A dynamic deterministic model of hydrocarbon generation in the Midgard Field drainage area offshore Mid-Norway

The Midgard Field offshore mid-Norway is a gas-condensate accumulation with a thin oil leg reservoired in Early and Middle Jurassic sandstones. There are two potential source rocks in the area; the Late Jurassic Spekk Formation is a marine shale with type II kerogen and a rich potential for oil, and the Åre Formation of Early Jurassic age which is a thick coal-bearing sequence with type III kerogen and potential mainly for gas. Geochemical analyses indicate that both the condensate and the oil leg are sourced mainly from the coal-bearing Åre Formation. Any contribution from the Spekk Formation appears to be of minor importance. Computer simulation of hydrocarbon generation in the drainage area for the Midgard Field indicates that huge volumes are formed, and confirms that hydrocarbon generation from the Åre Formation is volumetrically far more important than from the Spekk Formation. The simulation results also exclude any contribution to the reservoired gas from the Spekk Formation.

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Zusammenfassung Das Midgard Feld vor der Küste Mittelnorwegens ist eine Gas-Kondensat-Akkumulation mit einem nur geringen Ölanteil innerhalb unter- und mitteljurassischer Sandsteine. In diesem Gebiet gibt es zwei mögliche Muttergesteine: Einmal die oberjurassische Spekk-Formation, bei der es sich um einen marinen Schiefer mit Typ II Kerogen handelt und die ein hohes Ölpotential darstellt. Zum anderen gibt es die unterjurassische Åre-Formation, eine mächtige Kohle-führende Folge mit Typ III Kerogen und ein möglicher Gaslieferant. Geochemische Analysen deuten darauf hin, daß sowohl das Gas-Kondensat als auch das Öl des Midgard Feldes auf diese Kohle-führende Åre-Formation zurückzuführen sind. Jede Zufuhr aus der Spekk-Formation scheint von geringer Bedeutung zu sein. Eine durch Computersimulation rekonstruierte Kohlenwasserstofferzeugung im Einzugsgebiet des Midgard Feldes spricht für eine hohe Bildungsrate und bestätigt die Annahme, daß die Kohlenwasserstoff-produktion der Spekk-Formation gegenüber der Åre-Formation zu vernachlässigen ist. Die Simulation ergab ferner, daß keinerlei Gas von der Spekk-Formation dem Reservoir zugeführt wurde.

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Résumé Le champ off-shore de Midgard (Norvège moyenne) est une accumulation de gaz condensé accompagnée d'un mince corps d'huile, accumulation renfermée dans des grès d'âge jurassique inférieur et moyen. Il existe dans le secteur deux sources possibles: la formation de Spekk (shale marins du Jurassique tardif, à kérogène de type II, possédant un riche potentiel en huile) et la formation d'Åre (série épaisse jurassique inférieure, à couches de charbon, à kérogène de type III et potentiel essentiellement en gaz). Les analyses géochimiques montrent que le gaz condensé et l'huile ont tous deux comme origine la formation charbonneuse de Åre. La formation de Spekk ne semble être intervenue que de manière subordonnée. Une simulation par ordinateur de la genèse de l'hydrocarbure dans l'aire d'alimentation du champ de Midgard fait apparaître que des volumes importants ont été formés et confirme la large prépondérance de la formation de Åre parmi les roches-mères. De plus, cette simulation exclut toute expèce de contribution de la formation de Spekk dans la genèse du gaz.

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Midgard / / . : Spekk — , 2, , Are , 3 . . . , Are. Spekk, , . Midgard , Are . , , Spekk .

     

The Barents Sea Ice Sheet — A model of its growth and decay during the last ice maximum

On the basis of geomorphological and sedimentological data, we believe that the entire Barents Sea was covered by grounded ice during the last glacial maximum. ¹⁴C dates on shells embedded in tills suggest marine conditions in the Barents Sea as late as 22 ka BP; and models of the deglaciation history based on uplift data from the northern Norwegian coast suggest that significant parts of the Barents Sea Ice Sheet calved off as early as 15 ka BP. The growth of the ice sheet is related to glacioeustatic fall and the exposure of shallow banks in the central Barents Sea, where ice caps may develop and expand to finally coalesce with the expanding ice masses from Svalbard and Fennoscandia.The outlined model for growth and decay of the Barents Sea Ice Sheet suggests a system which developed and existed under periods of maximum climatic deterioration, and where its growth and decay were strongly related to the fall and rise of sea level.     

Experimental studies on the phase systems Fe-Ni-Pd-S and Fe-Pt-Pd-As-S applied to PGE deposits

Summary In the present paper current results of experimental investigation of the phase system Pd-Fe-Ni-S at 900°C, 725°C, 550°C and 400°C as well as of the phase system Pt-Fe-As-S at 850°C and 470°C are summarized. A preliminary note on the system Pt-Pd-As-S is added. Individual phase assemblages are presented, data on solubility of PGE in base metal sulphides/arsenides or alloys are given and solid solution ranges of important minerals are described as a function of temperature and phase assemblage. The extent and role of sulphide/arsenide melts in these systems are presented together with hints for, and examples of the application of the current experimental results for the explanation of ore-geological processes.

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Bisherige Ergebnisse experimenteller Untersuchungen in den Systemen Fe-Ni-Pd-S und Fe-Pt-Pd-As-S und ihre Bedeutung für Lagerstätten der Platin-Gruppen-Elemente

Zusammenfassung In der vorliegenden Arbeit werden bisherige Ergebnisse experimenteller Untersuchungen in den Phasensystemen Pd-Fe-Ni-S bei 900°C, 725°C, 550°C sowie 400°C, bzw. Pt-Fe-As-S bei 850°C und 470°C zusammengefasst. Vorläufige Anmerkungen zum System Pt-Pd-As-S werden gegeben. Die Phasenbeziehungen und die Löslichkeitsdaten von PGE's in Buntmetall-Sulfiden/Arseniden sowie deren Verbindungen werden präsentiert. Die Mischungsbereiche der wichtigsten Minerale werden als Funktion von Temperatur und Phasenvergesellschaftung diskutiert. Die Rolle von Sulfid/Arsenid Schmelzen in diesen Systemen und Beispiele für die Anwendung dieser experimentellen Ergebnisse zur Erklärung lagerstättenkundlicher Prozesse werden beschrieben.

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With 6 Figures     

Attenuation models inferred from intraplate earthquake recordings

Strong-motion recordings at 87 sites from 56 different intraplate earthquakes from North America, Europe, China and Australia have been used through a two-step regression analysis to develop new attenuation models for peak ground acceleration, and for pseudo-relative velocity for frequencies of 0.25, 0.5, 1.0, 2.0, 5.0 and 10.0 Hz, all for 5 per cent of critical damping. The estimates are obtained along with an analysis of residuals and scatter. A similar regression analysis has been performed also for Fourier spectra of acceleration, in which case the coefficient for the anelastic term has been interpreted in terms of a frequency dependent quality factor Q. The resulting Q-model shows a strong frequency sensitivity with values around 600–700 at 1 Hz, around 2000 at 10 Hz and around 5200 at 25 Hz. These PGA, PSV and Q results depend, however, on the underlying assumption for geometrical spreading, in particular for low frequencies.     

H-chondrites: Trace element clues to their origin

We have analyzed 10 H-chondrites for 20 trace elements, using RNAA. The meteorites included 4 of petrologic type 4 and 2 each of types 3, 5 and 6.The data show that H-chondrites are not isochemical. H3's are depleted by some 10% not only in Fe (Dodd, 1976), but also in the siderophiles Os, Re, Ir, Ni, Pd, Au, and Ge. Moreover, the abundance pattern of siderophiles varies systematically with petrologic type. As similar fractionations of REE have been observed by Nakamura (1974), it appears that both the proportions and compositions of the main nebular condensates varied slightly during accretion of the H-chondrites. Thus the higher petrologic types are independent nebular products, not metamorphosed descendants of lower petrologic types.Abundances of highly volatile elements (Cs, Br, Bi, Tl, In, Cd, Ar³⁶) correlate with petrologic type, declining by ≤ 10^?3 from Type 3 to Type 6. The trends differ from those for artificially heated Type 3's (Ikramuddinet al., 1977b; Herzoget al., 1979), but agree passably with theoretical curves for nebular condensation. Apparently the low volatile contents of higher petrologic types are a primary feature, not the result of metamorphic loss.The mineralogy of chondrites suggests that they accreted between 405 K (absence of Fe₃O₄) and 560 K (presence of FeS), and the abundances of Tl, Bi, and In further restrict this interval to 420–500 K. Accretion at 1070 ± 100 K, as proposed by Hutchisonet al. (1979, 1980), leads to some extraordinary problems. Volatiles must be injected into the parent body after cooling, which requires permeation of the body by 10¹¹ times its volume of nebular gas. This process must also achieve a uniform distribution of the less volatile elements (Rb, Cu, Ag, Zn, Ga, Ge, Sn, Sb, Se, F), without freezeout in the colder outer layers.Factor analysis of our data shows 3 groupings: siderophiles (Os, Re, Ir, Ni, Pd, Au, and Ge), volatiles (Ag, Br, In, Cd, Bi, and Tl) and alkalis (Rb and Cs). The remaining 5 elements (U, Zn, Te, Se, and Sb) remain unassociated.     

The structural state of iron in oxidized vs. reduced glasses at 1 atm: A57Fe Mössbauer study

A general model for the structural state of iron in a variety of silicate and aluminosilicate glass compositions in the systems Na₂O-Al₂O₃-SiO₂-Fe-O, CaO-Al₂O₃-SiO₂-Fe-O, and MgO-Al₂O₃-SiO₂-Fe-O is proposed. Quenched melts with variable Al/Si and NBO/T (average number of nonbridging oxygens per tetrahedrally coordinated cation), synthesized over a range of temperatures and values of oxygen fugacity, are analyzed with⁵⁷Fe Mössbauer spectroscopy. For oxidized glasses with Fe³⁺/∑Fe>0.50, the isomer shift for Fe³⁺ is in the range ～0.22–0.33 mm/s and ～0.36 mm/s at 298 K and 77 K, respectively. These values are indicative of tetrahedrally coordinated Fe^3?. This assignment is in agreement with the interpretation of Raman, luminescence, and X-ray,K-edge absorption spectra. The values of the quadrupole splitting are ～0.90 mm/s (298 K and 77 K) in the Na-aluminosilicate glasses and compare with the values of 1.3 mm/s and 1.5 mm/s for the analogous Ca- and Mg-aluminosilicate compositions. The variations in quadrupole splittings for Fe³⁺ are due to differences in the degree of distortion of the tetrahedrally coordinated site in each of the systems. The values of the isomer shifts for Fe²⁺ ions in glasses irrespective of Fe³⁺/∑Fe are in the range 0.90–1.06 mm/s at 298 K and 1.0–1.15 mm/s at 77 K. The corresponding range of values of the quadrupole splitting is 1.75–2.10 mm/s at 298 K and 2.00–2.35 mm/s at 77 K. The temperature dependence of the hyperfine parameters for Fe²⁺ is indicative of noninteracting ions, but the values of the isomer shift are intermediate between those values normally attributable to tetrahedrally and octahedrally coordinated Fe²⁺. The assignment of the isomer-shift values of Fe²⁺ to octahedral coordination is in agreement with the results of other spectral studies. For reduced glasses (Fe³⁺/∑Fe≈<0.50), the value of the isomer shift for Fe³⁺ at both 298 K and 77 K increases and is linearly correlated with decreasing Fe³⁺/∑Fe in the range of \(f_{O_2 } \) between 10^?3 and 10^?6 atm when a single quadrupole-split doublet is assumed to represent the absorption due to ferric iron. The increase in value of the isomer shift with decreasing \(f_{O_2 } \) is consistent with an increase in the proportion of Fe³⁺ ions that are octahedrally coordinated. The concentration of octahedral Fe³⁺ is dependent on the \(T - f_{O_2 } \) conditions, and in the range of log \(f_{O_2 } \) between 10^?2.0 and 10^?5 a significant proportion of the iron may occur as iron-rich structural units with stoichiometry similar to that of inverse spinels such as Fe₃O₄, in addition to isolated Fe²⁺ and Fe³⁺ ions.     

Introduction to soil degradation processes in drylands

Two efforts by UN organizations to diagnose and map the distribution and trends of soil degradation in drylands are briefly described and compared.Soil degradation by water is greatly accelerated under poor vegetation cover in the Tropics and Subtropics, probably for two major reasons: high rates of decomposition of organic matter and high intensities of rainfall. The consequences of soil losses and high water runoff can reach far downstream in the river basin, causing damage by sedimentation on floodplains and in reservoirs.Damages by wind erosion and deposition are also much accelerated by overexploitation of the meagre vegetation cover of drylands. Overgrazing, overcultivation, firewood collection are the consequences of human and animal pressure, leading to more or less long-lasting desertification. The finer material, clay, silt, and organic matter, is blown by dust storms over long distances and can be deposited as dry or wet fallout in oceans or on land under the dust trajectories.Salinization often affects highly productive soils under poor irrigation practices. It is therefore a form of dryland degradation which causes particularly high losses of potential crops.     

Lake Søbygaard: a shallow lake in recovery after a reduction in phosphorus loading

The development and recovery of a shallow and hypertrophic lake following a reduction in the external phosphorus load has been documented. In spite of this reduction, phosphorus concentrations and phytoplankton biomass in the lake water are still very high. The reason for this development can be explained by three main factors: (1): the sediment has been accumulating a large phosphorus pool which is now causing a high internal phosphorus load, (2) due to the shallow conditions, resuspension of the upper sediment often takes place because of wind action and thereby increases the phosphorus loading from the sediment, (3) the development of a large population of planktivorous fish decreases the zooplankton biomass resulting in the development of a large phytoplankton biomass.