Effect of $$\hbox {CO}_2$$ solubility on dissolution rate of calcite in saline aquifers for temperature range of 50–100 $$^{\circ } \hbox {C}$$∘C and pressures up to 600 bar: alterations of fractures geometry in carbonate rocks by $$\hbox {CO}_2$$-acidified brines

An empirical model is developed to predict the dissolution rate of calcite in saline solutions that are saturated with respect to dissolved \(\hbox {CO}_2\) over a broad range of both subcritical and supercritical conditions. The focus is on determining the rate of calcite dissolution within a temperature range of 50–100 \(^\circ \hbox {C}\) and pressures up to 600 bar, relevant for \(\hbox {CO}_2\) sequestration in saline aquifers. A general reaction kinetic model is used that is based on the extension of the standard Arrhenius equation with an added, solubility-dependent, pH term to account for the saturated concentration of dissolved \(\hbox {CO}_2\). On the basis of this kinetic model, a new rate equation is obtained using multi-parameter, nonlinear regression of experimental data to determine the dissolution of calcite as a function of temperature, pressure and salinity. Different models for the activity coefficient of \(\hbox {CO}_2\) dissolved in saline solutions are accounted for. The new rate equation helps us obtain good agreement with experimental data, and it is applied to study the geochemically induced alterations of fracture geometry due to calcite dissolution.     

Impact of tailings dam failure on spatial features of copper contamination (Mazraeh mine area,Iran)

Mining activities pose a potential risk of metal contamination around mining sites. On May 6, 2010, a tailings dam failure of the Mazraeh copper mine near Ahar in East Azerbaijan province, Iran, released vast amounts of mine wastes. To better understand the magnitude of copper contamination in the waste-affected soils, it is important to assess the spatial distribution of soil copper content at unsampled points. A total of 30 soil samples and their surficial sediments together with the 6 uncontaminated control samples (0–10 and 10–30 cm) were collected along the stream flow that joined Ahar-Chai River. Some of soil properties as well as total copper concentration were determined in all samples. The mean value of the latter in the surface contaminated soils was found to be approximately two times more than controls. Furthermore, the mean concentration of copper in the surface loaded material was 10 times more than the soils. High copper concentrations were observed in surficial sediments of the soils near the broken tailings dam. The Inverse Distance Weighting (IDW) method was employed in data analysis. The spherical and Gaussian semivariogram models were properly fitted to the data of copper contents in soils and surficial sediments.     

Study on the improving method for gas production prediction in tight clastic reservoir

Relative permeability and resistivity index are important parameters for the exploration and development in a tight sandstone gas field. In the splitting method which uses permeability (K), reservoir thickness (H), and relative permeability (K), briefly referred to as the KHK splitting method, the accuracy of the relative permeability is crucial. According to the relationship between resistivity index and relative permeability of the Mesozoic Lower Safa Formation at Obaiyed Field in the Western Desert of Egypt, we improved the split method and made it more in line with the real situation by adopting Pairoys’ model which is more suitable to our study area. In this paper, we use a radial basis function (RBF) to establish the relationship between logging data and the gas production split point to point in tight sandstone gas reservoirs. To compare with the result by support vector regression (SVR), our method is better as indicated by mean absolute error values. In order to solve the problem that the relative permeability is difficult to obtain in the well logging evaluation, we also provide a convenient method and application example.     

Preservation of organic matter in soils of a climo-biosequence in the Main Range of Peninsular Malaysia

Limited information is available about factors of soil organic carbon(SOC) preservation in soils along a climo-biosequence. The objective of this study was to evaluate the role of soil texture and mineralogy on preservation of SOC in the topsoil and subsoil along a climo-biosequence in the Main Range of Peninsular Malaysia. Soil samples from the A and B-horizons of four representative soil profiles were subjected to particle-size fractionation and mineralogical analyses including X-ray diffraction and selective dissolution. The proportion of SOC in the 250-2000 μm fraction(SOC associated with coarse sand) decreased while the proportion of SOC in the 53 μm fraction(SOC associated with clay and silt)increased with depth. This reflected the importance of the fine mineral fractions of the soil matrix for SOC storage in the subsoil. Close relationships between the content of SOC in the 53 μm fraction and the content of poorly crystalline Fe oxides [oxalate-extractable Fe(Fe_o) – pyrophosphate-extractable Fe(Fe_p)] and poorly crystalline inorganic forms of Al [oxalateextractable Al(Al_o) – pyrophosphate-extractable Al(Al_p)] in the B-horizon indicated the importance of poorly crystalline Fe oxides and poorly crystalline aluminosilicates for the preservation of SOC in the Bhorizon. The increasing trend of Fe_o-Fe_p and Al_o-Al_p over elevation suggest that the importance of poorly crystalline Fe oxides and poorly crystalline aluminosilicates for the preservation of SOC in the Bhorizon increased with increasing elevation. This study demonstrates that regardless of differences in climate and vegetation along the studied climobiosequence, preservation of SOC in the subsoil depends on clay mineralogy.     

The nonlinear association between the Arctic Oscillation and North American winter climate

Nonlinear projections of the Arctic Oscillation (AO) index onto North American winter (December–March) 500-mb geopotential height (Z500) and surface air temperature (SAT) anomalies reveal a pronounced asymmetry in the atmospheric patterns associated with positive and negative phases of the AO. In a linear view, the Z500 anomaly field associated with positive AO resembles a positive North Atlantic Oscillation pattern with statistically significant positive and negative anomalies stretching zonally into central-eastern USA and Canada, respectively, resulting in a cold climate anomaly over northeastern and eastern Canada, Alaska and the west coast of USA, and a warm climate anomaly over the rest of the continent. By contrast, the nonlinear behavior, mainly a quadratic association with AO, which is most apparent when the amplitude of the AO index is large, has the same spatial pattern and sign for both positive and negative values of the index. The nonlinear pattern reveals negative Z500 anomalies over the west coast of USA and the North Atlantic and positive Z500 anomalies at higher latitudes centered over the Gulf of Alaska and northeastern Canada accompanied by cooler than normal climate over the USA and southwestern Canada and warmer than normal climate over other regions of the continent. A similar analysis is conducted on the data from the Canadian Center for Climate Modelling and Analysis second generation coupled general circulation model. The nonlinear patterns of North American Z500 and SAT anomalies associated with the AO in the model simulation are generally consistent with the observational results, thereby confirming the robustness of the nonlinear behavior of North American winter climate with respect to the AO in a climate simulation that is completely independent of the observations.     

Monitoring of playa evaporites as seen with optical remote sensing sensors: case of Chott El Jerid,Tunisia, from 2003 to present

Chott El Jerid in the Zone of Chotts of Tunisia is one of the largest endorheic basins in the world. During the dry period, from May to August, it is generally covered by continental evaporites which result from the desiccation of the lake formed after a flooding event. This lake comprises runoff water from the surrounding relief and also water resurgence. In order to map and monitor these evaporitic surfaces (mineral composition and evolution in space and time), optical multisource, multispectral, and multidate satellite data have been used. Landsat 4–5 TM, Landsat 8 OLI, SPOT 6, and Landsat Surface Reflectance (LSR) constitute the main data set. The central part of the Chott, north and south of the road crossing the Chott over 70 km from Tozeur to Kebili, has been particularly studied, because it corresponds to the major evaporite accumulation zone. These evaporites precipitated as concentric layers (a relatively rare pattern), mainly north of the road, after several recent flooding events during the last 15 years. Winds can play a significant role in the development of the evaporite layers. Image interpretation associated with field data shows that after the final desiccation of the playa lake, the mineralogy of the salt crust comprised an assemblage dominated by halite south of the road and by gypsum north of the road. Halite and gypsum are the only minerals to be identified using satellite remote sensing data. Sulfates such as gypsum can be identified thanks to a drop in reflectance in the short-wave infrared (SWIR) range caused by vibrations of the SO₄ group. Gypsum crusts are more widely distributed than halite crusts. LSR data are particularly suitable for multitemporal comparison because they are calibrated and atmospherically corrected. The classical bull’s eye pattern characterizing evaporitic deposits (from carbonates along the rims to halite, gypsum, and finally potassium-magnesium minerals in the center of the basin) is deeply disturbed by the road crossing Chott El Jerid.     

塔克拉玛干沙漠沙垄起伏地形夏季地表温度差异特征

摘 要：开展塔克拉玛干沙漠沙垄起伏地形夏季地表温度观测试验，旨在为塔克拉玛干沙漠环境陆面过程研究提供科学依据。2019年6月7日至9月2日在塔中地区，沿沙垄迎风坡以及背风坡底部、中部、上部、顶点及垄间谷地共设8个地表温度观测点。结果表明：（1）夏季沙垄地表温度最高温出现在垄间谷地，为74.63 ℃，最低温出现在迎风坡底部，为10.52 ℃；地表温度一天中在7:00左右达到最低，15:00左右达到最高。（2）晴天、多云以及浮尘天各观测点地表温度日均变化曲线呈单峰型，降水、扬沙及沙尘暴天呈双峰型；地表温度的最高温与日均值最大值均出现在晴天的垄间谷地，地表温度的最低温及日均值最小值均出现在降水天的迎风坡底部。（3）沙垄顶点与两个底部最大温差范围是顶点与背风坡底部在晴天的温差范围，为0～18.62 ℃，最小温差范围是顶点与迎风坡底部在降水天的温差范围，为0.01～6.18 ℃；迎风坡和背风坡在晴天地表温度温差范围最大，为0.01～16.93 ℃，在降水天温差范围最小，为0.01～4.15 ℃；顶点与两个底部夏季综合温差范围在0～18.62 ℃，迎风坡与背风坡夏季综合温差范围为0～16.93 ℃。塔克拉玛干沙漠地表温度受典型天气影响变化类型多样，沙垄顶点与底部、迎风坡与背风坡地表温度差异受风力及地形作用明显。     

巴基斯坦近40a气温时空变化特征分析

基于巴基斯坦不同气候区4个代表站(卡拉奇、雅各布阿巴德、奎达、德罗什)1979—2018年地面观测资料和ERA-Interim气温资料,利用一元线性回归、Mann-Kendall突变检验和Morlet小波分析,分析其气温时空变化特征。结果表明:(1)巴基斯坦过去40 a经历了先降温后增温的过程,除北部山区年平均气温增温趋势显著,四季总体都有增温,春秋两季增温趋势显著。巴基斯坦于1998年左右发生气温突变,年平均气温存在4~5、12、20~22和32 a的周期。(2)ERAInterim再分析资料与地面观测数据拟合分析显示两者相关性达到极显著水平,除北部山区外,在大部分区域误差较小,能够较好地反映巴基斯坦气温的变化特征。(3)巴基斯坦年、季平均气温空间分布地带性明显,高温区位于南部印度河平原、三角洲地区,低温区分布在北部山区,年、春季、秋季平均气温变化在空间上总体均呈现明显增长趋势.