Complexity and non‐linearity in earth surface processes – concepts,methods and applications

Complexity has long been recognized and is increasingly becoming mainstream in geomorphology. However, the relative novelty of various concepts and techniques associated to it means that ambiguity continues to surround complexity. In this commentary, we present and discuss a variety of recent contributions that have the potential to help clarify issues and advance the use of complexity in geomorphology. Copyright © 2015 John Wiley & Sons, Ltd.     

An advanced signal processing technique for deriving grain size information of bedload transport from impact plate vibration measurements

A reliable characterization of bedload transport is required to gauge the engineering and theoretical issues related to the dynamics of sediments transport in rivers. However, while significant advances have been made in the development of monitoring techniques, robust quantitative predictive relationships have proven difficult to derive. In this article, we develop a dedicated signal processing technique aimed at improving the usage of impact plate measurements for material transport characterization. Our set‐up consists of a piezoelectric hydrophone mounted on the bottom side of a stainless steel plate, thus acting as a ‘sediment vibration sensor’. While the classical analysis with such systems is usually limited to rather simple procedures, such as impact counting, a large amount of useful information is contained in the actual waveform of the impact signal, which conveys the force and the contact time that the bedload imposes on the plate. An advanced signal processing technique called ‘first arrival atomic decomposition’ is used to improve the characterization of bedload transport by analysing the amplitude and frequency attributes of each single impact. This new processing approach proves to be well suited for bedload transport monitoring using plate systems and allows us to establish a relationship between the median grain size (D₅₀) and the impact signal properties. This link is first observed and validated with controlled flume experiments and then applied to continuous impact records in a small gravel‐bed river during a flood event. The estimated D₅₀ offers a novel possibility to observe the time‐varying grain size distribution of bedload transport. Copyright © 2014 John Wiley & Sons, Ltd.     

Sensitivity of the Atlantic Ocean circulation to a hydraulic overflow parameterisation in a coarse resolution model: Response of the subpolar gyre

We investigate the sensitivity of a coarse resolution coupled climate model to the representation of the overflows over the Greenland–Scotland ridge. This class of models suffers from a poor representation of the water mass exchange between the Nordic Seas and the North Atlantic, a crucial part of the large-scale oceanic circulation. We revisit the explicit representation of the overflows using a parameterisation by hydraulic constraints and compare it with the enhancement of the overflow transport by artificially deepened passages over the Greenland–Scotland ridge, a common practice in coarse resolution models. Both configurations increase deep water formation in the Nordic Seas and represent the large-scale dynamics of the Atlantic realistically in contrast to a third model version with realistic sill depths but without the explicit overflow transport. The comparison of the hydrography suggests that for the unperturbed equilibrium the Nordic Seas are better represented with the parameterised overflows. As in previous studies, we do not find a stabilising effect of the overflow parameterisation on the Atlantic meridional overturning circulation but merely on the overflow transport. As a consequence the surface air temperature in the Nordic Seas is less sensitive to anomalous surface fresh water forcing.Special attention is paid to changes in the subpolar gyre circulation. We find it sensitive to the overflow transport and the density of these water masses through baroclinic adjustments. The analysis of the governing equations confirms the presence of positive feedbacks inherent to the subpolar gyre and allows us to isolate the influence of the overflows on its dynamics.     

Chondritic ingredients: II. Reconstructing early solar system history via refractory lithophile trace elements in individual objects of the Leoville CV3 chondrite

We performed a LA-ICP-MS study of refractory lithophile trace elements in 32 individual objects selected from a single section of the reduced CV3 chondrite Leoville. Ingredients sampled include ferromagnesian type I and II chondrules, Al-rich chondrules (ARCs), calcium-aluminum-rich inclusions (CAIs), a single amoeboid olivine aggregate (AOA), and matrix. The majority of rare earth element (REE) signatures identified are either of the category “group II” or they are relatively flat, i.e., more or less unfractionated. Data derived for bulk Leoville exhibit characteristics of the group II pattern. The bulk REE inventory is essentially governed by those of CAIs (group II), ARCs (flat or group II), type I chondrules (about 90% flat, 10% group II), and matrix (group II). Leoville matrix also shows a superimposed positive Eu anomaly. The excess in Eu is possibly due to terrestrial weathering. The group II pattern, however, testifies to volatility-controlled fractional condensation from a residual gas of solar composition at still relatively high temperature. In principle, this signature (group II) is omnipresent in all types of constituents, suggesting that the original REE carrier of all components was CAI-like dust. In addition, single-element anomalies occasionally superimposing the group II signature reveal specific changes in redox conditions. We also determined the bulk chemical composition of all objects studied. For Mg/Si, Mg/Fe, and Al/Ca, Leoville's main ingredients—type I chondrules and matrix—display a complementary relationship. Both components probably formed successively in the same source region.     

Chemical evolution of waters during long term interaction with granitic rocks in northern Switzerland

As part of an assessment of crystalline rock as a potential host for a nuclear waste repository, water samples were collected from more than 50 locations from the crystalline basement where it is under sedimentary cover in Northern Switzerland and where it is at the surface in the Black Forest. These samples describe the changing chemistry of water in an extended flow system from dilute recharge waters far from chemical equilibrium with its host rock to saline waters at temperatures of 50 to 100°C with residence times far in excess of 105 a that have reached chemical equilibrium with their host rock.This unique set of samples allows an analysis of the chemical evolution of granitic waters from surficial waters far from equilibrium to almost equilibrated waters. Mobile ions, rare gases and isotopic data are used to estimate the extent of reaction between waters and their host rock. The evolution of controlled elements is interpreted as a function of this extent of reaction. Silica contents correspond to approximate equilibrium even in the recharge waters. The relative concentrations of Ca and especially Mg are significantly lower in the borehole waters than in recharge waters indicating a trend towards equilibrium. The Na/K ratios correspond to equilibrium only in the most evolved, older, waters which are shown to be at full equilibrium.     

Investigating the shock histories of lunar meteorites Miller Range 090034, 090070, and 090075 using petrography,geochemistry, and micro‐FTIR spectroscopy

Fourier transform infrared (FTIR) spectroscopy and cathodoluminescence (CL) imaging techniques, combined with electron microprobe analyses, have been used to determine the physical state of feldspathic phases that have been subject to varying levels of shock in the grouped lunar meteorites Miller Range 090034, 090070, and 090075. Six feldspathic phases have been identified based on spectral, textural, and chemical properties. A specific infrared wavelength band ratio (1064/932 cm^?1 equivalent to 9.40/10.73 μm), chosen because it can distinguish between some of the feldspathic phases, can be used to estimate the pressure regimes experienced by these phases. In addition, FTIR spatial mapping capabilities allow for visual comparison of variably shocked phases within the samples. By comparing spectral and compositional data, the origin and shock history of this lunar meteorite group has been determined, with each of the shocked feldspathic phases being related to events in its geological evolution. As such, we highlight that FTIR spectroscopy can be easily employed to identify shocked feldspathic phases in lunar samples; estimate peak shock pressures; and when compared with chemical data, can be used to investigate their shock histories.