Incorporation of chitosan and glass substrate for improvement in adsorption,separation, and stability of TiO<Subscript>2</Subscript> photodegradation

It is demonstrated that single titanium dioxide (TiO₂) has high potential for photodegradation of pollutants. However, it is still far from becoming an effective photocatalyst system, due to issues of adsorption process, separation, as well as dissolution. Therefore, this study highlights the high adsorption capacity, simplified separation, and the promising stability of TiO_2(SY) (synthesized via sol–gel method) photocatalyst, fabricated using chitosan–TiO_2(SY) and supported by glass substrate (Cs–TiO_2(SY)/glass substrate) photocatalysts. Chitosan (Cs), with abundant –R–NH and NH₂ groups, promotes the adsorption sites of methyl orange (MO) and OH groups for major attachment to TiO_2(SY). Meanwhile, the glass substrate increases stability and assists separation of the photocatalysts. Initially, nano-TiO_2(SY) has been characterized using high-resolution transmission electron microscope. Cs–TiO_2(SY)/glass substrate was fabricated via dip-coating. The distribution and interface between the photocatalytic components were characterized by Fourier transform infrared absorption spectroscopy, UV–Vis diffuse reflectance spectroscopy, field emission scanning electron microscopy, and energy-dispersive spectrometer. UV–Vis analysis of the multilayer photocatalyst (2, 4, 6, and 8 layers) was further carried out by the adsorption–photodegradation, with MO as model of pollutant. Seventy percent of the total removal of MO via optimized eight layers of photocatalyst was achieved within 1 h of UV irradiation. The adsorption photocatalyst achieved 50 % with no exposure to UV light for 15 min of irradiation. It is concluded that suitable photocatalytic conditions and sample parameters possessing the multilayer photocatalyst of Cs–TiO_2(SY) are beneficial toward the adsorption–photodegradation process in wastewater treatment.     

Early Eocene planktonic and benthic foraminifera from the Khangiran formation (northeast of Iran)

The Kopet-Dagh sedimentary basin is located in northeast of Iran and southeast of Turkmenistan in the Middle East. The Khangiran formation represents the last marine deposition in the Kopet-Dagh sedimentary basin. The early Eocene planktonic and benthic foraminifera from the Khangiran formation which belongs to the lower 376 m thickness of this formation are identified and biostratigraphically evaluated. Due to rarity of Morozovella species, planktonic foraminiferal zonation was difficult to determine in this formation. The determination of upper part of the late Paleocene for the lower 124 m of this formation is according to the lowest occurrence of Acarinina sibaiyaensis species. From E₅ to near middle of E₇ biozone, increasing trend of Acarinina frequency and a peak in Morozovella species and decreasing trend of frequency of Subbotina and Pseudohastigerina species indicate the warm and oligotrophic condition of the seawater during sedimentation of the studied interval. Toward the Ypresian-Lutetian boundary, the increasing trend of Pseudohastigerina and Subbotina species and decreasing in frequency of Acarinina species suggest the low-oxygen level, eutrophic and intermediate condition of the seawater. In this formation, the high abundance of the epifaunal taxa such as Anomalinoides spp., Cibicidoides spp., Gyroidinoides spp., and Lenticulina spp. from the base (late Paleocene sediments) up to E₆ biozone reflects oligotrophic and oxic shallow water conditions. The occurrence of several peaks in abundance of Bulimina and Uvigerina species at the Ypresian/Lutetian boundary suggests eutrophic condition. These paleoecological conditions could be correlated with fluctuations in the numbers of the planktonic foraminifera.     

Role of construction of large dams on river morphology (case study: the Karkheh dam in Iran)

Unfortunately in developing countries, human activities without attention to the environmental aspects damage to nature. For example, construction of large dams dries wetlands in southwest of Iran. Also, construction of dams is a very important factor for morphological changes. The case study of this research is downstream of the Karkheh dam. This dam is the largest Earth dam in Iran and locates in southwest of Iran. It was constructed in 1999. Small sinuosity coefficient of zone near to dam has been illustrated by satellite images in 2002 and 2014. This subject shows instability of this part of reach; also, the results of Shulits equation illustrate that this part is instable. But, increasing of morphological characteristics (sinuosity coefficient, central angle, and relative radius) show that stability of this reach is increasing. Surveying confirm this matter and shows that severe erosion in upstream and sedimentation in downstream of reach is finishing. Also, it is observed that flow discharge reduced (?56 %) after construction of dam and average width of river reduced (?21 %) from 2002 to 2014. In the early years after the construction of the dam, sediment discharge reduced considerably (?14 %) from Pay-e-Pol to Abdol Khan hydrometric stations. Increasing of morphological characteristics (especially at zones near to dam) and decreasing changes of bed level (sedimentation and erosion) prove that effects of dam are overcoming on effects of other factors, and these effects are permanent in long term.     

Theory-guided machine learning to predict density evolution of sand dynamically compacted under Ko condition

Acta Geotechnica - This paper introduces a theory-guided machine learning (TGML) framework, which combines a theoretical model (TM) and a machine learning (ML) algorithm to predict compaction...