Impact of drilling mud on chemistry and microbiology of an Upper Triassic groundwater after drilling and testing an exploration well for aquifer thermal energy storage in Berlin (Germany)

After completion of an exploration well, sandstones of the Exter Formation were hydraulically tested to determine the hydraulic properties and to evaluate chemical and microbial processes caused by drilling and water production. The aim was to determine the suitability of the formation as a reservoir for aquifer thermal energy storage. The tests revealed a hydraulic conductivity of 1–2 E-5 m/s of the reservoir, resulting in a productivity index of 0.6–1 m³/h/bar. A hydraulic connection of the Exter Formation to the overlaying, artesian “Rupelbasissand” cannot be excluded. Water samples were collected for chemical and microbiological analyses. The water was similarly composed as sea water with a maximum salinity of 24.9 g/L, dominated by NaCl (15.6 g/L Cl and 7.8 g/L Na). Until the end of the tests, the water was affected by drilling mud as indicated by the high pH (8.9) and high bicarbonate concentration (359 mg/L) that both resulted from the impact of sodium carbonate (Na₂CO₃) additives. The high amount of dissolved organic matter (>?58 mg/L) and its molecular-weight distribution pattern indicated that residues of cellulose, an ingredient of the drilling mud, were still present at the end of the tests. Clear evidence of this contamination gave the measured uranine that was added as a tracer into the drilling mud. During fluid production, the microbial community structure and abundance changed and correlated with the content of drilling mud. Eight taxa of sulfate-reducing bacteria, key organisms in processes like bio-corrosion and bio-clogging, were identified. It can be assumed that their activity will be affected during usage of the reservoir.     

Origin of complex zoning in olivine from diverse,diamondiferous kimberlites and tectonic settings: Ekati (Canada), Alto Paranaiba (Brazil) and Kaalvallei (South Africa)

Olivine in kimberlites can provide unique insights into magma petrogenesis, because it is the most abundant xenocrystic phase and a stable magmatic product over most of the liquid line of descent. In this study we examined the petrography and chemistry of olivine in kimberlites from different tectonic settings, including the Slave craton, Canada (Ekati: Grizzly, Koala), the Brasilia mobile belt (Limpeza-18, Tres Ranchos-04), and the Kaapvaal craton, South Africa (Kaalvallei: Samada, New Robinson). Olivine cores display a wide range of compositions (e.g., Mg# = 78–95). The similarity in olivine composition, resorption of core zones and inclusions of mantle-derived phases, indicates that most olivine cores originated from the disaggregation of mantle peridotites, including kimberlite-metasomatised lithologies (i.e. sheared lherzolites and megacrysts). Olivine rims typically show a restricted range of Mg#, with decreasing Ni and increasing Mn and Ca contents, a characteristic of kimberlitic olivine worldwide. The rims host inclusions of groundmass minerals, which implies crystallisation just before and/or during emplacement. There is a direct correlation between olivine rim composition and groundmass mineralogy, whereby high Mg/Fe rims are associated with carbonate-rich kimberlites, and lower Mg/Fe rims are correlated with increased phlogopite and Fe-bearing oxide mineral abundances. There are no differences in olivine composition between explosive (Grizzly) and hypabyssal (Koala) kimberlites. Olivine in kimberlites also displays transitional zones and less common internal zones, between cores and rims. The diffuse transitional zones exhibit intermediate compositions between cores and rims, attributed to partial re-equilibration of xenocrystic cores with the ascending kimberlite melt. In contrast, internal zones form discrete layers with resorbed margins and restricted Mg# values, but variable Ni, Mn and Ca concentrations, which indicates a discrete crystallization event from precursor kimberlite melts at mantle depths. Overall, olivine exhibits broadly analogous zoning in kimberlites worldwide. Variable compositions for individual zones relate to different parental melt compositions rather than variations in tectonic setting or emplacement mechanism.

     

A record of Lateglacial/Holocene environmental change from a high‐elevation site in the Intermountain West,USA

Records of past vegetation and fire history can be complicated by changes in the depositional environment of a sampling location. However, these changes can alternatively be used as a measure of climate variability. Our study site, ca. 18.0 cal. ka BP record from Little Brooklyn Lake, Wyoming, located near the crest of the Snowy Range, records three moisture states. Initially, the lake was likely a glacier‐fed pond indicated by the presence of Pediastrum algae colonies. Around 13.0 cal. ka BP this pond transitioned to a meadow environment, suggested by the loss of Pediastrum algae colonies and slow sedimentation rates. Meadow conditions were maintained until ca. 5.0 cal. ka BP when Pediastrum algae colony abundance increased,indicating the formation of a shallow lake. From 18.0 to ca. 5.0 cal. ka BP, the pollen record is suggestive of alpine vegetation conditions with relatively high spruce and herbaceous taxa. Low charcoal influx also characterizes the period between 18.0 and 5.0 cal. ka BP. After 5.0 cal. ka BP, the coincidence of the formation of shallow lake and pollen data, indicating a shift to a spruce and fir forest, suggests an increase in effective moisture. Fire remained rare in this basin over the entire record, however, once the lake established sedimentation rates and charcoal influx increased. Copyright © 2013 John Wiley & Sons, Ltd.     

Syn-thrust deformation across a transverse zone: the Grem–Vedra fault system (central Southern Alps, N Italy)

The lateral continuity of the E?CW trending thrust sheets developed within the Lower to Middle Triassic cover of the central Southern Alps (Orobic belt) is disturbed by the occurrence of several N?CS trending transverse zones, such as the poorly known Grem?CVedra Transverse Zone (GVTZ). The GVTZ developed during the emplacement of the up to six S-verging thrust sheets consisting of Lower to Middle Triassic units, occurring immediately south of the Orobic Anticlines. The transverse zone, active during thrust emplacement related to the early Alpine compressions which pre-date the Adamello intrusion, includes three major vertical shear zones, the Grem, Pezzel and Zuccone faults. The major structure of the transverse zone is the dextral Grem fault, forming a deep lateral ramp between thrust sheets 3 and 5. A similar evolution also occurred along the Zuccone and Pezzel faults, which show a left-lateral displacement of syn-thrust folds. The Grem fault was later reactivated as an oblique tear fault during the emplacement of the Orobic Anticlines, due to back-thrusting along out-of-sequence thrust surfaces (Clusone fault). Transpressional deformations along the fault zone are recorded by the rotation of major syn-thrust folds, which also suggest a horizontal offset close to 0.5?km. Records of the first stage of evolution of the Grem fault are better preserved along its northern segment, and structural relationships suggest that it propagated southward and downward in the growing thrust stack. The study of the meso and megascopic structures developed along the GVTZ constrains the evolution of the transverse zone, illustrating the complex deformational phenomena occurring in a transpressional regime. The GVTZ probably reflects the existence of pre-existing tectonic lineaments with a similar orientation. Evidence of pre-existing structures are not preserved in the exposed units, nevertheless the N?CS extensional fault systems that characterize the Norian to Jurassic rifting history of the Lombardian basin are valid candidates.     

Comparison of ladderane phospholipid and core lipids as indicators for anaerobic ammonium oxidation (anammox) in marine sediments

We investigated anaerobic ammonium oxidation (anammox) in continental shelf and slope sediments of the Irish and Celtic Seas by using anammox specific ladderane biomarker lipids. We used the presence of an intact ladderane phospholipid as a direct indicator for living anammox bacteria, and compared it with the abundance of ladderane core lipids derived from both living and dead bacterial biomass. All investigated sediments contained ladderane core lipids as well as the intact ladderane phospholipid, in agreement with ¹⁵N-labeling experiments, which revealed anammox activity at all sites. Ladderane core lipid and intact ladderane phospholipid concentrations were significantly correlated (R² = 0.957 and 0.464, respectively) with anammox activity over the transect of the continental shelf and slope sediments. In the Irish Sea (50-100 m water depth) highest abundances of the intact ladderane phospholipid were found in the upper 2 cm of the sediment, indicating a zone of active anammox. A sharp decline further down-core suggested a strong decrease in anammox biomass and rapid degradation of the intact lipids. In comparison, ladderane core lipids were 1-2 orders of magnitude higher in concentration than the intact ladderane phospholipid and accumulated as dead cell remnants with depth. In the slope sediments of the Celtic Sea both ladderane core lipids and the intact ladderane phospholipid were found in sediments at water depths ranging from 500 to 2000 m. Here, anammox seemed to be active at greater depths of the sediment (>2 cm). Mean abundances of both intact and core ladderane lipids in whole sediment cores increased downslope, indicating an increasing importance of anammox in deeper slope sediments.     

Severe weather affecting European transport systems: the identification,classification and frequencies of events

Severe weather can have serious repercussions in the transport sector as a whole by increasing the number of accidents, injuries and other damage, as well as leading to highly increased travel times. This study, a component of the EU FP7 Project EWENT, delineates a Europe-wide climatology of adverse and extreme weather events that can be expected to affect the transport network. We first define and classify the relevant severe weather events by investigating the effects of hazardous conditions on different transportation modes and the infrastructure. Consideration is given to individual phenomena such as snowfall, heavy precipitation, heat waves, cold spells, wind gusts; a combined phenomenon, the blizzard, is also considered. The frequency of severe weather events, together with the changes in their spatial extension and intensity, is analyzed based on the E-OBS dataset (1971–2000) and the ERA-Interim reanalysis dataset (1989–2010). Northern Europe and the Alpine region are the areas most impacted by winter extremes, such as snowfall, cold spells and winter storms, the frequency of heavy snowfall. The frequency of hot days is highest in Southern Europe. Severe winds and blizzards are the most common over the Atlantic and along its shores. Although heavy rainfall may affect the whole continent on an annual basis, extreme precipitation events are relative sparse, affecting particularly the Alps and the Atlantic coastline. A European regionalization covering similar impacts on the transport network is performed.     

Engineering geomorphological characterisation of the Vajont Slide,Italy, and a new interpretation of the chronology and evolution of the landslide

Although the 1963 Vajont Slide in Italy has been extensively studied for over 50 years, its regional geological and geomorphological context has been neglected. In this paper, we use field observations and remote sensing data to elucidate the interaction between endogenic and exogenic processes that brought the north slope of Monte Toc to failure. We present the first detailed pre- and post-failure engineering geomorphology maps of the slide area. The maps delineate two main landslide blocks, several sub-blocks, compressional and extensional zones, and secondary failures in the deposit. The maps provide new insights into the kinematics, dynamics and evolution of the slide. Finally, we discuss the origin of Vajont Gorge and a prehistoric failure that occurred at the same location as the 1963 slide. We propose, as part of a newly developed multi-stage landscape evolution sequence, that the prehistoric failure was a deep-seated gravitational slope deformation (sackung) that initiated during deglaciation and continued to slowly move until the catastrophic failure in 1963. We argue that the gorge was created by these deep-seated slow movements.     

Holocene climate variability in Sicily from a discontinuous stalagmite record and the Mesolithic to Neolithic transition

Fabric and stable isotopic composition of a Holocene stalagmite (CR1) from a cave in northern Sicily record changes in paleorainfall in the early Holocene. High δ¹³C stable isotope values in the calcite deposited from ca. 8500 to ca. 7500 yr ago are interpreted as reflecting periods of high rainfall. The wet phase was interrupted by two periods of multi-century duration characterized by relatively cool and dry winters centered at ca. 8200 and ca. 7500 yr ago, highlighted by low δ¹³C and δ¹⁸O values. A high variability of δ¹³C values is recorded from ca. 7500 to ca. 6500 yr ago and indicates that the transition from a pluvial early Holocene to the present-day climate conditions was punctuated by decadal-scale periods of relatively dry winters. In northern Sicily, the traditional elements of the Neolithic appear at ca. 7700 yr ago. It is possible that changes in rainfall influenced the passage from hunter-gathering to farming and sheep-herding economies.     

Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.