Chondritic ingredients: I. Usual suspects and some oddballs in the Leoville CV3 meteorite

Abstract– Reduced CV3 chondrites are relatively pristine rocks and prime candidates for studies exploring processes that predated planet formation. We closely examined the petrographic features and trace elemental composition of different CV3 constituents in the accretionary breccia Leoville. The petrographic results are presented here. Our sample (2.2 cm²) is not brecciated. The main ingredient—about 65 area%—is fine‐ to coarse‐grained ferromagnesian type I chondrules. Minor constituents (in order of 2‐D abundance) include refractory inclusions, Al‐rich chondrules, and very fine‐crystalline clasts of moderately volatile composition. Type II chondrules and metal nuggets occur sporadically. The chondrule–matrix ratio is approximately 3:1. Medium‐ and coarse‐grained chondrules exhibit porphyritic textures, probably caused by incomplete melting, and frequent, partial or continuous, recrystallized dust rims. The fine‐grained population most likely represents randomly sectioned dust rims. The rim material and some of the medium‐grained objects are relatively troilite‐rich. Iron‐nickel metal is rare. In addition, almost all constituents show strikingly ragged or convoluted outlines. Only a few, rim‐less components exhibit smooth contours. Evidence for incomplete melting and the formation of recrystallized or igneous rims in carbonaceous chondrites is well established, suggesting that both processes were widespread events. The observed features in Leoville support this conclusion. In addition, our findings indicate that surface abrasion in a turbulent dust‐filled regime may have taken place after the consolidation of dust rims. Alternatively, the irregular, convoluted nature of at least the rimmed chondrules may have been inherent to the dust accretion event and was not erased by subsequent heating.     

Climate and water budget change of a Mediterranean coastal watershed, Ravenna, Italy

It is generally difficult to quantify exactly the freshwater going in or out of the coastal watersheds along the northern Adriatic Sea because, on one hand, excess water is drained and pumped into the sea to prevent flooding but, on the other hand, water is brought onto the land from far away for irrigation. Fragmentation of water authorities makes it difficult to collect all the necessary information. Climate change and increasing salinization of the coastal aquifers make it imperative, however, to better know the quantities of freshwater involved in these small basins. The water budget of a small coastal agricultural watershed along the Adriatic Sea in Italy (The Quinto Basin near Ravenna) is presented here considering different land uses. The evaporation of open water and the evapotranspiration of wetlands, pine forests, bare soil and irrigated agriculture are calculated based on the Penman–Monteith equation and the Cropwat program. The current water budget is based on average climate data from 1989 to 2008 and drainage and irrigation data. Predictions for future evapotranspiration, net irrigation and hydrologic deficit are calculated with climate data from IPCC (The Fourth Assessment Report (AR4) 200, Climate change 2007). From the study results, the soil type may determine whether or not a crop will need more or less irrigation in the future. Regulations on land use should therefore consider which crop type can be grown on a specific soil type. Water budget analysis in scenarios A1b and A2 both show an increase of water deficits in the summer and an increase of water surplus in the winter. This is explained by the fact that a larger percentage of the rain will fall in winter and not during the growth season. The open water evaporation will decrease under future climate scenarios as a result of increased relative humidity in winter and decreased wind velocity. This may have a positive effect on the water cycle. The current irrigation is very abundant, but has beneficial effects in contrasting soil salinization and saltwater intrusion into the coastal aquifer.     

Hydrochemical considerations and heavy metal variability in the middle Paraná River

The Paraná River is one of the largest drainage systems in the Americas. Its hydrology is characterized by an active teleconnection with the ENSO, and by a significant discharge increase trend, evident since the mid-1970s. An Eh–pH data set collected in the Paraná’s middle stretch suggests that large flood events, such as the one triggered by the 1982–1983 ENSO, are discernible in the plot, probably due to the influx of water draining flood plain water bodies. The total (particulate + dissolved) concentration of a set of heavy metals (Cr, Mn, Ni, Cu, Zn, As, Cd, and Pb) was determined in a downriver survey of the middle stretch. With the exception of Cu, Cd, and Pb, the metals exhibit a significantly increasing concentration trend towards the river mouth. The slopes of the regression lines imply that Zn and Ni, on one hand, and Mn and Cr, on the other would have common controlling sources. Another set of analyses were performed during the 1982–1983 flooding event; besides an increased variability observable during the flood arrival, most elements, with the only exception of Pb, did not show a variability coherent with the discharge series.     

Alternative conceptual models and the robustness of groundwater management scenarios in the multi-aquifer system of the Central Veneto Basin, Italy

A three-dimensional (3D) groundwater flow model of the deep multi-aquifer Quaternary deposits of the Po plain sedimentary basin, within a 3,300-km² area (Veneto, Italy), is developed, tested and applied to aid sustainable large-scale water-resources management. Integrated mathematical modelling proves significantly successful, owing to an unusual wealth of available geological, geophysical, and hydrologic data and to state-of-the-art numerical tools. Of particular interest is the evaluation of the influence of alternative conceptual models; that is, of reconstructed representations of the 3D geological model of the structure of the aquifers. The reference conceptual model is set up by means of extended geological sections and stratigraphic records, and is used to create a large, unstructured 3D finite element grid. By analyzing the effects on piezometric surfaces and on the overall water budget of geometrical perturbations from the reference structure, alternative geo-structural models, obtained by systematically shifting the pinch-out of the aquitards, are compared. Interestingly, the impacts of aquitard pinch-out prove far from negligible. The results suggest the critical importance of reliable geological models even for large, complex 3D models. The good practice of iteratively testing numerically the impact of surprises on the conceptual model, as more field information is collected, is thus supported.     

New igneous zircon Pb/Pb and metamorphic Rb/Sr ages in the Yaounde Group (Cameroon, Central Africa): implications for the Central African fold belt evolution close to the Congo Craton

Three meta-igneous bodies from the Yaounde Group have been analyzed for their petrography, geochemistry, and ²⁰⁷Pb/²⁰⁶Pb zircon ages. According to their geochemical patterns, they represent meta-diorites. The meta-plutonites yielded identical zircon ages with a mean of 624?±?2?Ma interpreted as their intrusion age. This age is in agreement with previously published zircon ages of meta-diorites from the Yaounde Group. The meta-diorites derived mainly from crustal rocks with minor contribution from mantle material. The ⁸⁷Rb/⁸⁶Sr isochron ages of one meta-diorite sample and three meta-sedimentary host rocks are significantly younger than the obtained intrusion age. Therefore, they are not related to igneous processes. ⁸⁷Rb/⁸⁶Sr isochron ages differ from sample to sample (599?±?3, 572?±?4, 554?±?5, 540?±?5?Ma) yielding the oldest Neoproterozoic age (~600?Ma) for a paragneiss sample at a more northern location. The youngest Rb/Sr isochron age (~540?Ma) was obtained for a mica schist sample at a more southern location closer to the border of the Congo Craton. The ⁸⁷Rb/⁸⁶Sr whole rock-biotite ages are interpreted as cooling ages related to transpressional processes during exhumation. Therefore, several discrete metamorphic events related to the exhumation of the Yaounde Group were dated. It could be shown by Rb/Sr dating for the first time that these late tectonic processes occurred earlier at more distant northern locations of the Yaounde Group and lasted at least until early Cambrian (~540?Ma) more closely to the border of the Congo Craton.     

Dam-break Modeling in Alpine Valleys

Dam-break analysis is of great importance in mountain environment,especially where reservoirs are located upstream of densely populated areas and hydraulic hazard should be assessed for land planning purposes.Accordingly,there is a need to identify suitable operative tools which may differ from the ones used in flat flood-prone areas.This paper shows the results provided by a 1D and a 2D model based on the Shallow Water Equations（SWE） for dam-break wave propagation in alpine regions.The 1D model takes advantage of a topographic toolkit that includes an algorithm for pre-processing the Digital Elevation Model（DEM） and of a novel criterion for the automatic cross-section space refinement.The 2D model is FLO-2D,a commercial software widely used for flood routing in mountain areas.In order to verify the predictive effectiveness of these numerical models,the test case of the Cancano dam-break has been recovered from the historical study of De Marchi（1945）,which provides a unique laboratory data set concerning the consequences of the potential collapse of the former Cancano dam（Northern Italy）.The measured discharge hydrograph at the dam also provides the data to test a simplified method recently proposed for the characterization of the hydrograph following a sudden dam-break.     

Large wood load fluctuations in an Andean basin

The importance of monitoring and analysing wood fluxes in mountain environments is widely recognized. However, there is a lack of information related to the long-term fluctuations in wood load and associated to the changes in large wood (LW) characteristics. The main aims of the research were to analyse (i) changes in wood characteristics, (ii) fluctuations in wood load, and (iii) the relationship between wood load and sub-reach settings, proposing an ad hoc roughness index (RI). Repeated field surveys to measure wood load and LW characteristics during a 13-year period were conducted within a 2.2 km-long reach of the Rio Toro (Chile), which flows through the Malleco Forest National Reserve that was affected by wildfires in 2002 and 2015. Two spatial scales (i.e. study reach and sub-reach) were considered. Irrespective of the adopted scale wood load fluctuated considerably, in both number and volume, with significant changes in LW characteristics (i.e. mean diameter and length). Moreover, a clear tendency to the aggregation in wood jams (WJs) was observed within the entire study reach. Based on our results, we conclude that 17 years after the first wildfire wood recruitment has started in the upper parts of the basin. Moreover, Generalized Linear Mixed Models (GLMM) analyses were carried out to investigate the relationship between RI and both number and volume of LW. Both models are characterized by high adjusted R² of 74.9% and 72.8% for volume and number, respectively. This demonstrated that the RI can characterize the reaches in terms of tendency to deposition and trapping of wood. These results are promising, particularly in improving the knowledge related to potential deposition areas that can control wood load fluctuations, also permitting its management to be improved. © 2020 John Wiley & Sons, Ltd.     

Vesta's mineralogical composition as revealed by the visible and infrared spectrometer on Dawn

The Dawn spacecraft mission has provided extensive new and detailed data on Vesta that confirm and strengthen the Vesta–howardite–eucrite–diogenite (HED) meteorite link and the concept that Vesta is differentiated, as derived from earlier telescopic observations. Here, we present results derived by newly calibrated spectra of Vesta. The comparison between data from the Dawn imaging spectrometer—VIR—and the different class of HED meteorites shows that average spectrum of Vesta resembles howardite spectra. Nevertheless, the Vesta spectra at high spatial resolution reveal variations in the distribution of HED‐like mineralogies on the asteroid. The data have been used to derive HED distribution on Vesta, reported in Ammannito et al. (2013), and to compute the average Vestan spectra of the different HED lithologies, reported here. The spectra indicate that, not only are all the different HED lithologies present on Vesta, but also carbonaceous chondritic material, which constitutes the most abundant inclusion type found in howardites, is widespread. However, the hydration feature used to identify carbonaceous chondrite material varies significantly on Vesta, revealing different band shapes. The characteristic of these hydration features cannot be explained solely by infalling of carbonaceous chondrite meteorites and other possible origins must be considered. The relative proportion of HEDs on Vesta's surface is computed, and results show that most of the vestan surface is compatible with eucrite‐rich howardites and/or cumulate or polymict eucrites. A very small percentage of surface is covered by diogenite, and basaltic eucrite terrains are relatively few compared with the abundance of basaltic eucrites in the HED suite. The largest abundance of diogenitic material is found in the Rheasilvia region, a deep basin, where it clearly occurs below a basaltic upper crust. However, diogenite is also found elsewhere; although the depth to diogenite is consistent with one magma ocean model, its lateral extent is not well constrained.     

Robust resolution of Kepler’s equation in all eccentricity regimes

The singularity for the big bang state can be represented using the generalized anisotropic Friedmann equation, resulting in a system of differential equations in a central force field. We study the regularizability of this singularity as a function of a parameter, the equation of state, w. We prove that for w > 1 it is regularizable only for w satisfying relative prime number conditions, and for w ≤ 1 it can always be regularized. This is done by using a McGehee transformation, usually applied in the three and four-body problems. This transformation blows up the singularity into an invariant manifold. The relationship of this result to other cosmological models is briefly discussed.     

Testing different sorting techniques in macroinvertebrate samples from running waters

With the aim of finding an efficient, standardised and practical protocol for sorting macroinvertebrate samples for water management practice, three different sorting techniques were tested: RIVPACS sorting, a modified AQEM/STAR (MAS) sorting protocol and a Live-sorting method. Based on the same AQEM/STAR sample to ensure comparable results, we compared RIVPACS and MAS sorting for 20 samples, and Live-sorting and MAS for a different set of 20 samples. Comparisons were based on both ecological and financial parameters relevant for the implementation of the EU Water Framework Directive in Germany. Parameters include recently developed multimetric assessment indices, their stream type specific core metric results, time effort and costs. While RIVPACS and MAS sorting produced similar results in terms of ecological assessment, time effort and costs, Live-sorting differed notably in all three respects. Live-sorting is the quickest and least expensive protocol, but shows higher variability than the other protocols. We discuss the differences and the level of standardisation for each of these methods.