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51.
An Analysis Platform for Multiscale Hydrogeologic Modeling with Emphasis on Hybrid Multiscale Methods 下载免费PDF全文
Timothy D. Scheibe Ellyn M. Murphy Xingyuan Chen Amy K. Rice Kenneth C. Carroll Bruce J. Palmer Alexandre M. Tartakovsky Ilenia Battiato Brian D. Wood 《Ground water》2015,53(1):38-56
One of the most significant challenges faced by hydrogeologic modelers is the disparity between the spatial and temporal scales at which fundamental flow, transport, and reaction processes can best be understood and quantified (e.g., microscopic to pore scales and seconds to days) and at which practical model predictions are needed (e.g., plume to aquifer scales and years to centuries). While the multiscale nature of hydrogeologic problems is widely recognized, technological limitations in computation and characterization restrict most practical modeling efforts to fairly coarse representations of heterogeneous properties and processes. For some modern problems, the necessary level of simplification is such that model parameters may lose physical meaning and model predictive ability is questionable for any conditions other than those to which the model was calibrated. Recently, there has been broad interest across a wide range of scientific and engineering disciplines in simulation approaches that more rigorously account for the multiscale nature of systems of interest. In this article, we review a number of such approaches and propose a classification scheme for defining different types of multiscale simulation methods and those classes of problems to which they are most applicable. Our classification scheme is presented in terms of a flowchart (Multiscale Analysis Platform), and defines several different motifs of multiscale simulation. Within each motif, the member methods are reviewed and example applications are discussed. We focus attention on hybrid multiscale methods, in which two or more models with different physics described at fundamentally different scales are directly coupled within a single simulation. Very recently these methods have begun to be applied to groundwater flow and transport simulations, and we discuss these applications in the context of our classification scheme. As computational and characterization capabilities continue to improve, we envision that hybrid multiscale modeling will become more common and also a viable alternative to conventional single‐scale models in the near future. 相似文献
52.
Heterogeneous distributions of CO2 may be more important for dissolution and karstification in coastal eogenetic limestone than mixing dissolution 下载免费PDF全文
Jason D. Gulley Jonathon B. Martin Paul J. Moore Amy Brown Patricia D. Spellman John Ezell 《地球表面变化过程与地形》2015,40(8):1057-1071
Mixing dissolution, a process whereby mixtures of two waters with different chemical compositions drive undersaturation with respect to carbonate minerals, is commonly considered to form cavernous macroporosity (e.g. flank margin caves and banana holes) in eogenetic karst aquifers. On small islands, macroporosity commonly originates when focused dissolution forms globular chambers lacking entrances to the surface, suggesting that dissolution processes are decoupled from surface hydrology. Mixing dissolution has been thought to be the primary dissolution process because meteoric water would equilibrate rapidly with calcium carbonate as it infiltrates through matrix porosity and because pCO2 was assumed to be homogeneously distributed within the phreatic zone. Here, we report data from two abandoned well fields in an eogenetic karst aquifer on San Salvador Island, Bahamas, that demonstrate pCO2 in the phreatic zone is distributed heterogeneously. The pCO2 varied from less than log ?2.0 to more than log ?1.0 atm over distances of less than 30 m, generating dissolution in the subsurface where water flows from regions of low to high pCO2 and cementation where water flows from regions of high to low pCO2. Using simple geochemical models, we show dissolution caused by heterogeneously distributed pCO2 can dissolve 2.5 to 10 times more calcite than the maximum amount possible by mixing of freshwater and seawater. Dissolution resulting from spatial variability in pCO2 forms isolated, globular chambers lacking initial entrances to the surface, a morphology that is characteristic of flank margin caves and banana holes, both of which have entrances that form by erosion or collapse after cave formation. Our results indicate that heterogeneous pCO2, rather than mixing dissolution, may be the dominant mechanism for observed spatial distribution of dissolution, cementation and macroporosity generation in eogenetic karst aquifers and for landscape development in these settings. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
53.
以中天山东段的天湖东铁钼矿含矿花岗岩为例,在LA-ICP-MS锆石U-Pb年代学测定其为早古生代花岗岩((445.3±4.6) Ma)基础上,通过岩相学、地球化学及锆石原位Hf同位素组成等多方面研究,探讨该岩体的成岩作用及其构造背景。天湖东含矿片麻状花岗岩的主要矿物为斜长石、石英、钾长石,并含少量黑云母和角闪石等。全岩地球化学分析结果表明,该片麻状花岗岩高硅、弱富铝、富钙、富钠而贫钾,ASI值为0.68~0.82,属于准铝质钙碱性花岗岩,总体上富集大离子亲石元素(LILE)Rb、Ba等和轻稀土元素La、Ce、Nd等,而亏损高场强元素Nb、Ta、Ti、Yb等,轻重稀土分异明显,轻稀土分异较为明显,而重稀土分异不明显,表现出典型岛弧岩浆岩的地球化学特征。锆石的εHf(445 Ma)值为-6.31~-1.77,二阶段Hf模式年龄(TDM2)为1.538~1.825 Ga,表明该花岗岩的源区主要为壳源物质。综合分析上述资料,认为天湖东铁钼矿片麻状花岗岩是由俯冲过程中地壳物质重熔的产物。结合前人的研究和本课题组的新近研究成果认为,在早古生代时,中天山为岩浆弧构造环境,形成一系列的钙碱性岩浆岩,而该岩浆弧的形成可能是受到介于吐哈陆块和塔里木板块之间的古天山大洋在早古生代时期向南俯冲而形成的。 相似文献
54.
Social memory and resilience in New Orleans 总被引:1,自引:1,他引:0
A key concept in resilience studies is that human societies can learn from hazard events and use their accumulated social
memory to better contend with future catastrophes. This article explores the deliberate referral to historical records complied
after Hurricane Betsy in 1965 and how they were used to prepare for tropical storms at the time of Hurricane Katrina in 2005.
Despite proclamations that Louisiana would not repeat its mistakes, hazards planners seriously neglected the historical record. 相似文献
55.
We examined the effects of the presence of larval conspecifics on larval vertical distribution of four‐arm and six‐arm plutei of Strongylocentrotus droebachiensis and bipinnaria of Asterias rubens, in laboratory experiments, by manipulating population density. Larvae were introduced to experimental columns (10 × 10 × 30 cm) at one of two or three population densities (S. droebachiensis: 0.1 and 10 larvae·ml?1; A. rubens: 0.1, 1 and 10 larvae·ml?1). Subsequent changes in vertical distribution were determined from images of the larvae in the columns illuminated by a 532‐nm laser and captured by a high‐resolution camera. Larvae of both species were found higher in the water column in the high than in the low and intermediate population densities. The relationship between vertical swimming velocity and nearest neighbour distance (NND) was measured for four‐arm plutei of S. droebachiensis, and used to determine a range in distances among individuals that may affect potential interactions. The variation in swimming velocity decreased with increasing proximity below a threshold distance among individuals of 10 mm, which was greater than the estimated distance in the high population density. We suggest that the increased larval aggregation near the water surface under high population density is the result of a behavioural response to conspecifics. 相似文献
56.
Organic carbon inputs,common ions and degassing: rethinking mixing dissolution in coastal eogenetic carbonate aquifers 下载免费PDF全文
Caves deliver freshwater from coastal carbonate landscapes to estuaries but how these caves form and grow remains poorly understood. Models suggest fresh and salt water mixing drives dissolution in eogenetic limestone, but have rarely been validated through sampling of mixing waters. Here we assess controls on carbonate mineral saturation states using new and legacy geochemical data that were collected in vertical profiles through three cenotes and one borehole in the Yucatan Peninsula. Results suggest saturation states are primarily controlled by carbon fluxes rather than mixing. Undersaturation predicted by mixing models that rely on idealized end members is diminished or eliminated when end members are collected from above and below actual mixing zones. Undersaturation due to mixing is limited by CO2 degassing from fresh water in karst windows, which results in calcite supersaturation. With respect to saline groundwater, controls on capacity for mixing dissolution were more varied. Oxidation of organic carbon increased pCO2 of saline groundwater in caves (pCO2 = 10–2.06 to 10–0.96 atm) relative to matrix porosity (10–2.39 atm) and local seawater (10–3.12 atm). The impact of increased pCO2 on saturation state, however, depended on the geochemical composition of the saline water and the magnitude of organic carbon oxidation. Carbonate undersaturation due to mixing was limited where gypsum dissolution (Cenote Angelita) or sulfate reduction (Cenote Calica) increased concentrations of common ions (Ca2+ or HCO3?, respectively). Maximum undersaturation was found to occur in mixtures including saline water that had ion concentrations and ratios similar to seawater, but with moderately elevated pCO2 (Cenote Eden). Undersaturation, however, was dominated by the initial undersaturation of the saline end member, mixing was irrelevant. Our results add to a growing body of literature that suggests oxidation of organic carbon, and not mixing dissolution, is the dominant control on cave formation and enlargement in coastal eogenetic karst aquifers. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
57.
In the recent past, Australia has experienced several catastrophic hazard events and the frequency and intensity of such events is expected to increase in the future. Natural hazards can rarely be fully prevented, yet their losses can be minimized if the necessary preparedness and mitigation actions are taken before an event occurs. Identification of vulnerable groups is an important first step in any preparedness and emergency management planning process. Social vulnerability refers to population characteristics that influence the capacity of a community to prepare for, respond to and recover from disasters. Factors that contribute to social vulnerability are often hidden and difficult to capture. This study analyzes the relative levels of social vulnerability of communities at the urban?Cbush interface in the Blue Mountains and Ku-ring-gai local council areas in New South Wales (NSW), Australia. We tested whether a standardized social vulnerability index could be developed using a pre-existing set of indicators. We created an exploratory principle component analysis model using Australian Bureau of Statistics 2006 census data at the Census Collection District (CCD) level. We identified variables contributing to social vulnerability and used the component scores to develop a social vulnerability index. Finally, the social vulnerability index was mapped at the CCD level. Our results indicate that both contributors to and the level of social vulnerability differ between and within communities. In other words, they are spatially variable. They show different spatial patterns across the areas, which provides useful information for identifying communities that are most likely to experience negative disaster impacts due to their socio-demographic characteristics. 相似文献
58.
O'Leary BC Smart JC Neale FC Hawkins JP Newman S Milman AC Roberts CM 《Marine pollution bulletin》2011,62(12):2642-2648
We analysed the extent to which European politicians have adhered to scientific recommendations on annual total allowable catches (TACs) from 1987 to 2011, covering most of the period of the Common Fisheries Policy (CFP). For the 11 stocks examined, TACs were set higher than scientific recommendations in 68% of decisions. Politically-adjusted TACs averaged 33% above scientifically recommended levels. There was no evidence that the 2002 reform of the CFP improved decision-making, as was claimed at the time. We modelled the effects of such politically-driven decision-making on stock sustainability. Our results suggest that political adjustment of scientific recommendations dramatically increases the probability of a stock collapsing within 40 years.In 2012 European fisheries policy will undergo a once-a-decade reform. Ten years ago radical reforms were promised but the changes failed to improve sustainability. It is likely that the 2012 reform will be similarly ineffective unless decision-making is changed so that catch allocations are based on science rather than politics. 相似文献
59.
Paul A. Bukaveckas Amy MacDonald Anthony Aufdenkampe John H. Chick John E. Havel Richard Schultz Ted R. Angradi David W. Bolgrien Terri M. Jicha Debra Taylor 《Aquatic Sciences - Research Across Boundaries》2011,73(3):419-436
Main channel habitats of the Ohio, Missouri, and Upper Mississippi Rivers were surveyed during the summers of 2004, 2005 and
2006 using a probability-based sampling design to characterize inter-annual and inter-river variation in suspended chlorophyll
a (CHLa) and related variables. Large (fivefold) differences in CHLa were observed with highest concentrations in the Upper
Mississippi (32.3 ± 1.8 μg L−1), intermediate values in the Missouri (19.7 ± 1.1 μg L−1) and lowest concentrations in the Ohio (6.8 ± 0.5 μg L−1). Inter-annual variation was small in comparison to inter-river differences suggesting that basin-specific factors exert
greater control over river-wide CHLa than regional-scale processes influencing climate and discharge. The rivers were characterized
by variable but generally low light conditions as indicated by depth-averaged underwater irradiance <4 E m−2 day−1 and high ratios of channel depth to euphotic depth (>3). Despite poor light conditions, regression analyses revealed that
TP was the best single predictor of CHLa (R
2 = 0.40), though models incorporating both light and TP performed better (R
2 = 0.60). Light and nutrient conditions varied widely within rivers and were inversely related, suggesting that riverine phytoplankton
may experience shifts in resource limitation during transport. Inferred grazing and sedimentation losses were large yet CHLa
concentrations did not decline downriver indicating that growth and loss processes were closely coupled. The contribution
by algae to suspended particulate organic matter in these rivers (mean = 41%) was similar to that of lakes (39%) but lower
relative to reservoirs (61%). 相似文献
60.
Amy Gartman Mustafa Y��cel Andrew S. Madison David W. Chu Shufen Ma Christopher P. Janzen Erin L. Becker Roxanne A. Beinart Peter R. Girguis George W. Luther III 《Aquatic Geochemistry》2011,17(4-5):583-601
The sulfide (H2S/HS?) that is emitted from hydrothermal vents begins to oxidize abiotically with oxygen upon contact with ambient bottom water, but the reaction kinetics are slow. Here, using in situ voltammetry, we report detection of the intermediate sulfur oxidation products polysulfides [ $ {\text{S}}_{\text{x}}^{2 - } $ ] and thiosulfate [ $ {\text{S}}_{ 2} {\text{O}}_{ 3}^{ 2- } $ ], along with contextual data on sulfide, oxygen, and temperature. At Lau Basin in 2006, thiosulfate was identified in less than one percent of approximately 10,500 scans and no polysulfides were detected. Only five percent of 11,000 voltammetric scans taken at four vent sites at Lau Basin in May 2009 show either thiosulfate or polysulfides. These in situ data indicate that abiotic sulfide oxidation does not readily occur as H2S contacts oxic bottom waters. Calculated abiotic potential sulfide oxidation rates are <10?3 ??M/min and are consistent with slow oxidation and the observed lack of sulfur oxidation intermediates. It is known that the thermodynamics for the first electron transfer step for sulfide and oxygen during sulfide oxidation in these systems are unfavorable, and that the kinetics for two electron transfers are not rapid. Here, we suggest that different metal catalyzed and/or biotic reaction pathways can readily produce sulfur oxidation intermediates. Via shipboard high-pressure incubation experiments, we show that snails with chemosynthetic endosymbionts do release polysulfides and may be responsible for our field observations of polysulfides. 相似文献