Unequilibrated ordinary chondrites: A tentative subclassification based on volatile-element content

For unequilibrated ordinary chondrites (= UOC), two measures of primitiveness are available: volatile content, in principle reflecting accretion conditions from the solar nebula, and metamorphism, reflecting reheating in the parent bodies. These two measures do not always correlate, and we have therefore developed a tentative classification scheme based on volatile content that complements the Searset al. (1980) scheme based on metamorphism. Like the latter, it subdivides type 3 chondrites on a scale of 3.0 to 3.9; the notation 3.4/0 indicates a meteorite that is subtype 3.4 according to metamorphism and 3.0 according to volatile content.The classification is based mainly on C and Xe—two elements that are little affected by shock-induced reheating—and to a lesser extent on Ar³⁶,Bi,In, and Tl. Of 22 meteorites considered, the majority have concordant classifications (±0.2) on the two scales. However, 5 meteorites are richer in volatiles than their metamorphic grade indicates: Sharps 3.4/0, ALHA 77011 3.5/0, Ngawi 3.6/3, ALHA 77299 3.7/4, and Mezö-Madaras 3.7/3. It remains to be seen whether these differences indeed denote a more primitive nature.Some new clues to the formation of chondrites may eventually come from Xe and C. Their concentrations in UOC's vary by more than 5×, but the $\text{Xe}\text{C}$ ratio remains nearly constant at 3.4 × 10^?3 of the solar-system ratio. Even the ratios for other chondrite classes differ only slightly from that for UOC's, e.g., C3O (1.5×) and E3,4 (0.4×). Either the 4 factors determining this ratio (T, t, P, and internal surface area of the carbon) varied in complementary fashion, or—more probably—they varied only slightly in the entire source region of chondrites.     

Determination of the deformation properties of bedrock under turbine foundations

Summary This paper presents an improved investigation technique for in-situ determination of the deformation properties of rock masses, which are important parameters in the desing of foundations. This technique permits testing on a circular, one square metre area of the rock. In order to obtain reproducible loading conditions when testing, an equipment was introduced that gave almost uniformly distributed loading of the rock surface. This device is described in this paper. Displacement measurements are made in a central measuring hole, since a point of zero displacement, located equidistant between the loaded surface and the upward-pointing anchoring forces, offered a suitable reference point. In this way, the measuring device is also well protected against disturbing variations in temperature. During cyclic loading and unloading, charateristic load/deflection graphs are recorded, which directly demonstrate the deformation properties of the rock, such as the modulus of deformation at different loads, linearity deviation from linearity, as well as hysteresis effects and creep. It is clear that the results of the investigation apply only to the measuring point—the place at which the investigation was carried out. The properties of the rock nearby may vary considerably. The procedure for using this method of investigation for testing improvement measures for turbine foundations is shown in some examples.     

A parallel computing thin‐sheet inversion algorithm for airborne time‐domain data utilising a variable overburden

Accurate modelling of the conductivity structure of mineralisations can often be difficult. In order to remedy this, a parametric approach is often used. We have developed a parametric thin‐sheet code, with a variable overburden. The code is capable of performing inversions of time‐domain airborne electromagnetic data, and it has been tested successfully on both synthetic data and field data. The code implements an integral solution containing one or more conductive sheets, buried in a half‐space with a laterally varying conductive overburden. This implementation increases the area of applicability compared to, for example, codes operating in free space, but it comes with a significant increase in computational cost. To minimise the cost, the code is parallelised using OpenMP and heavily optimised, which means that inversions of field data can be performed in hours on multiprocessor desktop computers. The code models the full system transfer function of the electromagnetic system, including variable flight height. The code is demonstrated with a synthetic example imitating a mineralisation buried underneath a conductive meadow. As a field example, the Valen mineral deposit, which is a graphite mineral deposit located in a variable overburden, is successfully inverted. Our results match well with previous models of the deposit; however, our predicted sheet remains inconclusive. These examples collectively demonstrate the effectiveness of our thin‐sheet code.     

Integrity of Clay Till Aquitards to DNAPL Migration: Assessment Using Current and Emerging Characterization Tools

Field investigations were carried out to determine the occurrence of tetrachloroethene (PCE) dense nonaqueous phase liquid (DNAPL), the source zone architecture and the aquitard integrity at a 30‐ to 50‐year old DNAPL release site. The DNAPL source zone is located in the clay till unit overlying a limestone aquifer. The DNAPL source zone architecture was investigated through a multiple‐lines‐of‐evidence approach using various characterization tools; the most favorable combination of tools for the DNAPL characterization was geophysical investigations, membrane interface probe, core subsampling with quantification of chlorinated solvents, hydrophobic dye test with Sudan IV, and Flexible Liner Underground Technologies (FLUTe) NAPL liners with activated carbon felt (FACT). While the occurrence of DNAPL was best determined by quantification of chlorinated solvents in soil samples supported by the hydrophobic dye tests (Sudan IV and NAPL FLUTe), the conceptual understanding of source zone architecture was greatly assisted by the indirect continuous characterization tools. Although mobile or high residual DNAPL (S _t > 1%) only occurred in 11% of the source zone samples (intact cores), they comprised 86% of the total PCE mass. The dataset, and associated data analysis, supported vertical migration of DNAPL through fractures in the upper part of the clay till, horizontal migration along high permeability features around the redox boundary in the clay till, and to some extent vertical migration through the fractures in the reduced part of the clay till aquitard to the underlying limestone aquifer. The aquitard integrity to DNAPL migration was found to be compromised at a thickness of reduced clay till of less than 2 m.     

Late Quaternary glacier and sea-ice history of northern Wijdefjorden,Svalbard

The deglaciation history and Holocene environmental evolution of northern Wijdefjorden, Svalbard, are reconstructed using sediment cores and acoustic data (multibeam swath bathymetry and sub-bottom profiler data). Results reveal that the fjord mouth was deglaciated prior to 14.5±0.3 cal. ka BP and deglaciation occurred stepwise. Biomarker analyses show rapid variations in water temperature and sea ice cover during the deglaciation, and cold conditions during the Younger Dryas, followed by minimum sea ice cover throughout the Early Holocene, until c. 7 cal. ka BP. Most of the glaciers in Wijdefjorden had retreated onto land by c. 7.6±0.2 cal. ka BP. Subsequently, the sea-ice extent increased and remained high throughout the last part of the Holocene. We interpret a high Late Holocene sediment accumulation rate in the northernmost core to reflect increased sediment flux to the site from the outlet of the adjacent lake Femmilsjøen, related to glacier growth in the Femmilsjøen catchment area. Furthermore, increased sea ice cover, lower water temperatures and the re-occurrence of ice-rafted debris indicate increased local glacier activity and overall cooler conditions in Wijdefjorden after c. 0.5 cal. ka BP. We summarize our findings in a conceptual model for the depositional environment in northern Wijdefjorden from the Late Weichselian until present.     

Jurassic smectite and kaolinite trends of the East European Platform: implications for palaeobathymetry and palaeoclimate

Clay minerals cannot only give information on sedimentary depositional environment but also the climate regime under which sediment was weathered. The successions of non‐marine to marine Middle and Late Jurassic strata of the East European Platform show upwards increasing contents of smectite and decreasing contents of kaolinite. There is also an increasing smectite vs. kaolinite ratio laterally, in a basinward direction within individual formations. Vertical smectite and kaolinite content curves coincide broadly with the Sahagian and Jones eustatic sea‐level curve. All this implies differential settling of smaller smectite particles offshore and larger kaolinite particles onshore. Smectite formation, preservation and supply were further enhanced as the eastwards expanding Late Jurassic arid zone of Laurasia influenced weathering conditions in the sediment source areas, to the north and east of the East European Platform.     

Dissolved organic matter (DOM) export to a temperate estuary: seasonal variations and implications of land use

Inputs of dissolved carbon, nitrogen, and phosphorus were assessed for an estuary and its catchment (Horsens, Denmark). Seasonal patterns in the concentrations of DOM in the freshwater supply to the estuary differed depending on the soil and drainage characteristics of the area. In streams draining more natural areas the, patterns observed were largely driven by seasonal temperature fluctuations. The material exported from agricultural areas was more variable and largely controlled by precipitation events. Positive exponential relationships were found between the nitrogen and phosphorus loading, and the percentage of catchment area used for agriculture. Colored DOM (CDOM) loading measurements were found to be a good predictor of dissolved organic carbon (DOC) loading across the different subcatchments, offering a rapid and inexpensive alternative of operationally monitoring DOC export. For all the dissolved nutrient inputs to the estuary, dissolved inorganic nitrogen (DIN) and dissolved organic phosphorus dominated the loadings. Although 81% of the nitrogen annually supplied to the estuary was DIN, 83% of the nitrogen exported from the estuary was dissolved organic nitrogen (DON). Results show that increasing the area of the catchment covered by forest and natural pastures would have a positive effect on the trophic status of the estuary, leading to a considerable decrease in the phosphorus loading and a shift in the nitrogen loading from DIN to DON. Such a change in land use would also increase the export of DOC and CDOM to the estuary having the potential to increase oxygen consumption and reduce the photic depth.     

The earth system model of intermediate complexity CLIMBER-3α. Part I: description and performance for present-day conditions

We herein present the CLIMBER-3α Earth System Model of Intermediate Complexity (EMIC), which has evolved from the CLIMBER-2 EMIC. The main difference with respect to CLIMBER-2 is its oceanic component, which has been replaced by a state-of-the-art ocean model, which includes an ocean general circulation model (GCM), a biogeochemistry module, and a state-of-the-art sea-ice model. Thus, CLIMBER-3α includes modules describing the atmosphere, land-surface scheme, terrestrial vegetation, ocean, sea ice, and ocean biogeochemistry. Owing to its relatively simple atmospheric component, it is approximately two orders of magnitude faster than coupled GCMs, allowing the performance of a much larger number of integrations and sensitivity studies as well as longer ones. At the same time its oceanic component confers on it a larger degree of realism compared to those EMICs which include simpler oceanic components. The coupling does not include heat or freshwater flux corrections. The comparison against the climatologies shows that CLIMBER-3α satisfactorily describes the large-scale characteristics of the atmosphere, ocean and sea ice on seasonal timescales. As a result of the tracer advection scheme employed, the ocean component satisfactorily simulates the large-scale oceanic circulation with very little numerical and explicit vertical diffusion. The model is thus suited for the study of the large-scale climate and large-scale ocean dynamics. We herein describe its performance for present-day boundary conditions. In a companion paper (Part II), the sensitivity of the model to variations in the external forcing, as well as the role of certain model parameterisations and internal parameters, will be analysed.