苏皖凹凸棒石矿物红外光谱特征研究

苏皖凹凸捧石粘土矿物包括沉积、风化及火山碎屑蚀变三种成因类型。成矿物质来源于内陆浅水湖盆水下玄武岩风化蚀变及地表玄武岩的风化。不同成因类型的凹凸棒石在矿物晶体结晶程度上有较大差异。通常,由风化作用生成并与碳酸盐共生的沉积型凹凸棒石结晶程度低,较纯的并与硅质岩共生的沉积型凹凸棒石结晶程度高。它们在红外吸收光谱特征上表现为:前者红外振动吸收带分裂程度低,吸收峰弱且峰形钝。后者红外振动吸收带分裂程度高,吸收峰尖锐。因此研究凹凸捧石的红外吸收光谱特征可基本上区分出它们的成因类型。本文还对凹凸棒石红外吸收光谱振动波数带进行了划分,并对相应的振动类型作了探讨。     

Valency Study of Vanadium in Stone Coal Ash of Jiangxi Province

Vanadium-bearing stone coal is a new vanadium resource;recovery ofV_2O_5 from the coal has been investigated.It has been found that a satisfactoryextraction of V_2O_5 depends on both the oxidation of V and its reaction with so-dium salt.V in the coal ash of Yushan mainly exists in two oxidation states:98％V(Ⅲ)and2％V(Ⅳ).The distribution of valency of V shows that organicmatter determines V valency at low temperatures,at about470℃,V(Ⅲ)iscompletely oxidized to V(Ⅳ);above500℃,the temperature is the most impor-tant factor for the oxidation of V .At higher temperatures no more V is oxidizedto V(Ⅴ);an equilibrium is established after92％of V is oxidized to V(Ⅴ).The roles of NaCl in the recovery of V_2O_5 from the coal ash were discussed.The best conditions for roasting are temperature750-800℃for1 h.underthe oxidation-chlorination atmosphere.When the ore:NaCl=100:10 by weight,η_roast reaches85.5％.According to the results,a flowsheet for V_2O_5 extrac-tion from coal ash has been proposed.     

X射线荧光技术用于西秦岭地区金矿勘查

本文根据用轻便型X射线荧光仪在西秦岭数个金异常区测量金的伴生元素——砷的荧光强度,间接找寻金矿的实践,阐明用该仪器可快速圈定金矿远景区和揭示隐伏金矿体,提高找矿效果。并对使用X射线荧光技术进行现场测量及配合金异常查证工作,作了初步探讨。     

柴达木盆地及邻区主要活动断裂及其与地震的关系

本文根据野外调查资料及重力、航磁等资料,对柴达木盆地及其邻区的主要活动断裂的大地构造位置、产状、深度和第四纪活动特点等进行了分析研究,並讨论了这些断裂与地震活动的关系。这一地区的地震活动强度与断裂深度有关,具左旋运动特征的全新世近东西向活断层与强地震活动的关系最为密切。     

地球化学计算中误差传递分析的应用

通过两个实例讨论了地球化学计算中的误差传递问题,对照了四种不同方法的潜力和限制,拓广了蒙特卡洛方法在相关变量分析中的应用,指出其在不同条件下总能用有限机时逼近合理结果,揭示出协方差矩阵法的特殊效益,可相对于独立初始变量展现中间变量的相关关系。     

The Discovery and Study of Mantle-Derived Dunite Inclusions in Hornblende-Diorite in the Handan-Xingtai Area,Hebei

Phlogopiie-and diopside-bearing dunite occurs as rounded inclusions in hornblende-diorite. Thepetrofabrics, mineral composition and abundances of the trace elements in the dunite indicate that the inclu-sions were derived from the upper mantle and are the residues of high-degree partial melting of mantlepeirdotite. The study of trace elements in the inclusions and their host rocks shows that the magma was origi-nated from the mantle which was enriched in incompatible elements by mantle metasomatism prior to the par-tial melting.     

湖南香花岭复式碱长花岗岩体侵入期次关系的识别

香花岭碱长花岗岩为一复式岩体。不同期次侵入体之间的接触关系、白色和绿色含铍条纹岩以及磁铁矿条纹岩与不同期次侵入体之间的对应关系、通天庙、塘官铺、太平和新风不同矿化组合与不同期次侵入体之间的成因联系以及遥感图像中的环形构造特点和差异明显的Rb-Sr同位素等时年龄表明该岩体是两期四次碱长花岗质岩浆侵入作用的产物,燕山早期的三次岩浆侵入与本区矿化关系密切;而燕山晚期的一次岩浆侵入与矿化无关。上述认识可对矿区的某些地质问题作出合理的解释。     

矿物包裹体中水溶气体成分的物理化学参数图解

本文计算出1m～3mNaCl体系.温度为100～500℃条件下CO_2、CH_4、H_2、CO、N_2、H_2S和SO_2亨利常数,以及上述成分在100～350℃时的分配系数和气、液平衡常数.并设计出矿物包裹体中水溶气体的lgfo_2—T、lgf_(co)-T、lgf_(co)-T和lgf_(co)-pH等物理化学参数图,解析了江西茅坪锡矿床中石英和锡石的矿物包裹体形成的物理化学条件.