Characterization of phosphoric acid- and lime-stabilized tropical lateritic clay

The effect of calcium-based stabilizers such as lime on the geotechnical properties of tropical soils has been reported by many researchers. However, the amount of literature available on the micro-structural, molecular, and leaching characteristics of lime and in particular phosphoric acid-stabilized lateritic clays has been limited. This research was carried out in an attempt to identify the time-dependent soil-chemical reactions. In addition, the possible mechanisms that contributed to the stabilization process were discussed in the light of various spectroscopic and microscopic techniques such as X-ray diffractometry (XRD), energy-dispersive X-ray spectrometry (EDAX), field emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FTIR), and nuclear magnetic resonance spectroscopy (NMR) etc. Based on the results it was found that in lime-treated samples, the coating action of free iron oxides on clay particles imposed inhibitive effects on the dissolution of clay alumina. On the other hand, in phosphoric acid-stabilized soil, due to the increase in solubility of metal oxides and also the subsequent release of clay alumina the formation of cementitious compounds were more feasible. From engineering point of view, the phosphoric acid-stabilized lateritic soil showed the highest degree of improvement with an approximately threefold strength increase in comparison with the natural soil over an 8-month curing period.     

Geological and geophysical exploration of the groundwater aquifers of As Suqah area, Makkah district, Western Arabian Shield, Saudi Arabia

As Suqah area is a NW–SE trending wadi present in the west central part of the Arabian Shield. It comprises Precambrian–Cambrian basement rocks, Cretaceous–Tertiary sedimentary succession, Tertiary–Quaternary basaltic lava flows, and Quaternary–Recent alluvial deposits. The magnetic anomalies indicated the presence of many recent local buried faults. These affected the distribution of the clastic sedimentary succession and seem to have controlled the deep groundwater aquifers. Groundwater movement is towards the west and northwest, following in general the surface drainage system. Hydraulic gradient varies greatly from one point to another depending on the pumping rates and cross-sectional area of the aquifer in addition to its transmissivity. The detailed results of the resistivity and seismic measurements were integrated with those obtained from test holes drilled in the study area. Groundwater occurs mainly in two water-bearing horizons, the alluvial deposits and within the clastic sedimentary rocks of Haddat Ash Sham and Ash Shumaysi formations. The shallow zone is characterized with a saturated thickness of 3–20 m and water is found under confined to semi-confined conditions. Water levels were encountered at depths varying from 3 to 16 m in the alluvial wadi deposits and from 18 to 62 m in the sedimentary succession. The combinations of vertical electrical sounding, horizontal electrical profiling, and drilling led to the identification of groundwater resources in the study area. Resistivity soundings clearly identified the nature of the lithological depth and proved useful at identifying water-bearing zones. Significantly, the majority of the groundwater was found within the deep confined aquifer gravelly sandstone, rather than in the shallow unconfined aquifer.     

Adaptation of climate variability/extreme in arid environment of the Arabian peninsula by rainwater harvesting and management

Water management in Saudi Arabia is facing major challenges due to the limited water resources and increasing uncertainties caused by climate change. The rainfall and temperature records of the Saudi meteorological data for more than three decades were analyzed for policy suggestions in water sectors based on the changing rainfall patterns. The trends in the annual aridity and rain indices were also examined to define the changing climate conditions and for determining the dry months in different cities of the Kingdom. An increased annual and maximum rainfall was observed for six cities while a decreasing trend in both annual and maximum rainfall was observed for the same number of cities highlighting the variability of rainfall in the whole region. An increasing maximum rainfall with decreasing annual rainfall was observed for the rest of the cities signifying the more extreme rainfall evens and resulting floods of short durations. The changing rainfall trends were also observed for different months during 31 years of the recorded period in addition to the varying climate pattern for different cities within the same district. Finally, these preliminary assessments of any systematic changes in view of the increased rain intensities and extreme climate events are viewed to demonstrate the value rainwater harvesting and management as a local adaptation to the climate variability and extreme in the Kingdom.     

Integration of ASTER and landsat TM remote sensing data for chromite prospecting and lithological mapping in Neyriz ophiolite zone,south Iran

Chromite deposits in Iran are located in the ophiolite complexes, which have mostly podiform types and irregular in their settings. Exploration for podiform chromite deposits associated with ophiolite complexes has been a challenge for the prospectors due to tectonic disturbance and their distribution patterns. Most of Iranian ophiolitic zones are located in mountainous and inaccessible regions. Remote sensing approach could be applicable tool for choromite prospecting in Iranian ophiolitic zones with intensely rugged topography, where systematic sampling and conventional geological mapping are limited. In this study, Landsat Thematic Mapper (TM) and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) satellite data were used for chromite prospecting and lithological mapping in the Neyriz ophiolitic zone in the south of Iran. Image transformation techniques, namely decorrelation stretch, band ratio and principal component analysis (PCA) were applied to Landsat TM and ASTER data sets for lithological mapping at regional scale. The RGB decorrelated image of Landsat TM spectral bands 7, 5, and 4, and the principal components PC1, PC2 and PC3 image of ASTER SWIR spectral bands efficiently showed the occurrence of major lithological units in the study area at regional scale. The band ratios of 5/3, 5/1, 7/5 applied on ASTER VNIR‐SWIR bands were very useful for discriminating most of rock units in the study area and delineation of the transition zone and mantle harzburgite in the Neyriz ophiolitic complex. Spectral Angle Mapper (SAM) technique was implemented to ASTER VNIR‐SWIR spectral bands for detecting minerals of rock units and especially delineation of the transition zone and mantle harzburgite as potential zones with high chromite mineralization in the Neyriz ophiolitic complex. The integration of information extracted from the image processing algorithms used in this study mapped most of lithological units of the Neyriz ophiolitic complex and identified potential areas of high chromite mineralization (transition zone and mantle harzburgite) for chromite prospecting targets in the future. Furthermore, image processing results were verified by comprehensive fieldwork and laboratory analysis in the study area. Accordingly, result of this investigation indicate that the integration of information extracted from the image processing algorithms using Landsat TM and ASTER data sets could be broadly applicable tool for chromite prospecting and lithological mapping in mountainous and inaccessible regions such Iranian ophiolitic zones.     

Downscaling and projection of precipitation from general circulation model predictors in an equatorial climate region by the automated regression-based statistical method

The authors have applied an automated regression-based statistical method, namely, the automated statistical downscaling (ASD) model, to downscale and project the precipitation climatology in an equatorial climate region (Peninsular Malaysia). Five precipitation indices are, principally, downscaled and projected: mean monthly values of precipitation (Mean), standard deviation (STD), 90th percentile of rain day amount, percentage of wet days (Wet-day), and maximum number of consecutive dry days (CDD). The predictors, National Centers for Environmental Prediction (NCEP) products, are taken from the daily series reanalysis data, while the global climate model (GCM) outputs are from the Hadley Centre Coupled Model, version 3 (HadCM3) in A2/B2 emission scenarios and Third-Generation Coupled Global Climate Model (CGCM3) in A2 emission scenario. Meanwhile, the predictand data are taken from the arithmetically averaged rain gauge information and used as a baseline data for the evaluation. The results reveal, from the calibration and validation periods spanning a period of 40 years (1961–2000), the ASD model is capable to downscale the precipitation with reasonable accuracy. Overall, during the validation period, the model simulations with the NCEP predictors produce mean monthly precipitation of 6.18–6.20 mm/day (root mean squared error 0.78 and 0.82 mm/day), interpolated, respectively, on HadCM3 and CGCM3 grids, in contrast to 6.00 mm/day as observation. Nevertheless, the model suffers to perform reasonably well at the time of extreme precipitation and summer time, more specifically to generate the CDD and STD indices. The future projections of precipitation (2011–2099) exhibit that there would be an increase in the precipitation amount and frequency in most of the months. Taking the 1961–2000 timeline as the base period, overall, the annual mean precipitation would indicate a surplus projection by nearly 14~18 % under both GCM output cases (HadCM3 A2/B2 scenarios and CGCM3 A2 scenario). According to the model simulation, the September–November periods might be the more significant months projecting the increment of the precipitation amount around over 50 %, while the precipitation deficit would be seen in March–May periods.     

Time dependent chemical study of contracting interstellar clouds. II. abundances of oxygen- and sulphur-bearing molecules

Abstract. We have constructed a chemical reaction system in a contracting interstellar cloud. In paper (I) we have presented the details of the physical and chemical scheme and the method of solution. The results of our chemical model produce fractional abundances of H₂CO, CO, OH, H₂O, SO and OCS which are in good agreement with the results of observations. On the other hand, the results of chlorine-bearing species are not in agreement with those of the observations. The calculated abundances of H₂CO, CO, OH, H₂O, SO, OCS and Cl⁺ are in agreement with the results of previous theoretical studies.     

Temporal variations of tides on the west coast of Great Britain

Summary. Temporal variations of tides are investigated by analysing tidal observations from five ports on the west coast of Great Britain. Variations considered here are those occurring in the semi-diurnal species daily, in the tidal constituents resolved from analyses of 29 day sets over a period of two years, 1980–81, and in the tidal constituents resolved from 1 yr sets over a period of 19 yr. The time variations of tidal constituents are mainly due to inseparable terms grouping with the principal term due to the short length of data and the insufficiency of the procedures to account for them. Surges and surge-tide interaction are affecting the resolution of tides. Time variations of constituents of the diurnal species induced by non-tidal forces are spatially consistent. The use of equilibrium relationships to account for modulations of principal constituents by waves separable in an 18.61 yr nodal cycle improves the analysis. However, the modulation is smaller in the real tide than in the equilibrium tide. When the application of this principle is extended to a wider frequency band to cover constituents which cannot be resolved from one month of observations, it may produce the opposite effect. These problems start compounding with decreasing length of data, i.e. increasing band width of resolution.
Functional approximations of interaction coefficients (bi-admittance) of non-linear tides, similar to the response (admittance) of linear tides are computed for semi-diurnal, fourth-diurnal and sixth-diurnal bands. These functional estimates may be used to interpolate unseparable constituents to improve the quality of analyses. The results are consistent with the fact that the response of the sea does not change in a narrow frequency band covering a nodal cycle of the Moon. The change in the equilibrium relationship between the principal term and its nodal term can be interpreted in terms of the damping effect of bottom friction.     

An approach to the problem of coastal erosion in quaternary sediments

Approximately 40 per cent of the shorelines of the lower Great Lakes are backed by relatively weak Quaternary sediments, and similar shorelines are found on many middle and high-latitude coasts. The high rates of bluff recession which are characteristic of these areas lead to economic losses through erosion of land and damage to buildings, and may prompt a wide range of measures designed to reduce erosion and protect property. Assessment of the physical problem and of possible solutions to it can best be achieved through a sediment budget approach. This is illustrated through a case study of an area near Grimsby, Ontario. The volume of sediment supply to the beach was calculated from measurements of bluff height and annual recession rates. The potential volume of longshore sediment transport was determined from the wave climate of the area and computer modelling of wave refraction. The relationship between sediment supply and potential transport rate can be used to assess the magnitude of the sediment deficit or surplus at points along the shoreline, and this provides an insight into the controls on alongshore variations in recession rates.     

The chemical evolution in a model of contracting cloud

The evolution of the different chemical species are followed in a model of contracting interstellar cloud. The central density increases from n = 10 cm^–3 diffuse initial cloud model to a dense cloud with central density number of n >- 10⁵ cm^–3 after a time of 1.2 × 10⁷ yr. A network of 622 reactions has been involved. The chemistry of the cloud is integrated simultaneously with the hydrodynamic equations of contraction.The results predict that the different molecular species increase in abundance as the contraction proceeds. The species which enhance significantly are CO, HCO, CS and NO. The fractional abundances of many of the other molecular species increase distinctly with contraction, e.g. CH, C₂H, CN, SO₂, CO₂, H₂O, C₂, NH₃, HCN, SO, OCS and SN. The transformation of the initial diffuse cloud model with small abundances of molecular species to a dense molecular cloud with enhancement of the different molecular species is confirmed. The results predict good agreements of our results with both the observations and other theoretical studies.