The effects of mining in Northern Romania on the heavy metal distribution in sediments of the rivers Szamos and Tisza (Hungary)

The breach in the dam of a tailing pond in the processing plant of a gold mine in Baia Mare (NW Romania) in January 2000 lead to an ecological disaster in the rivers Szamos and Tisza. It was mainly caused by the released slurries containing cyanides and heavy metals. The investigation of surface sediment samples and depth profiles of the years 2000 and 2001 documented the pollution of the rivers Szamos and Tisza on Hungarian territory. In the Szamos and large areas of the Tisza floodplains a significant enrichment with the heavy metals Pb, Cd, Cu, and Zn is existent. The identification of the binding forms with sequential extraction showed that Cd and Zn exist in an easily available form. Therefore the remobilization is possible and an environmental hazard in the downstream areas must be considered. The anthropogenically caused portions of heavy metal concentrations decrease considerably with increasing distance to the mining region. The comparison of the concentrations of heavy metals in both years shows that the pollution is not only caused by the accident in January 2000. The increase of concentrations is based on the permanent input of pollutants into the rivers. The pollution is mainly caused by the erosion of exposed tailing dumps and the poor maintenance of the treatment plants.     

Second-order interpolation of later-arrival traveltimes

The performance of a 3D prestack migration of the Kirchhoff type can be significantly enhanced if the computation of the required stacking surface is replaced by an efficient and accurate method for the interpolation of diffraction traveltimes. Thus, input traveltimes need only be computed and stored on coarse grids, leading to considerable savings in CPU time and computer storage. However, interpolation methods based on a local approximation of the traveltime functions fail in the presence of triplications of the wavefront or later arrivals. This paper suggests a strategy to overcome this problem by employing the coefficients of a hyperbolic traveltime expansion to locate triplications and correct for the resulting errors in the interpolated traveltime tables of first and later arrivals.     

Latent heat fluxes simulated with a non-hydrostatic weather forecast model using actual surface properties from measurements and remote sensing

In this study the influence of land-surface parameters on latent heat fluxes simulated with the numerical weather prediction model Lokalmodell (LM) of the German Meteorological Service is investigated. The area of interest is the LITFASS area during the LITFASS-2003 campaign. Based on simulations with varying soil and vegetation properties, we confirm that simulated latent heat fluxes strongly depend on soil moisture and leaf area index. Both parameters are difficult to obtain from in situ measurements with sufficient spatial resolution over heterogeneous land surfaces. Therefore, a procedure is proposed to determine area average values of soil moisture from time domain reflectometer measurements performed at a limited number of sites. The area averages cover the 7 × 7 km² grid cells of the LM around Lindenberg (south-east of Berlin). Furthermore, satellite inferred plant parameters from NOAA–AVHRR are used to initialise model runs; the derived vegetation parameters show notable differences with those in the standard input of LM. The latent heat fluxes from the LM are compared with the aggregated eddy-covariance-measurements, and while the operational LM shows a strong overestimation of latent heat fluxes, it is demonstrated that the application of land-surface parameters derived from measurements can significantly reduce the deviation between the simulated and measured latent heat fluxes.     

Determination of geometrical spreading from traveltimes

Geometrical spreading plays an important role for amplitude preserving migration, which is a very time-consuming process. In order to achieve efficiency in terms of computational time and, particularly, storage space, we propose a method to determine geometrical spreading from coarsely gridded traveltime tables. The method is based on a hyperbolic traveltime expansion and provides also a fast and accurate algorithm for the interpolation of traveltimes, including the interpolation of complete shots. Examples demonstrate the applicability of the method to isotropic and anisotropic media.     

Las Matras Block, Central Argentina (37°S-67°W): the Southernmost Cuyania Terrane and its Relationship with the Famatinian Orogeny

The Las Matras Block in Central Argentina constitutes the southernmost part of the Cuyania terrane, which was accreted to the southwestern margin of Gondwana during the Early to Mid Ordovician Famatinian orogeny. The Grenville-aged rocks of the Las Matras Block are represented by the tonalitic to trondhjemitic Las Matras pluton. A new U-Pb conventional zircon age of 1244±42 Ma confirms previous Sm-Nd and Rb-Sr isochron ages of this pluton. Mineral composition data are consistent with the tonalitic-trondhjemitic character of the pluton, and constrain its emplacement level to 1.9 to 2.6 kb. This shallow level of emplacement and the undeformed character of the pluton are distinctive features of this southernmost basement. A regional comparison indicates that the igneous-metamorphic evolution of the Grenville-aged basement rocks of the Cuyania terrane occurred over a period of more than 200 million years, with ages older than 1200 Ma up to those close to 1000 Ma. The shallowest crustal level is found in Las Matras, suggesting a southward shallowing of the exposed level of basement. The deformation and metamorphism associated with the collisional Famatinian orogeny affect both the Cuyania terrane and the adjacent western margin of Gondwana, and the Gondwana margin was also the locus of the related arc magmatism, but the compressive effects of the collision decrease in intensity toward the south. The Famatinian metamorphism and magmatism continue even further south into the Patagonia region, but the southern continuity of the Cuyania terrane into this region remains uncertain.     

Deglacial and postglacial climate history in east-central Isla Grande de Chiloé, southern Chile (43°S)

Palynologic and stratigraphic data from Laguna Tahui (42°50′S, 73°30′W) indicate cool-temperate and humid conditions there between 14,000 and 10,000 ¹⁴C yr B.P., followed by warmer and drier-than-present conditions between 10,000 and 7000 ¹⁴C yr B.P., and subsequent cooling and rise in precipitation over the last 5800 ¹⁴C yr. The thermophilous Valdivian trees Eucryphia cordifolia and Caldcluvia paniculata reached their maximum abundance during the early Holocene warm-dry phase (10,000-7000 ¹⁴C yr B.P.), followed by a rise in lake levels and reexpansion of North Patagonian conifers starting at 7000 and 5800 ¹⁴C yr B.P., respectively. Variations in the stratigraphic and geographic distribution of temperate rainforests in southern Chile suggest multimillennial trends in temperature and westerly activity, which are spatially and temporally coherent with paleoclimate records from neighboring regions. Climate variability at millennial and submillennial time scales may account for the establishment and persistence of fine-scale mosaics of Valdivian and North Patagonian rainforest species in low- to mid-elevation communities since ∼5800 ¹⁴C yr B.P.     

The structure and the phyllosilicates (chemistry, crystallinity and texture) of Talas Ala-Tau (Tien Shan, Kyrgyz Republic): comparison with more recent subduction complexes

Geological mapping and structural analysis of the Talas Ala Tau (Tien Shan, Kyrgyz Republic) have revealed a complex structure composed of folds with axial-plane cleavage and thrust faults verging towards the NE. The main structures of the range correspond to minor Tertiary and Carboniferous–Permian deformation superimposed on the main deformation event that took place during the Baikalian orogeny. The pervasive axial-plane cleavage diminishes in penetrativity from the hinterland to the foreland in both the Uzunakhmat and Karagoin sheets. The main thrusts developed phyllonitic shear-related rocks on the hangingwall immediately above the thrust planes. A crystal-chemical study of the phyllosilicates growth during the Baikalian deformation event along a cross-section revealed changes in the crystallinity, composition and lattice parameters of them. The phyllosilicates present in the Talas Ala Tau rocks were crystallized in very low-grade metamorphic conditions, that is below 300 °C, as indicated by their Kübler Index (KI), which decreases from SW towards the NE. Detailed TEM study of the phyllosilicates reveals a clear textural difference at the lattice level between samples with higher or lower KI parameters. There is also a clear difference in crystal-chemical parameters (KI and b) and composition between the phyllosilicates growth in relation to the axial-plane cleavage and the ones belonging to the thrust-related phyllonites. The first ones are more affected by the ferrimuscovitic vector than the phyllosilicates of phyllonites, closer to the theoretical phengitic component. Huge ranges of values of phengitic content of micas at sample level are interpreted as the result of a decompression path from at least 8 kbar. We propose a subduction geodynamic environment for the regional deformation and the origin of the phyllosilicates, as they are similar to those obtained in more recent accretionary complexes.     

Critical shear stress for mechanical twinning of jadeite—an experimental study

Coarse-grained natural jadeitite samples from Myanmar were experimentally deformed in a Griggs-type solid-medium apparatus at strain rates of 2·10⁻⁵ and 5·10⁻⁶ s⁻¹ and temperatures of 900 and 1000 °C. The microfabrics of the deformed samples are investigated by scanning electron microscopy (SEM) using the electron backscatter diffraction (EBSD) technique. The critical shear stress for twinning in the (100) [001] system is derived from the orientation distribution of jadeite crystals with and without mechanical twins. The results indicate a homogeneous stress field within the sample and a critical shear stress of 150±25 MPa, which compares well to that determined by Kollé and Blacic [J. Geophys. Res. 87 (1982) 4019] for mechanical twinning of other clinopyroxenes. With the critical shear stress known, mechanical twinning of jadeite can be used as a paleopiezometer for high stress tectonic environments.     

Evolutionary synthesis of stellar populations: a modular tool

A new tool for the evolutionary synthesis of stellar populations is presented, which is based on three independent matrices, giving respectively (1) the fuel consumption during each evolutionary phase as a function of stellar mass, (2) the typical temperatures and gravities during such phases, and (3) the colours and bolometric corrections as functions of gravity and temperature. The modular structure of the code allows one easily to assess the impact on the synthetic spectral energy distribution of the various assumptions and model ingredients, such as, for example, uncertainties in stellar evolutionary models, the mixing length, the temperature distribution of horizontal branch stars, asymptotic giant branch mass loss, and colour–temperature transformations. The so-called 'AGB phase transition' in Magellanic Cloud clusters is used to calibrate the contribution of the thermally pulsing asymptotic giant branch phase to the synthetic integrated luminosity. As an illustrative example, solar-metallicity ( Y  = 0.27, Z  = 0.02) models, with ages ranging between 30 Myr and 15 Gyr and various choices for the slope of the initial mass function, are presented. Synthetic broad-band colours and the luminosity contributions of the various evolutionary stages are compared with Large Magellanic Cloud and Galactic globular cluster data. In all these cases, a good agreement is found. Finally, the evolution is presented of stellar mass-to-light ratios in the bolometric and U B V R K passbands, in which the contribution of stellar remnants is accounted for.     

Effect of degassing on sulfur contents and δ34S values in Somma-Vesuvius magmas

Sulfur contents and δ³⁴S values of Somma-Vesuvius magmas are consistent with syneruptive, open-system degassing at temperatures of 800–850°C for Plinian pumices and 1100–1200°C for lavas. The extent of degassing appears to be greater in lavas than in pumices. The key parameter controlling the ³⁴S/³²S ratio of Somma-Vesuvius volcanics is the average magma oxidation state, which generally varies from 0.85 to 1.20 Δ NNO units for lavas and from 1.20 to 1.40 Δ NNO units for pumices. Consequently, S contents and δ³⁴S values of magmas constitute a potentially valuable tool in estimating their average redox conditions. The results of this study may help in risk mitigation when the Vesuvius magmatic system evolves toward eruptive conditions. Received: 20 January 1998 / Accepted: 5 May 1998