The Cloud Ice Mountain Experiment (CIME) 1998: experiment overview and modelling of the microphysical processes during the seeding by isentropic gas expansion

The second field campaign of the Cloud Ice Mountain Experiment (CIME) project took place in February 1998 on the mountain Puy de Dôme in the centre of France. The content of residual aerosol particles, of H₂O₂ and NH₃ in cloud droplets was evaluated by evaporating the drops larger than 5 μm in a Counterflow Virtual Impactor (CVI) and by measuring the residual particle concentration and the released gas content. The same trace species were studied behind a round jet impactor for the complementary interstitial aerosol particles smaller than 5 μm diameter. In a second step of experiments, the ambient supercooled cloud was converted to a mixed phase cloud by seeding the cloud with ice particles by the gas release from pressurised gas bottles. A comparison between the physical and chemical characteristics of liquid drops and ice particles allows a study of the fate of the trace constituents during the presence of ice crystals in the cloud.In the present paper, an overview is given of the CIME 98 experiment and the instrumentation deployed. The meteorological situation during the experiment was analysed with the help of a cloud scale model. The microphysics processes and the behaviour of the scavenged aerosol particles before and during seeding are analysed with the detailed microphysical model ExMix. The simulation results agreed well with the observations and confirmed the assumption that the Bergeron–Findeisen process was dominating during seeding and was influencing the partitioning of aerosol particles between drops and ice crystals. The results of the CIME 98 experiment give an insight on microphysical changes, redistribution of aerosol particles and cloud chemistry during the Bergeron–Findeisen process when acting also in natural clouds.     

Behaviour of H2O2, NH3, and black carbon in mixed-phase clouds during CIME

We investigated the partitioning of trace substances during the phase transition from supercooled to mixed-phase cloud induced by artificial seeding. Simultaneous determination of the concentrations of H₂O₂, NH₃ and black carbon (BC) in both condensed and interstitial phases with high time resolution showed that the three species undergo different behaviour in the presence of a mixture of ice crystals and supercooled droplets. Both H₂O₂ and NH₃ are efficiently scavenged by growing ice crystals, whereas BC stayed predominantly in the interstitial phase. In addition, the scavenging of H₂O₂ is driven by co-condensation with water vapour onto ice crystals while NH₃ uptake into the ice phase is more efficient than co-condensation alone. The high solubility of NH₄⁺ in the ice could explain this result. Finally, it appears that the H₂O₂–SO₂ reaction is very slow in the ice phase with respect to the liquid phase. Our results are directly applicable for clouds undergoing limited riming.     

Free cupric ion concentrations and Cu complexation in selected Swiss lakes and rivers

[Cu²⁺] and Cu complexation parameters in some selected freshwater systems in Switzerland were determined by the technique of ligand-exchange and DPCSV. Results from the water columns of some eutrophic and oligotrophic lakes are presented and compared to small acid lakes. Cu is strongly complexed by organic ligands which with very high stability constants at low concentrations are probably biologically produced, as indicated by the seasonal variations in the eutrophic lakes and by the relationship between Cu complexation and algal activity in the eutrophic (pCu=15–16), oligotrophic (pCu=13–14) and acidic (pCu=9–10) lakes. The extent of Cu complexation in river waters was generally lower than in the eutrophic lakes, at similar DOC levels. No obvious correlation between Cu complexation and DOC was observed, indicating that Cu complexing ligands are specific organic compounds.     

A viscoelastic shear zone model of compressional and extensional plate boundaries

A model is proposed describing the mechanical evolution of a shear zone along compressional and extensional plate boundaries, subject to constant strain rate. The shear zones are assumed as viscoelastic with Maxwell rheology and with elastic and rheological parameters depending on temperature and petrology. Stress and strain are computed as functions of time and depth. For both kinds of boundaries the model reproduces the existence of a shallow seismogenic zone, characterized by a stress concentration. The thickness of the seismogenic layer is evaluated considering the variations of shear stress and frictional strength on faults embedded in the shear zone. Assuming that a fault dislocation takes place, the brittle-ductile transition is assumed to occur at the depth at which the time derivative of total shear stress changes from positive to negative values. The effects of different strain rates and geothermal gradients on the depth of the brittle-ductile transition are studied. The model predictions are consistent with values inferred from seismicity data of different boundary zones.     

Taxonomische Studien über Cyanophyceen aus Oxydationsteichen

Zusammenfassung Die Cyanophyceen aus 8 Oxydationsteichen Südschwedens wurden untersucht. Drei Arten kamen regelm?ssig vor:Phormidium autumnale, Oscillatoria chalybea undO. tenuis. Letztere war in allen Teichen vorhanden und trat oft massenhaft auf. Es wurden statistische Messungen der Trichombreite, in erster Linie beiO. tenuis, die eine erhebliche Breitenvariation in ein und derselben Probe aufwies, vorgenommen. Die gr?sste Variationsbreite betrug 3,5 bis 10 μ. Trotzdem mussO. tenuis als eine gute Art betrachtet werden. Sie ist leicht identifizierbar, und die Kleinformen (Mikrotaxa) sind statistisch nicht auseinander zu halten. Wahrscheinlich stellen auch dievar. natans undtergestina solche Kleintypen dar und sollten daher in die Hauptart eingezogen werden. Eine schmale Form aus Humleb?cken (kein Oxydationsteich) weicht ausser der Zellbreite in weiteren Merkmalen von der Hauptart ab und k?nnte deshalb als eine Variet?t betrachtet werden.

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Summary The Cyanophyta found in 8 oxydation ponds in the South of Sweden were analysed. Three species appeared regularly:Phormidium autumnale, Oscillatoria chalybea andO. tenuis. The last species was present in all of the ponds and often in very large quantities. Statistical measures were made of the trichom width, especially ofO. tenuis for which considerable variations were observed in a single sample. The largest differences in width varied from 3·5 to 10 μ. Nevertheless,O. tenuis must be considered as a good species. It is easy to identify and its microtaxa cannot statistically be held apart. Thevar. natans andtergestina should probably be considered as microtaxa and included in the main species. A smaller type from Humleb?cken (not from an oxydation pond) differs from the main species not only in the width of its cells, but also in other characteristics and could therefore be considered as a variety.

     

Reporting negative results to stimulate experimental hydrology: discussion of “The role of experimental work in hydrological sciences – insights from a community survey”*

ABSTRACT

Experimental work in hydrology is in decline. Based on a community survey, Blume et al. showed that the hydrological community associates experimental work with greater risks. One of the main issues with experimental work is the higher chance of negative results (defined here as when the expected or wanted result was not observed despite careful experimental design, planning and execution), resulting in a longer and more difficult publishing process. Reporting on negative results would avoid putting time and resources into repeating experiments that lead to negative results, and give experimental hydrologists the scientific recognition they deserve. With this commentary, we propose four potential solutions to encourage reporting on negative results, which might contribute to a stimulation of experimental hydrology.     

Energy flow and elemental concentrations in the Steina River ecosystem (Black Forest, Germany)

Considering food web energetics and elemental cycling together allows the testing of hypotheses about the coevolution of biological systems and their physical environment. We investigated the energy flow and the distribution of 25 elements in the Steina River.¶We constructed an annual energy flow network and estimated the emergy ("embodied energy" that includes all the energy involved in a process) contributions of resources sustaining the system. Furthermore, we measured the concentration of various macronutrients, essential elements, and heavy metals in the physical environment and trophic compartments. Finally, we examined the hypothesis of a positive relationship between the "rarity" of an element and its tendency to bioaccumulate. To do so, we used transformity, the relative energy input required to sustain a compartment's net production or the concentration differential of an element between the living community and the physical environment.¶The resulting energy flow network is one of the most complete available for streams. In the Steina, over 99% of the energy input is transported through the system without being processed. Dissolved inorganic matter and sunlight are the largest inputs, but uptake efficiency is much higher for dissolved and particulate organic matter. Transformities of trophic compartments and elements span 6 to 7 orders of magnitude.¶The tendency to bioaccumulate was as predicted for most elements, with macronutrients showing no accumulation and heavy elements accumulating in high-transformity compartments. However, Na and K were found at highest concentrations in consumers, and Pb, Ga, and Cd in algae. Improved estimates may become possible as more knowledge is available on ecosystem flows. We suggest further ways of testing hypotheses about strategies of element processing.     

Comparing palaeolimnological and instrumental evidence of climate change for remote mountain lakes over the last 200 years

This paper compares the palaeolimnological evidence for climate change over the last 200 years with instrumental climate data for the same period at seven European remote mountain lakes. The sites are Øvre Neådalsvatn (Norway), Saanajärvi (Finland), Gossenköllesee (Austria), Hagelseewli (Switzerland), Jezero v Ledvici (Slovenia), Estany Redó (Spain, Pyrenees), and Niné Terianske Pleso (Slovakia). We used multiple regression analysis to transfer homogenised lowland air temperature records to each of the sites, and these reconstructions were validated using data from on-site automatic weather stations. These data showed that mean annual temperature has varied over the last 200 years at each site by between 1 and 2 °C, typical of the high frequency variability found throughout the Holocene, and appropriate, therefore, to test the sensitivity of the various proxy methods used. Sediment cores from each site were radiometrically dated using ²¹⁰Pb, ¹³⁷Cs and ²⁴¹Am and analysed for loss-on-ignition, C, N, S, pigments, diatoms, chrysophytes, Cladocera and chironomids. Comparisons between the proxy data and the instrumental data were based on linear regression analysis with the proxy data treated as response variables and the instrumental data (after smoothing using LOESS regressions) as predictor variables. The results showed few clear or consistent patterns with generally low or very low r² values. Highest values were found when the data were compared after smoothing using a broad span, indicating that some of the proxy data were capturing climate variability but only at a relatively coarse time resolution. Probable reasons for the weak performance of the methods used include inaccurate dating, especially for earlier time periods, the influence of confounding forcing factors at some sites e.g., air pollution, earthquakes, and the insensitivity of some methods to low amplitude climate forcing. Nevertheless, there were trends in some proxy records at a number of sites that had a relatively unambiguous correspondence with the instrumental climate records. These included organic matter and associated variables (C and N) and planktonic diatom assemblages at the majority of sites and chrysophytes and chironomids at a few sites. Overall for longer term studies of the Holocene, these results indicate the need to be cautious in the interpretation of proxy records, the importance of proxy method validation, the continuing need to use reinforcing multi-proxy approaches, and the need for careful site and method selection.     

Contributions to the Ring Current Energy During Geomagnetic Storms

The purpose of this research was to study the complexity of the energization of the ring current during a geomagnetic storm, produced during southern Bz(IMF) by the injection of plasma sheet ions, accelerated by enhanced convective electric fields. This model assumes that the plasma sheet is continuously populated by H⁺ from the sun and the ionosphere, and sporadically by ionospheric O⁺, making the ring current a coupled system whose energy can hardly be expressed analytically. When Bz(IMF) turns north, the ring current becomes uncoupled, and the energy decays exponentially if the storm is weak, or can be expressed as a combination of exponentials during strong storms representing the quick decay of O⁺ and the slower decay of H⁺, as has been shown.