Action “Meteorology applied to urban air pollution problems (1998–2004). COST 715 reached a consensus proposing representatively sited measurements of meteorological parameters and turbulent fluxes above roof-tops, and recognised that such data are needed to improve numerical models of the urban surface processes.     

Reworked Middle Jurassic sandstones as a marker for Upper Cretaceous basin inversion in Central Europe—a case study for the U–Pb detrital zircon record of the Upper Cretaceous Schmilka section and their implication for the sedimentary cover of the Lausitz Block (Saxony,Germany)

International Journal of Earth Sciences - The Saxonian–Bohemian Cretaceous Basin (Elbsandsteingebirge, E Germany and Czech Republic, Elbtal Group) comprises Upper Cretaceous sedimentary rocks...     

A ~565 Ma old glaciation in the Ediacaran of peri-Gondwanan West Africa

International Journal of Earth Sciences - In the Cadomian orogen of the NE Bohemian Massif and of SW Iberia, a post-Gaskiers glacial event dated at c. 565 Ma has been detected. Such...