Modeling of changes in thermal bioclimate: examples based on urban spaces in Freiburg, Germany

The Place of the Old Synagogue is a popular place in the city center of Freiburg, a medium-sized city in southwest Germany. It is going to be redesigned soon. In this paper the impact of urban street design and surface material on human thermal comfort is analyzed using the example of the Place of the Old Synagogue. The models SkyHelios, RayMan, and ENVI-met were applied to quantify and qualify the changes. All three models are freely available. Their combination allows analysis of development in long-term conditions, as well as changes in spatial distribution of thermal comfort, as well as of heat stress in summer. Results show that the models can provide valuable information. About the Place of the Old Synagogue, quantitative results show that the period with heat stress will become longer, while the intensity of heat stress increases. The spatial results show that the most significant changes are due to changes in shading. Nevertheless, an increase in thermal stress up to 10 °C is calculated for areas, where ground coverage changes from grass to pavement.     

The SFR and IMF of the galactic disk

There is a long term dynamical heating of stellar populations with age observed in the age – velocity dispersion – relation (AVR). This effect allows a determination of the star formation history SFR(t) from local kinematical data of main sequence stars. Using a self-consistent disk model for the vertical structure of the disk, we find from the kinematics of the stars in the solar neighbourhood that the SFR shows a moderate star burst about 10 Gyr ago followed by a continuous decline to the present day value consistent with the observed number of OB stars. The gravitational potential of the gas component and of the Dark Matter Halo is included and the effect of chemical enrichment, finite lifetime of the stars and mass loss of the stellar component are taken into account. The scale heights for main sequence stars together with the SFR is then used to determine constistently the IMF from the observed local luminosity function. The main new result is that the power law break in the present day mass function (PDMF) around 1 M _⊙ is entirely due to evolutionary effects of the disk and does not appear in the IMF. This revised version was published online in August 2006 with corrections to the Cover Date.     

Sulfurous acid (H2SO3) on Io?

Sulfurous acid (H₂SO₃) has never been characterized or isolated on Earth. This is caused by the unfavorable conditions for H₂SO₃ within Earth's atmosphere due to the high temperatures, the high water content and the oxidizing environment. Kinetic investigations by means of transition state theory showed that the half-life of H₂SO₃ at 300 K is 1 day but at 100 K it is increased to 2.7 billion years. Natural conditions to form H₂SO₃ presumably require cryogenic SO₂ or SO₂/H₂O mixtures and high energy proton irradiation at temperatures around 100 K. Such conditions can be found on the Jupiter moons Io and Europa. Therefore, we calculated IR-spectra of H₂SO₃ which we compared with Galileo's spectra of Io and Europa. From the available data we surmise that H₂SO₃ is present on Io and probably but to a smaller extent on Europa.     

Sedimentology of early Pliocene sandstones in the south-western Taiwan foreland: Implications for basin physiography in the early stages of collision

This work presents sedimentological observations and interpretations on three detailed sections of the Pliocene Yutengping/Ailiaochiao formations, deposited in the early stages of collision in Taiwan. Seven facies associations record paleoenvironments of deposition ranging from nearshore to lower offshore with a strong influence of tidal reworking, even in shelfal sub-tidal environments, and a pro-delta setting characterized by mass-flows. The association of shallow facies of the upper offshore to lower shoreface with pro-delta turbidite facies sourced in the orogen to the east suggests a peculiar setting in which turbidite deposition occurred below wave base but on the shelf, in water depths of probably less than 100 m. This adds to the examples of “shallow turbidites” increasingly commonly found in foreland basins and challenges the classical view of a “deep” early underfilled foreland basin. Time series analysis on tidal rhythmites allow us to identify a yearly signal in the form of periodic changes of sand-supply, energy and bioturbation that suggests a marked seasonality possibly affecting precipitation and sediment delivery as well as temperature. The Taiwan foreland basin may also present a potentially high-resolution record in shallow sediments of the early installation of monsoonal circulation patterns in east Asia. We confirm partly the paleogeography during the early stages of collision in Taiwan: the Chinese margin displayed a pronounced non-cylindrical geometry with a large basement promontory to the west in place of the modern Taiwan mountain range. Collision in Taiwan may have happened at once along the whole length of the modern mountain range, instead of progressively from north to south as classically considered.     

Ultra-Deep Optical Spectroscopy with PMAS. Using the Nod-and-Shuffle Technique

PMAS, the Potsdam Multi-Aperture Spectrophotometer, is a new integral field spectrograph in the optical, which is optimized for good transmission and high image quality from 350 nm to 1 μm. We present our plan to implement a CCD charge-shuffle mode to allow for beam switching with a very high degree of sky subtraction accuracy for faint object 3-D spectroscopy. This revised version was published online in July 2006 with corrections to the Cover Date.     

A Raman spectroscopic study on the structural disorder of monazite–(Ce)

This study addresses whether Raman spectra can be used to estimate the degree of accumulated radiation damage in monazite-(Ce) samples whose chemical composition was previously determined. Our results indicate that the degree of disorder in monazite–(Ce), as observed from increasing Raman band broadening, generally depends on both the structural state (i.e., radiation damage) and the chemical composition (i.e., incorporation of non-formula elements). The chemical effects were studied on synthetic orthophosphates grown using the Li-Mo flux method, and non radiation-damaged analogues of the naturally radiation-damaged monazite–(Ce) samples, produced by dry annealing. We found that the “chemical” Raman-band broadening of natural monazite–(Ce) can be predicted by the empirical formula, $$ {\hbox{FWHM}} {\hbox{[c}}{{\hbox{m}}^{ - {1}}}{]} = {3}{.95} + {26}{.66} \times {\hbox{(Th}} + {\hbox{U}} + {\hbox{Ca}} + {\hbox{Pb)}} {\hbox{[apfu]}} $$ where, FWHM = full width at half maximum of the main Raman band of monazite–(Ce) (i.e., the symmetric PO₄ stretching near 970?cm^?1), and (Th+U+Ca+Pb) = sum of the four elements in apfu (atoms per formula unit). Provided the chemical composition of a natural monazite–(Ce) is known, this “chemical band broadening” can be used to estimate the degree of structural radiation damage from the observed FWHM of the ν₁(PO₄) band of that particular sample using Raman spectroscopy. Our annealing studies on a wide range of monazite–(Ce) reference materials and other monazite–(Ce) samples confirmed that this mineral virtually never becomes highly radiation damaged. Potential advantages and the practical use of the proposed method in the Earth sciences are discussed.     

Assessing the Vibrational Frequencies of the Cathedral of Cologne (Germany) by Means of Ambient Seismic Noise Analysis

Ambient seismic noise measurements were conducted inside the Cathedral of Cologne (Germany) for assessing its frequencies of vibration and for checking whether these occur in the range where soil amplification is expected. If this is the case, damages may increase in case of an earthquake due to an increased structural response of the building. Analysis of the ratio between the horizontal and vertical components of the spectra recorded at stations located inside the building as well as the ratio between the corresponding components of the spectra recorded simultaneously inside the building and at a reference station placed in the basement of the cathedral indicated several modes of vibration. Facilitated by these results an assessment of the seismic vulnerability was attempted for a 2D ground motion scenario using the finite element method.     

Element signatures of subduction-zone fluids. An experimental study of the element partitioning (Dfluid/rock) of natural partly altered igneous rocks from the ODP drilling site 1,256

The trace element signatures of fluids were investigated by leaching experiments on natural samples of partly altered mafic igneous rocks recovered from the drilling site 1,256 of ODP Leg 206 on the Cocos plate (Central America). Experiments with ultrapure water were performed at 400 °C/0.4 GPa and 500 °C/0.7 GPa. Both fluids and residual solids were examined to obtain the partition coefficients (D^fluid/rock) of various trace elements. Element partition coefficients (D^fluid/rock) obtained at 500 °C/0.7 GPa are significantly lower compared to results obtained at 400 °C/0.4 GPa, which is in contrast to observations at higher pressures (2.2–6 GPa) and temperatures between 700 and 1,400 °C (Kessel et al. in Earth Planet Sci Lett 237: 873–892, 2005a; Spandler et al. in Chem Geol 239: 228–249, 2007). This finding may indicate a considerable pressure effect on the leaching processes and strongly divergent fluid–rock interactions in the upper part of a subduction zone at 0.4–0.7 GPa compared to deeper subduction areas with higher pressures. Furthermore, this may be interpreted as one of the earliest fractionation processes during the subduction of crustal material.     

What Can be Expected from the GRACE-FO Laser Ranging Interferometer for Earth Science Applications?

The primary objective of the gravity recovery and climate experiment follow-on (GRACE-FO) satellite mission, due for launch in August 2017, is to continue the GRACE time series of global monthly gravity field models. For this, evolved versions of the GRACE microwave instrument, GPS receiver, and accelerometer will be used. A secondary objective is to demonstrate the effectiveness of a laser ranging interferometer (LRI) in improving the satellite-to-satellite tracking measurement performance. In order to investigate the expected enhancement for Earth science applications, we have performed a full-scale simulation over the nominal mission lifetime of 5 years using a realistic orbit scenario and error assumptions both for instrument and background model errors. Unfiltered differences between the synthetic input and the finally recovered time-variable monthly gravity models show notable improvements with the LRI, on a global scale, of the order of 23 %. The gain is realized for wavelengths smaller than 240 km in case of Gaussian filtering but decreases to just a few percent when anisotropic filtering is applied. This is also confirmed for some typical regional Earth science applications which show randomly distributed patterns of small improvements but also degradations when using DDK4-filtered LRI-based models. Analysis of applied error models indicates that accelerometer noise followed by ocean tide and non-tidal mass variation errors are the main contributors to the overall GRACE-FO gravity model error. Improvements in these fields are therefore necessary, besides optimized constellations, to make use of the increased LRI accuracy and to significantly improve gravity field models from next-generation gravity missions.