Fecal Sterols in Estuarine Sediments as Markers of Sewage Contamination in the Cubat?o Area, S?o Paulo, Brazil

Sterol biomarkers serve as an alternative method for detecting sewage pollution. Sterols were extracted from samples of surface sediment collected in Cubat?o (the Vila dos Pescadores and Vila Esperan?a communities) and quantified using GC–MS after Soxhlet extraction, cleanup, and derivatization. Fecal contamination was evaluated based on the concentration of coprostanol and the ratio of the selected sterols. The most abundant sterol was cholestanol, followed by coprostanol. The concentrations of coprostanol in surface sediments ranged from a minimum of 4.21?μg?g^?1 dry sediment (Vila dos Pescadores station) to a maximum of 8.32?μg?g^?1 dry sediment (Vila Esperan?a station). A coprostanol concentration of about 10?μg?g^?1 was found, indicating areas of high sewage contamination. Coprostanol levels at sewage stations were higher than in other Brazilian coastal areas, which may be attributed to the fraction of the population without sanitation services.     

The historical development of built heritage awareness and conservation policies: a comparison of two World Heritage Sites: Edinburgh and Salvador do Bahia

Values regarding built heritage have developed historically in response to both international agendas and local circumstances, and have underpinned the creation of World Heritage Sites and regeneration approaches within these. Such regeneration processes are an arena where different interests meet and often confront each other, with concepts and values of built heritage being used to different ends by the actors involved. However, the origins of conservation concepts and approaches are seldom considered. This paper examines the historical development of built heritage awareness and conservation policies from an institutionalist perspective at the international, European and Latin. American levels. It then considers conservation policies in Scotland and Brazil, particularly in the central areas in Edinburgh and Salvador from the 19th century to the 1970s, and the growing awareness of built heritage among certain sections of society and local institutions in these localities. Finally, the paper analyses the reasons behind, and types of, interventions in Edinburgh’s Old Town and Salvador’s Pelourinho and Maciel neighbourhoods, and the level of awareness of built heritage among the general population in the two cities. The paper draws conclusions on the influence of various factors on the development of approaches to built heritage and on the different ways in which these contributed to a particular awareness of built heritage in Edinburgh and Salvador.     

The Mechanics of Rocking Stones: Equilibria on Separated Scales

Rocking stones, balanced in counter-intuitive positions, have always intrigued geologists. In our paper, we explain this phenomenon based on high-precision scans of pebbles which exhibit similar behavior. We construct their convex hull and the heteroclinic graph carrying their equilibrium points. By systematic simplification of the arising Morse–Smale complex in a one-parameter process, we demonstrate that equilibria occur typically in highly localized groups (flocks), the number of the latter being reliably observed and determined by hand experiments. Both local and global (micro and macro) equilibria can be either stable or unstable. Most commonly, rocks and pebbles are balanced on stable local equilibria belonging to stable flocks. However, it is possible to balance a convex body on a stable local equilibrium belonging to an unstable flock and this is the intriguing mechanical scenario corresponding to rocking stones. Since outside observers can only reliably perceive flocks, the last described situation will appear counter-intuitive. A comparison between computer experiments and hand experiments reveals that the latter are consistent, that is, the flocks can be reliably counted and the pebble classification system proposed in our previous work is robustly applicable. We also find an interesting logarithmic relationship between the flatness of pebbles and the average number of global equilibrium points, indicating a close relationship between classical shape categories and the new classification system.     

Dynamics of a particle under the gravitational potential of a massive annulus: properties and equilibrium description

This paper studies the main features of the dynamics around a massive annular disk. The first part addresses the difficulties finding an appropriated expression of the gravitational potential of a massive disk, which will be used to define the differential equations of motion of our dynamical system. The second part describes the main features of the dynamics with special attention to equilibrium of the system.     

Hypersaline fluids generated by high-grade metamorphism of evaporites: fluid inclusion study of uranium occurrences in the Western Zambian Copperbelt

In the Pan-African Lufilian belt (Western Zambian Copperbelt), uranium mineralizations, preferentially scattered in kyanite ± talc micaschists (metamorphosed evaporitic sediments) or concentrated along transposed quartz veins provide an opportunity to (1) understand the time/space relationship between the ore minerals and the deformation of the host rocks, (2) identify the different fluid events associated with specific stages of quartz deformation and (3) characterize the ore fluid geochemistry in terms of fluid origin and fluid/rock interactions. In the U occurrences studied in Lolwa and Mitukuluku (Domes region, Western Zambian Copperbelt), two mineralizing stages are described. The first generation of ore fluids (53–59 wt% CaCl₂, 13–15 wt% NaCl; N₂–H₂ in the gas phase of fluid inclusions) circulated during the high-temperature quartz recrystallization, at 500–700 °C. This temperature is in agreement with the P–T conditions recorded during the crustal thickening related to continental collision at ca. 530 Ma. LA-ICPMS analyses show the presence of uranium within this fluid, with a concentration mode around 20 ppm. The second generation of ore fluid (21–32 wt% NaCl, 19–21 wt% CaCl₂; CO₂–CO in the gas phase of fluid inclusions) percolated at lower temperature conditions, at the brittle–ductile transition, between 200 and 300 °C. This temperature could be related to the exhumation of the high-grade metamorphic rocks at ca. 500 Ma. The formation of H₂ and CO is interpreted as the result of radiolysis in the presence of dissolved uranium in the aqueous phase of these fluid inclusions. Finally, a late fluid (14–16 wt% NaCl_equiv) circulated in the brittle domain but seems unrelated to U (re-)mobilization event.     

An epidemiological approach to determining the risk of road damage due to landslides

Disruption of segments of roads can have a significant impact on the vulnerability of the entire network. Natural disasters are frequent causes of disruptions of this kind. This article focuses on determining the risk of road disruptions due to landslides. Our approach is based on methodology widely used in the field of epidemiology. We had available data on the location of the landslides, the road network and a list of the disrupted road segments. With the use of a 2 × 2 table, we determined the relationship between landslide data and road segment disruptions and derived the risk coefficient based on the number of landslides in the vicinity of the road and its length. The result is a disruption risk map with risk coefficients ranging from 0 to 47.94. In order to distinguish the most risky segments, we calculated a threshold of 12.40 with the use of a risk breakdown in a group of segments without damage. Nineteen percentage (402 km) of the road network in the Zlín region (Czech Republic), where the methodology was applied, is located beyond this threshold. The benefits of this approach stem from its speed and potential to define the most risky areas on which a detailed geomorphologic analysis can be focused.     

Methodology to evaluate the renewal period of carbonate aquifers: a key tool for their management in arid and semiarid regions,with the example of Becerrero aquifer,Spain

A methodological procedure is proposed for determining the renewal period (RP), which expresses the ratio of total storage to recharge of carbonate aquifers, and it was applied to the overexploited moderate-size Becerrero carbonate aquifer (southern Spain). To this end, geological and subsurface data—time domain electromagnetic (TEM) soundings and borehole logs—were integrated to construct a three-dimensional (3D) geological model of the aquifer. The interconnected porosity was estimated by analyzing 73 rock samples. The resulting 3D geometrical model makes it possible to quantify the fractions of the aquifer having a confined or unconfined behaviour. Based on the total storage capacity (179?·?10⁶–514?·?10⁶ m³) and available aquifer recharge estimation (4.8?·?10⁶–6.4?·?10⁶ m³/year), an RP between 37 and 106 years is obtained. In view of the RP, an exploitation rate slightly lower than the average recharge of the system is recommended, so that the piezometric level will be stable but below the discharge head that is produced through the springs in natural conditions. The proposed methodology to obtain an aquifer RP and the management strategies designed accordingly are of broad interest, especially for carbonate aquifers, which are abundant in arid and semiarid regions.     

Correlation of sedimentary units from grain-size and mineralogic analyses as a tool for constraining trench interpretations in palaeoseismology

In palaeoseismological trench studies, precise correlation of sedimentary units between fault blocks has an unquestionable value for accurately inferring the amounts of coseismic displacement and hence for assessing seismic hazard. A methodology based on laser analysis of particle size and mineralogic composition by X-ray diffraction is proposed in order to strengthen the correlation of sedimentary units in a trench excavated across the Concud Fault (central Iberian Chain, Spain). The surveyed sediments show sharp and multiple lateral facies changes, as well as inconsistent optically stimulated luminescence (OSL) ages. The results reinforce the correlation based on field inspection of lithologic and sedimentologic features. Moreover, they allow interpretation of rejuvenation of OSL ages of samples in the upthrown fault block, which has been attributed to partial erosion of sedimentary units, as evidenced by their smaller thickness and erosive boundaries. The correlated units are then used to estimate coseismic displacements for three palaeoseismic events.     

Relationship between hydrogeological parameters for data-scarce regions: the case of the Araripe sedimentary basin, Brazil

This paper applies and validates a method for generating spatially distributed hydraulic conductivity (k) based on the specific capacity (Q _s) for data-scarce regions. This method has been applied to the Araripe sedimentary basin, Brazil, and consists of four steps: (1) selection of (32) wells for which both k and Q _s data are available; (2) estimation of k as a function of Q _s for the (128) wells for which only specific capacity data are available; (3) spatial distribution of k using the kriging geostatistical tool; (4) validation of the method, using (17) representative wells with k measured data. The equation relating k and Q _s showed a statistically significant linear relationship (R = 0.93), from which a database has been generated using kriging with the spherical model. The results showed a calibration coefficient of Nash and Sutcliffe (NS) of 0.54 and moderate spatial dependence ratio of 69 %. The validation process provided only a moderate efficiency (NS = 0.22), possibly due to the geological complexity of the focus system. Despite its limitations, the method indicates the possibility of application of ordinary kriging to generate reliable data from auxiliary variables, especially for the water management of data-scarce areas.     

Regional recharge estimation using multiple methods: an application in the Annapolis Valley, Nova Scotia (Canada)

Recharge is a key parameter in groundwater resources management, and a reliable estimate of recharge is required for their sustainable development. Several methods are available to evaluate recharge; however, selecting the appropriate one is made difficult because each method has its advantages and drawbacks, and results can vary greatly from one method to another. Recharge methods can actually refer to different processes. This paper compares and discusses the results obtained from five regional-scale recharge assessment approaches applied to a fractured rock aquifer in a region with a temperate and humid climate (Annapolis Valley, Nova Scotia, Canada). These methods are distinguished between those providing estimates of the net infiltration (I) into the subsurface (river hydrograph separation and soil moisture balance) from those considering the net recharge (W) to the regional bedrock aquifer (river 7-day low-flows, the corrected soil moisture balance, a numerical groundwater flow model developed with FEFLOW and an infiltration model developed with HELP). The estimated net infiltration ranges from 160 to 250 mm/year, whereas the net recharge estimates range from 80 to 175 mm/year for the entire study area. Although different assessment methods were used, the estimated recharge range is still quite large, demonstrating the importance of using several methods. This case study should provide guidance on choices to be made in the development of a strategy for assessing representative values of aquifer recharge at the regional scale under similar geological and climatic conditions. The use of multiple complementary approaches should lead to a better understanding of the system dynamics and to better defined a representative range of recharge estimates.