Origin of chemically distinct granites in a composite intrusion in east-central Sweden: geochemical and geothermal constraints

A few tens of millions of years after the intrusion of the Early Svecofennian (1.87–1.85 Ma) granitoids in central Sweden, a renewed magmatic activity resulted in the emplacement of the Late Svecofennian granites, the tectonic setting of which remains obscure. S-type granites dominate this group, but both I-type and transitional granites are common. This study deals with one of these intrusions in east-central Sweden; a composite pluton that is insignificantly deformed and hosts both I- and S-type granites. One of the I-type granites shows a compositional trend from granodiorite to granite, which is uncommon among the Late Svecofennian granites. Major element and incompatible trace element compositions and _Nd data show that two different sources, one igneous and one sedimentary, were involved. An important conclusion is that nearly coeval granites derived from different sources are found in close connection. The granites are suggested to have formed by partial melting in a thickened continental crust that was formed in an early stage of the Svecofennian event. Thermal models suggest that the slightly older, high-temperature I-type granite (granodiorite) was formed deeper in the crust than the S-type granite. The coexistence of essentially pure I- and S-type granites, rather than transitional mixtures, reflects the relative depths of the proposed sources and the varying thermal parameters of the lithologic units in the Svecofennian crust.     

Solubilities of noble gases in magnetite: implications for planetary gases in meteorites

Solubilities of noble gases in magnetite were determined by growing magnetite in a noble-gas atmosphere between 450 and 700°K. Henry's law is obeyed at pressures up to 10^?2 atm for He, Ne, Ar and up to 10^?5 atm for Kr, Xe, with the following distribution coefficients at 500° (cc STP g^?1 atm^?5): He 0.042, Ne 0.016, Ar 3.6, Kr 1.3, Xe 0.88, some 10²–10⁵ times higher than previous determinations on silicate and fluoride melts. Apparent heats of solution in kcal/mole are: He ?2.42 ±0.12, Ne ?2.20 ±0.10, Ar ?15.25 ±0.25, Kr ?13.0 ±0.3, Xe ?12-5 ± 0.5. These values, too, stand in sharp contrast with earlier determinations on melts which were small and positive, but are comparable to the values for clathrates. Presumably the gases are held in anion vacancies.Extrapolation of the magnetite data to the formation temperature of C1 chondrites, 360°K, shows that the Ar_p³⁶ content of Orgueil magnetite could be acquired by equilibrium solubility at a total nebular pressure of 4 × 10^?6 atm. In the absence of data for silicates (the principal host phase of planetary gas), an attempt is made to estimate the solubilities required to account for planetary gases in meteorites. These values do not appear grossly unreasonable in the light of the magnetite data, when structural differences between the two minerals are taken into account. It seems that equilibrium solubility may be able to account for four features of planetary gas: elemental ratios, amounts, correlations with other volatiles and retentive siting. It cannot account for the isotopic fractionation of planetary gas, however.     

A hydrothermal investigation of the system FeO, Fe2O3, TiO2

Phase relations in the system FeO---Fe₂O₃---TiO₂, at temperatures ranging between 300°C and 700°C, have been investigated experimentally with special refference to the reaction Fe₃O₄ + TiO₂ = Fe₂O₃ + FeTiO₃. Pressure was varied between 500 and 2000 bars but its effect was negligible. Magnetite and rutile are the stable assemblage at temperatures above 550 dgC, and hematite and ilmenite are stable for lower temperatures. The equilibrium oxygen fugacity is estimated to be 10^−17.5 bars at equilibrium temperature. It is suggested that intermediate hematite-ilmenite solid solutions are inhomogeneous, consisting of ‘domains’ of hematite and ilmenite. The ‘domains’ are too small to be resolved by X-ray diffraction techniques. The top of the solvus curve in the hematite-ilmenite solution corresponds to a temperature of 660°C. Regular solution theory is not applicable to the solid solution.     

新疆南天山奥图拉托格拉克一带前震旦系基底地质特征

1994年在新疆南天山地区奥图拉托格拉克一带 ,首次发现了晚太古代、元古宙结晶基底。晚太古代变质岩主要由变质深成岩组成 ,表壳岩组合为沙窝大沟岩组 ,岩性为一套变质火山—沉积岩。阜平期变侵入岩为巴什托格拉克片麻杂岩 ,为一套无序的 TTG岩系。五台期变侵入岩为沙窝布拉克片麻岩套。为一套基本有序的变侵入岩系列 ,包括 TTG和二长花岗岩两个岩系。三者组成太古宙古陆核。下元古界奥图拉托格拉克岩群为一套无序变质火山—沉积岩系 ,具有古老沟弧盆体系特征 ,阿牙克托格拉克岩组原岩为古蛇绿岩组合 ,具洋脊玄武岩特征 ;克孜拉格岩组原岩为杂砂岩 ,属盆地沉积 ;卡拉格兹岩组原岩为岛弧火山岩。长城系乱滩布拉克组由一套变火山岩、火山碎屑岩组成 ,属岛弧或活动陆缘沉积 ;卫东庄组为一变质碎屑岩建造 ,具弧盆碎屑岩沉积特征。长城纪末侵入了多岛滩超单元花岗岩     

Enstatite chondrites: Trace element clues to their origin

We have analyzed by RNAA 3 EH and 3 EL chondrites for 20 trace elements. Interelement correlations were examined visually and by factor analysis, to assess the effects of nebular fractionation and metamorphism.Refractory siderophiles (Ir, Os, Re) correlate with “normal siderophiles” (Ni, Pd, Au, Sb, and Ge) in EL's but not EH's; presumably these two element groups originally condensed on separate phases (CAI and metal), but then concentrated in metal during metamorphism. Sb and Ge are more depleted than the other three elements of the “normal” group, presumably by volatilization during chondrule formation.Volatiles are consistently more depleted in EL's than EH's, by factors >10× for the more volatile elements. Some of the stronger correlations are found for In-Tl, Tl-Bi, and Zn-Cd-In. These correlations are about equally consistent with predicted condensation curves for the solar nebula (especially for host phases with negative heats of solution, or for P = 0.1?1 atm) and with volatilization curves for artificially heated Abee, as determined by M E. Lipschutz and coworkers at Purdue. No decisive test between these alternatives is available at present, but the close correlation of Zn, Cd, In may eventually provide a crucial test.Factor analysis shows that 3 factors account for 93% of the variance; they seem to reflect volatile (F1), siderophile (F2), and chalcophile (F3) behavior. The element groupings agree largely with those recognized visually; they are listed with the inferred host phases. F1 (minor sulfide, probably ZnS): Zn, Cd, In, Br; F2 (CAI, later metal): Ir, Os. Re; F1, F2 (metal): Ni, Pd, Au, Ge, Sb; F3, F1 (FeS): Se, Te, Bi, Tl. These correlations differ to some extent from those obtained by Shaw (1974) in an earlier factor analysis, presumably because the new data are more homogeneous and extensive, especially for siderophiles. The new correlations also show that the cosmochemical behavior of some volatiles in E-chondrites differs from that predicted for ordinary chondrites, so that condensation curves for the latter are not strictly applicable.     

Tropical versus high latitude freshwater influence on the Atlantic circulation

We investigate the model sensitivity of the Atlantic meridional overturning circulation (AMOC) to anomalous freshwater flux in the tropical and northern Atlantic. Forcing in both locations leads to the same qualitative response: a positive freshwater anomaly induces a weakening of the AMOC and a negative freshwater anomaly strengthens the AMOC. Strong differences arise in the temporal characteristics and amplitude of the response. The advection of the tropical anomaly up to the deep water formation area leads to a time delayed response compared to a northern forcing. Thus, in its transient response, the AMOC is less sensitive to a constant anomalous freshwater flux in the tropics than in the north. This difference decreases with time and practically vanishes in equilibrium with constant freshwater forcing. The equilibrium response of the AMOC shows a non-linear dependence on freshwater forcing in both locations, with a stronger sensitivity to positive freshwater forcing. As a consequence, competitive forcing in both regions is balanced when the negative forcing is about 1.5 times larger than the positive forcing. The relaxation time of the AMOC after termination of a freshwater perturbation depends significantly on the AMOC strength itself. A strong overturning exhibits a faster relaxation to its unperturbed state. By means of a set of complementary experiments (pulse-perturbations, constant and stochastic forcing) we quantify these effects and discuss the corresponding time scales and physical processes.     

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Seeking commonalities of community resilience to natural hazards: A cluster analysis approach

ABSTRACT

The aim of the study on which the article is based was to identify groups of communities with similar resilience profiles, using Norwegian municipalities as a case. The authors used a set of socioeconomic and environmental indicators as measures of municipalities’ resilience and performed a cluster analysis to divide the municipalities into groups with similar multivariate resilience signatures. The results revealed six groups of municipalities that, apart from their unique combinations of indicator scores, featured certain spatial patterns, such as an “urban cluster” with urbanized municipalities and a “suburban cluster” with municipalities concentrated around major cities. The authors conclude that municipalities in each of the groups shared aspects that made them either more or less resilient to natural hazards, which could make them potential targets for shared interventions. Additionally, the authors conclude that clustering can be used to identify municipalities with similar resilience features and that could benefit from networking and sharing operational planning as a way to improve their respective communities' resilience to natural hazards.     

Persistence and biodegradation of kerosene in high-arctic intertidal sediment

A kerosene type hydrocarbon fraction (equivalent to 7 L m(-2)) was added to enclosures in the surface layer of high-arctic intertidal beach sediment. The experimental spill was repeated in two consecutive years in the period July-September. The rate and extent of hydrocarbon removal and the accompanying bacterial response were monitored for 79 days (2002) and 78 days (2003). The bulk of added kerosene, i.e. 94-98%, was lost from the upper 5 cm layer by putatively abiotic processes within 2 days and a residual fraction in the range 0.6-1.2mg per g dry sediment was stably retained. Concomitant addition of oleophilic fertilizer led to higher initial retention, as 24% of the kerosene remained after 2 days in the presence of a modified, cold-climate adapted version of the well-known Inipol EAP 22 bioremediation agent. In these enclosures, which showed an increase in hydrocarbon-degrader counts from 6.5 x 10(3) to 4.1 x 10(7) per g dry sediment within 8 days, a 17% contribution by biodegradation to subsequent hydrocarbon removal was estimated. Stimulation in hydrocarbon-degrader counts in fertilizer-alone control enclosures was indistinguishable from the stimulation observed with both kerosene and fertilizer present, suggesting that the dynamics in numbers of hydrocarbon-degrading bacteria was primarily impacted by the bioremediation agent.