Molecular stable carbon isotope compositions of alkylphenanthrenes in coals and marine shales related to source and maturity

Phenanthrene (PHE) and methylphenanthrenes (MPs) extracted from coaly shale and coal samples containing terrestrial organic matter are compared with the same compounds from marine shales in terms of yields and δ¹³C values at marginally to fully mature stages of thermal evolution. The shales derived from four boreholes in the Hils Half-Graben area, northwestern Germany, were shown to be representative of a greater number of samples from the same sites. The δ¹³C values of extractable PHE and MPs are less negative in the terrestrial (−24.3 to −26.0‰) than in the marine (−28.8 to −30.5‰) samples. Since these values are unrelated to mean vitrinite reflectance (R_r) values in the range of 0.5–0.9%, it appears that the stable carbon isotope composition of PHE and MPs is controlled by organic matter type rather than maturity.     

Groundwater utilization through the centuries focusing οn the Hellenic civilizations

Groundwater has been utilized since the Prehistoric times. Water supply of some Minoan settlements on the eastern side of the island of Crete (Greece) was based on groundwater. Later on, many wells were constructed in several areas of Greece and their use expanded through subsequent periods. The greatest achievement in groundwater exploitation by ancient Greeks was the construction of long underground galleries or qanats, which collected water from springs and alluvial deposits. In Classical times, most of the wells were on private properties and their owners were forced by regulations to maintain the wells in good condition and ready for use in wartime. During that period, the first scientific theories of Aristotle and Theophrastus were developed in regards to hydrological phenomena, and the processes involved in the formation of surface water and groundwater were clarified. Wells played a major part in urban water supply during the Roman period, in which famous aqueducts were constructed to transfer water; however, several regions of Greece were self-sufficient in water, supplied by many wells from the Prehistoric to the Byzantine period. People understood the local geological conditions and, according to their culture, constructed and managed their own types of wells. In addition to the wells and aqueducts, the hydraulic technology included cisterns to store rainwater, and systems to capture spring water for transport by aqueducts. The examples of hydro-technologies and water management practices described in this paper may have some relevance for water engineering even in modern times.     

Depositional architecture and evolution of progradationally stacked lobe complexes in the Eocene Central Basin of Spitsbergen

The down‐dip portion of submarine fans comprises terminal lobes that consist of various gravity flow deposits, including turbidites and debrites. Within lobe complexes, lobe deposition commonly takes place in topographic lows created between previous lobes, resulting in an architecture characterized by compensational stacking. However, in some deep water turbidite systems, compensational stacking is less prominent and progradation dominates over aggradation and lateral stacking. Combined outcrop and subsurface data from the Eocene Central Basin of Spitsbergen provide a rare example of submarine fans that comprise progradationally stacked lobes and lobe complexes. Evidence for progradation includes basinward offset stacking of successive lobe complexes, a vertical change from distal to proximal lobe environments as recorded by an upward increase in bed amalgamation, and coarsening and thickening upward trends within the lobes. Slope clinoforms occur immediately above the lobe complexes, suggesting that a shelf‐slope system prograded across the basin in concert with deposition of the lobe complexes. Erosive channels are present in proximal axial lobe settings, whereas shallow channels, scours and terminal lobes dominate further basinward. Terminal lobes are classified as amalgamated, non‐amalgamated or thin‐bedded, consistent with turbidite deposition in lobe axis, off‐axis and fringe settings, respectively. Co‐genetic turbidite–debrite beds, interpreted as being deposited from hybrid sediment gravity flows which consisted of both turbulent and laminar flow phases, occur frequently in lobe off‐axis to fringe settings, and are rare and poorly developed in channels and axial lobe environments. This indicates bypass of the laminar flow phase in proximal settings, and deposition in relative distal unconfined settings. Palaeocurrent data indicate sediment dispersal mainly towards the east, and is consistent with slope and lobe complex progradation perpendicular to the NNW–SSE trending basin margin.     

笔石、几丁虫和虫牙反射率在热成熟度上的应用

根据中国湖北黄陵背斜周缘11条奥陶纪、志留纪地层剖面的笔石,几丁虫和虫牙反射率的研究,结合相同或邻近层位牙形石色变指数(CAI)和分散有机质成熟度的红外光谱鉴定,进一步证明:笔石、几丁虫和虫牙的反射率具有随成熟度增加而增加的特点以及各自不同的反射率径迹,因此,在不含镜质组的前泥盆纪地层中,它们可以作为热成熟度的指示。笔石具有明显的各向异性的光学特点,在平行层面所切笔石光面上测量笔石最大油浸反射率,对确定含化石母岩的成熟度最为合适。几丁虫和虫牙具有各向同性的光性特点,因而它们的光面仅显示反射率而无双反射率。笔石、几丁虫和虫牙反射率分布趋势的分析表明,可以将本区奥陶系与志留系划分为3个成熟度区。并对各区形成油气的潜在可能性进行了讨论,其结果与牙形石色变指数和有机质红外光谱分析,所证明的区域有机质成熟度分布模式基本一致。     

Cr isotopes in physically separated components of the Allende CV3 and Murchison CM2 chondrites: Implications for isotopic heterogeneity in the solar nebula and parent body processes

Chromium isotopic data of physically separated components (chondrules, CAIs, variably magnetic size fractions) of the carbonaceous chondrites Allende and Murchison and bulk rock data of Allende, Ivuna, and Orgueil are reported to evaluate the origin of isotopic heterogeneity in these meteorites. Allende components show ε⁵³Cr and ε⁵⁴Cr from ?0.23 ± 0.07 to 0.37 ± 0.05 and from ?0.43 ± 0.08 to 3.7 ± 0.1, respectively. In components of Murchison, ε⁵³Cr and ε⁵⁴Cr vary from ?0.06 ± 0.08 to 0.5 ± 0.1 and from 0.7 ± 0.2 to 1.7 ± 0.1, respectively. The non‐systematic variations of ε⁵³Cr and ⁵⁵Mn/⁵²Cr in the components of Allende and Murchison were likely caused by small‐scale, alteration‐related redistribution of Mn >20 Ma after formation of the solar system. Chondrule fractions show the lowest ⁵⁵Mn/⁵²Cr and ε⁵⁴Cr values of all components, consistent with evaporation of Mn and ε⁵⁴Cr‐rich carrier phases from chondrule precursors. Components other than the chondrules show higher Mn/Cr and ε⁵⁴Cr, suggestive of chemical and isotopic complementarity between chondrules and matrix‐rich fractions. Bulk rock compositions calculated based on weighted compositions of components agree with measured Cr isotope data of bulk rocks, in spite of the Cr isotopic heterogeneity reported by the present and previous studies. This indicates that on a sampling scale comprising several hundred milligrams, these meteorites sampled isotopically and chemically homogeneous nebular reservoirs. The linear correlation of ⁵⁵Mn/⁵²Cr with ε⁵³Cr in bulk rocks likely was caused by variable fractionation of Mn/Cr, subsequent mixing of phases in nebular domains, and radiogenic ingrowth of ⁵³Cr.     

Oxygen isotope systematics of chondrule olivine,pyroxene, and plagioclase in one of the most pristine CV3Red chondrites (Northwest Africa 8613)

We performed in situ oxygen three‐isotope measurements of chondrule olivine, pyroxenes, and plagioclase from the newly described CV_Red chondrite NWA 8613. Additionally, oxygen isotope ratios of plagioclase in chondrules from the Kaba CV3_OxB chondrite were determined to enable comparisons of isotope ratios and degree of alteration of chondrules in both CV lithologies. NWA 8613 was affected by only mild thermal metamorphism. The majority of oxygen isotope ratios of olivine and pyroxenes plot along a slope‐1 line in the oxygen three‐isotope diagram, except for a type II and a remolten barred olivine chondrule. When isotopic relict olivine is excluded, olivine, and low‐ and high‐Ca pyroxenes are indistinguishable regarding Δ¹⁷O values. Conversely, plagioclase in chondrules from NWA 8613 and Kaba plot along mass‐dependent fractionation lines. Oxygen isotopic disequilibrium between phenocrysts and plagioclase was caused probably by exchange of plagioclase with ¹⁶O‐poor fluids on the CV parent body. Based on an existing oxygen isotope mass balance model, possible dust enrichment and ice enhancement factors were estimated. Type I chondrules from NWA 8613 possibly formed at moderately high dust enrichment factors (50× to 150× CI dust relative to solar abundances); estimates for water ice in the chondrule precursors range from 0.2× to 0.6× the nominal amount of ice in dust of CI composition. Findings agree with results from an earlier study on oxygen isotopes in chondrules of the Kaba CV chondrite, providing further evidence for a relatively dry and only moderately high dust‐enriched disk in the CV chondrule‐forming region.     

On the dynamics of the satellite galaxies in NGC 5044

The NGC 5044 galaxy group is dominated by a luminous elliptical galaxy that is surrounded by ∼160 dwarf satellites. The projected number density profile of this dwarf population deviates within ∼1/3 of the virial radius from a projected Navarro, Frenk and White (NFW) profile, which is assumed to approximate the underlying total matter distribution. By means of a semi-analytic model, we demonstrate that the interplay between gravitation, dynamical friction and tidal mass loss and destruction can explain the observed number density profile. We use only two parameters in our models: the total to stellar mass fraction of the satellite haloes and the disruption efficiency. The disruption efficiency is expressed by a minimum radius. If the tidal radius of a galaxy (halo) falls below this radius, it is assumed to become unobservable. The preferred parameters are an initial total to stellar mass fraction of ∼20 and a disruption radius of  4 kpc  . In that model, about 20 per cent of all the satellites are totally disrupted on their orbits within the group environment. Dynamical friction is less important in shaping the inner slope of the number density profile because the reduction in mass by tidal forces lowers the impact of the friction term. The main destruction mechanism is tide. In the preferred model, the total B -band luminosity of all disrupted galaxies is about twice the observed luminosity of the central elliptical galaxy, indicating that a significant fraction of stars are scattered into the intragroup medium. Dwarf galaxy satellites closer to the centre of the NGC 5044 group may exhibit optical evidence of partial tidal disruption. If dynamical friction forces the satellite to merge with the central elliptical, the angular momentum of the satellite tends to be removed at the apocentre passage. Afterwards, the satellite drops radially towards the centre.     

The Creston,California, meteorite fall and the origin of L chondrites

It has been proposed that all L chondrites resulted from an ongoing collisional cascade of fragments that originated from the formation of the ~500 Ma old asteroid family Gefion, located near the 5:2 mean‐motion resonance with Jupiter in the middle Main Belt. If so, L chondrite pre‐atmospheric orbits should be distributed as expected for that source region. Here, we present contradictory results from the orbit and collisional history of the October 24, 2015, L6 ordinary chondrite fall at Creston, CA (here reclassified to L5/6). Creston's short 1.30 ± 0.02 AU semimajor axis orbit would imply a long dynamical evolution if it originated from the middle Main Belt. Indeed, Creston has a high cosmic ray exposure age of 40–50 Ma. However, Creston's small meteoroid size and low 4.23 ± 0.07° inclination indicate a short dynamical lifetime against collisions. This suggests, instead, that Creston originated most likely in the inner asteroid belt and was delivered via the ν₆ resonance. The U‐Pb systematics of Creston apatite reveals a Pb‐Pb age of 4,497.1 ± 3.7 Ma, and an upper intercept U‐Pb age of 4,496.7 ± 5.8 Ma (2σ), circa 70 Ma after formation of CAI, as found for other L chondrites. The K‐Ar (age ~4.3 Ga) and U,Th‐He (age ~1 Ga) chronometers were not reset at ~500 Ma, while the lower intercept U‐Pb age is poorly defined as 770 ± 320 Ma. So far, the three known L chondrites that impacted on orbits with semimajor axes a <2.0 AU all have high (>3 Ga) K‐Ar ages. This argues for a source of some of our L chondrites in the inner Main Belt. Not all L chondrites originate in a continuous population of Gefion family debris stretching across the 3:1 mean‐motion resonance.     

Internal heating and thermal emission from old neutron stars

The equilibrium composition of neutron star matter is achieved through weak interactions (direct and inverse beta decays), which proceed on relatively long time scales. If the density of a matter element is perturbed, it will relax to the new chemical equilibrium through non-equilibrium reactions, which produce entropy that is partly released through neutrino emission, while a similar fraction heats the matter and is eventually radiated as thermal photons. We examined two possible mechanisms causing such density perturbations: (1) the reduction in centrifugal force caused by spin-down (particularly in millisecond pulsars), leading to rotochemical heating, and (2) a hypothetical time-variation of the gravitational constant, as predicted by some theories of gravity and current cosmological models, leading to gravitochemical heating. If only slow weak interactions are allowed in the neutron star (modified Urca reactions, with or without Cooper pairing), rotochemical heating can account for the observed ultraviolet emission from the closest millisecond pulsar, PSR J0437-4715, which also provides a constraint on |dG/dt| of the same order as the best available in the literature. This work made use of NASA’s Astrophysics Data System Service, and received financial support from FONDECYT through regular grants 1020840 and 1060644.