Sulfuric Acid Production on Europa: The Radiolysis of Sulfur in Water Ice

Europa's surface is chemically altered by radiolysis from energetic charged particle bombardment. It has been suggested that hydrated sulfuric acid (H₂SO₄·nH₂O) is a major surface species and is part of a radiolytic sulfur cycle, where a dynamic equilibrium exists between continuous production and destruction of sulfur polymers S_x, sulfur dioxide SO₂, hydrogen sulfide H₂S, and H₂SO₄·nH₂O. We measured the rate of sulfate anion production for cyclo-octal sulfur grains in frozen water at temperatures, energies, and dose rates appropriate for Europa using energetic electrons. The measured rate is G_Mixture(SO₄²⁻)=f_Sulfur (r₀/r)^βG₁ molecules (100 eV)⁻¹, where f_Sulfur is the sulfur weight fraction, r is the grain radius, r₀=50 μm, β≈1.9, and G₁=0.4±0.1. Equilibrium column densities N are derived for Europa's surface and follow the ordering N(H₂SO₄) » N(S)>N(SO₂)>N(H₂S). The lifetime of a sulfur atom on Europa's surface for radiolysis to H₂SO₄ is τ(−S)=120(r/r₀)^β years. Rapid radiolytic processing hides the identity of the original source of the sulfurous material, but Iogenic plasma ion implantation and an acidic or salty ocean are candidate sources. Sulfate salts, if present, would be decomposed in <3800 years and be rapidly assimilated into the sulfur cycle.     

Paleoproterozoic gold deposits in the Bald Hill and Coyote areas, Western Tanami, Western Australia

Significant gold deposits in the western Tanami region of Western Australia include deposits in the Bald Hill and Coyote areas. The ca. 1,864 Ma Bald Hill sequence of turbiditic and mafic volcanic rocks hosts the Kookaburra and Sandpiper deposits and a number of smaller prospects. The ca. 1,835 Ma turbiditic Killi Killi Formation hosts the Coyote deposit and several nearby prospects. The Kookaburra deposit forms as a saddle reef within a syncline, and the Sandpiper deposit is localized within graphitic metasedimentary rocks along a limb of an anticline. Gold in these deposits is hosted by anastomosing quartz–(–pyrite–arsenopyrite) veins within quartz–sericite schist with disseminated arsenopyrite, pyrite, and marcasite (after pyrrhotite). Based on relative timing relationships with structural elements, the auriferous veins are interpreted to have been emplaced before or during the ca. 1,835–1,825 Ma Tanami Orogeny (regional D₁). Gold deposition is thought to have been caused by pressure drops associated with saddle reef formation (Kookaburra) and chemical reactions with graphitic rocks (Sandpiper). The Coyote deposit, the largest in the western Tanami region, consists of a number of ore lenses localized along the limbs of the Coyote Anticline, which formed during the Tanami Orogeny. The largest lenses are associated with the Gonzalez Fault, which is located along the steeply dipping southern limb of this fold. Gold was introduced at ca. 1,790 Ma into dilatant zones that formed in local perturbations along this fault during later reactivation (regional D₅) towards the end of a period of granite emplacement. Gold is associated with quartz–chlorite–pyrite–(arsenopyrite–galena–sphalerite) veins with narrow (<?5 mm) chloritic selvages. A quartz–muscovite–biotite–K–feldspar–(tourmaline–actinolite–arsenopyrite) assemblage, which is interpreted to relate to granite emplacement, overprints the regional greenschist facies metamorphic assemblage. The mineralogical similarity between this overprinting assemblage and the vein assemblage suggests that the auriferous veins at the Coyote deposit are associated with the granite-related metamorphic–metasomatic assemblage. Gold deposition is thought to have been caused by pressure drops within dilatant zones.     

Continuous record of environmental changes in Chukotka during the last 350 thousand years

The comprehensive study of the upper 1283 cm of sediment from Lake El’gygytgyn, which formed nearly 4 Ma ago following a meteorite impact in northern Chukotka, yielded the first continuous record of the extreme changes in the Beringian climate and vegetation from the middle Middle Pleistocene to recent time (equivalent of marine isotope stages of 1–7 and the upper part of isotope stage 8). During this period, the climate was warmer than at present between 8600 and 10 7000 ¹⁴C years and during the Late Pleistocene (isotope substage 5e, 116–128 ka ago). In 2003, the German-Russian-USA expedition continued studying sediments of Lake El’gygytgyn to obtain new evidence of the change in the vegetation cover in the Middle Pleistocene and the first information on the Middle Pleistocene interglacial (isotope stage 9; 297–347 ka ago). Pollen spectra characterizing the Middle Pleistocene interglacial are similar to spectra of the early stage of the Early Pleistocene interglacial and the climatic optimum in the Pleistocene to Holocene transitional period. The climatic history of Lake El’gygytgyn is basic for stratigraphic interpretations and correlations in the eastern sector of the Arctic. These data also expand our understanding of climatic changes that are studied within the framework of the “Pole-Equator-Pole Paleoclimate,” “Past Global Changes,” and other international projects.     

Geologic assessment of environmental impact in Lake Macatawa,Michigan

A historical record of the effects of human development upon Lake Macatawa is established using geologic criteria. Significant cultural events are recognized using the pollen record, particularly ambrosia/vesiculate pollen ratios, and occurrences of detrital and chemical contaminants within the more recent sedimentary column. Detrital contaminants include such things as cinder and ash from coal burning power plants and animal hair from early tanning operations. Trace metal contaminants, frequently associated with specific industrial events, are particularly useful in establishing a modern sedimentary chronology. The impact of human activity upon Lake Macatawa is measured using fossil diatoms. The advantage of this method of environmental impact assessment is that it provides a historical perspective in which changes within an environment are related to its natural conditions.     

Studies in diffusion,II. Oxygen in phlogopite mica

Self-diffusion of oxygen in a natural phlogopite mica (annite 4%) has been measured under hydrothermal conditions at 2000 bars pressure and from 500 to 800°C using water enriched in¹⁸O. Diffusional transport is dominantly parallel to the c crystallographic axis. A linear Arrhenius plot was obtained with a pre-exponential term = (1.03 ± 0.38) × 10^?9cm²sec^?1 a and an activation energy of 29 ± 2kcal/g-atom O. The difference in transport rate between oxygens in the OH groups and those in tetrahedral sites is small to non-existent unless the OH oxygens diffuse much more slowly than the other oxygens, which we consider unlikely. A typical phlogopite crystal, 0.2 mm thick by 1 mm across will lose radiogenic argon faster than it will exchange oxygen at temperatures above 435°C, but the reverse holds at lower temperatures if the diffusion mechanism can be extrapolated to temperatures below 500°C. Such a crystal will lose only 5% of its argon if held at 380°C for 1 m.y., but could exchange 27% of its oxygen in that time. The rate at which phlogopite will undergo deformation by diffusional creep does not appear to be controlled by oxygen diffusion.     

Correlation of lunar far-side magnetized regions with ringed impact basins

By the method of electron reflection, we have identified seven well-defined magnetized regions in the equatorial belt of the lunar far side sampled by the Apollo 16 Particles and Fields subsatellite. Most of these surface magnetic fields lie within one basin radius from the rim of a ringed impact basin, where thick deposits of basin ejecta are observed or inferred. The strongest of the seven magnetic features is linear, at least 250 km long, and radial to the Freundlich-Sharonov basin. The apparent correlation with basin ejecta suggests some form of impact origin for the observed permanently magnetized regions.