The Late Cretaceous-Paleogene active margin of Northeastern Asia: Geodynamic setting of terrigenous sedimentary basins in the Central Koryak terrane

The northeastern segment of the Late Cretaceous suprasubduction Okhotsk-Chukotka volcanic belt is not an analogue of Andean-type continental margin. During its formation, the belt was separated from the Paleopacific by a complexly built assembly that comprised the Central Koryak continental block and the Essoveem volcanic arc at its margin. Various types of independent terrigenous sedimentary basins were formed in the Late Cretaceous and Early Paleogene at the subsided portion of the microcontinent and its slope. The Uchkhichkhil-type basin was characterized by deposition of polymictic clastic sediments produced during erosion of the volcanic arc and pyroclastic material derived from active volcanic centers of this arc that extended along the microcontinent margin that faced the Okhotsk-Chukotka volcanic belt. The deposition of quartz-feldspathic flyschoid sequences as products of scouring of sialic basement of the continental block was inherent to the Ukelayat type of sedimentation. The closure of the minor oceanic basin that separated the Asian margin from microcontinent in the late Campanian resulted in the cessation of subduction-related activity of the Okhotsk-Chukotka volcanic belt and the Essoveem arc and initiated the formation of the Late Cretaceous accretionary margin of Asia. The deep structure of the central Koryak Highland deduced from the results of seismic surveying with the earthquake converted-wave method has corroborated the geotectonic interpretation.     

Analysis of unresolved complex mixtures of hydrocarbons extracted from Late Archean sediments by comprehensive two-dimensional gas chromatography (GC×GC)

Hydrocarbon mixtures too complex to resolve by traditional capillary gas chromatography display gas chromatograms with dramatically rising baselines or “humps” of coeluting compounds that are termed unresolved complex mixtures (UCMs). Because the constituents of UCMs are not ordinarily identified, a large amount of geochemical information is never explored. Gas chromatograms of saturated/unsaturated hydrocarbons extracted from Late Archean argillites and greywackes of the southern Abitibi Province of Ontario, Canada contain UCMs with different appearances or “topologies” relating to the intensity and retention time of the compounds comprising the UCMs. These topologies appear to have some level of stratigraphic organization, such that samples collected at any stratigraphic formation collectively are dominated by UCMs that either elute early- (within a window of C₁₅–C₂₀ n-alkanes), early- to mid- (C₁₅–C₃₀ n-alkanes), or have a broad UCM that extends through the entire retention time of the sample (from C₁₅–C₄₂ n-alkanes). Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC–MS) was used to resolve the constituents forming these various UCMs. Early- to mid-eluting UCMs are dominated by configurational isomers of alkyl-substituted and non-substituted polycyclic compounds that contain up to six rings. Late eluting UCMs are composed of C₃₆–C₄₀ mono-, bi-, and tricyclic archaeal isoprenoid diastereomers. Broad UCMs spanning the retention time of compound elution contain nearly the same compounds observed in the early-, mid-, and late-retention time UCMs. Although the origin of the polycyclic compounds is unclear, the variations in the UCM topology appear to depend on the concentration of initial compound classes that have the potential to become isomerized. Isomerization of these constituents may have resulted from hydrothermal alteration of organic matter.     

Mercury emission from terrestrial background surfaces in the eastern USA. II: Air/surface exchange of mercury within forests from South Carolina to New England

Mercury air/surface exchange was measured over litter-covered soils with low Hg concentrations within various types of forests along the eastern seaboard of the USA. The fieldwork was conducted at six forested sites in state parks in South Carolina, North Carolina, New Jersey, Pennsylvania, New York and Maine from mid-May to early June 2005. The study showed that the Hg air/surface exchange was consistently very low and similar (overall daytime mean flux = 0.2 ± 0.9 ng m⁻² h⁻¹, n = 310, for all six sites monitored) with the various forest types. These flux values are comparable with those found in a year-long study in Tennessee (yearly daytime mean = 0.4 ± 0.5 ng m⁻² h⁻¹), but lower than many previous flux results reported for background soils. The Hg fluxes at all sites oscillated around zero, with many episodes of deposition (negative fluxes) occurring in both daytime and nighttime. While there were particular days showing significant correlations among the Hg air/surface exchange and certain environmental parameters, perhaps because of the low fluxes encountered, few significant correlations were found for any particular day of sampling between the Hg flux and environmental parameters such as solar radiation, soil temperature, air temperature (little variability seen), relative humidity, and ambient air Hg concentrations. Factors driving the Hg exchange as previously found for enriched soils may not hold for these background litter-covered forest soils. The results suggest that spatial variations of the Hg air/surface exchange were small among these different forest types for this particular time of year.     

Heat flow and lithospheric thermal regime in the Northeast German Basin

New values of surface heat flow are reported for 13 deep borehole locations in the Northeast German Basin (NEGB) ranging from 68 to 91 mW m^− 2 with a mean of 77 ± 3 mW m^− 2. The values are derived from continuous temperature logs, measured thermal conductivity, and log-derived radiogenic heat production. The heat-flow values are supposed free of effects from surface palaeoclimatic temperature variations, from regional as well as local fluid flow and from thermal refraction in the vicinity of salt structures and thus represent unperturbed crustal heat flow. Two-D numerical lithospheric thermal models are developed for a 500 km section along the DEKORP-BASIN 9601 deep seismic line across the basin with a north-eastward extension across the Tornquist Zone. A detailed conceptual model of crustal structure and composition, thermal conductivity, and heat production distribution is developed. Different boundary conditions for the thickness of thermal lithosphere were used to fit surface heat flow. The best fit is achieved with a thickness of thermal lithosphere of about 75 km beneath the NEGB. This estimate is corroborated by seismological studies and somewhat less than typical for stabilized Phanerozoic lithosphere. Modelled Moho temperatures in the basin are about 800 °C; heat flow from the mantle is about 35 to 40 mW m^− 2. In the southernmost part of the section, beneath the Harz Mountains, higher Moho temperatures up to 900 to 1000 °C are shown. While the relatively high level of surface heat flow in the NEGB obviously is of longer wave length and related to lithosphere thickness, changes in crustal structure and composition are responsible for short-wave-length anomalies.     

Sensitivity of Turbine-Height Wind Speeds to Parameters in Planetary Boundary-Layer and Surface-Layer Schemes in the Weather Research and Forecasting Model

We evaluate the sensitivity of simulated turbine-height wind speeds to 26 parameters within the Mellor–Yamada–Nakanishi–Niino (MYNN) planetary boundary-layer scheme and MM5 surface-layer scheme of the Weather Research and Forecasting model over an area of complex terrain. An efficient sampling algorithm and generalized linear model are used to explore the multiple-dimensional parameter space and quantify the parametric sensitivity of simulated turbine-height wind speeds. The results indicate that most of the variability in the ensemble simulations is due to parameters related to the dissipation of turbulent kinetic energy (TKE), Prandtl number, turbulent length scales, surface roughness, and the von Kármán constant. The parameter associated with the TKE dissipation rate is found to be most important, and a larger dissipation rate produces larger hub-height wind speeds. A larger Prandtl number results in smaller nighttime wind speeds. Increasing surface roughness reduces the frequencies of both extremely weak and strong airflows, implying a reduction in the variability of wind speed. All of the above parameters significantly affect the vertical profiles of wind speed and the magnitude of wind shear. The relative contributions of individual parameters are found to be dependent on both the terrain slope and atmospheric stability.     

Fine-Scale Measurements Of Turbulence In The Lower Troposphere: An Intercomparison Between A Kite- And Balloon-Borne, And A Helicopter-Borne Measurement System

Two state-of-the-art, high-resolution, in situ turbulence measurement systems, which can be deployed at altitudes well above the atmospheric surface layer, are compared: the Tethered Lifting System (TLS) of the Cooperative Institute for Research in Environmental Sciences (CIRES)at the University of Colorado, Boulder, Colorado, and the helicopter-borneturbulence measurement system HELIPOD of the Technical UniversityBraunschweig, Germany, and the University of Hanover, Germany. Whilethe CIRES TLS is a fixed-point platform, HELIPOD is a moving platform.On the basis of data taken with the two systems in separate field campaigns,the system capabilities are quantified and discussed. Criteria for instrumentalrequirements are presented. It is shown that both the CIRES TLS and HELIPODare well suited for measuring fine-scale turbulence that is characterized by very small temperature structure parameters 10⁶ K² m^–2/3 and smaller) and very small energy dissipation rates (10^-7 m² s^-3 and smaller). The authors are not aware of any other turbulence measurement systems that have similar capabilities and can be deployed at altitudes of up to several kilometres. The HELIPOD is ideal for high-resolution horizontal measurements while the TLS is ideal for high-resolution vertical measurements using multiple sensors attached to a suspended line.     

Low paleosecular variation at the equator: a paleomagnetic pilgrimage from Galapagos to Esterel with Allan Cox and Hans Zijderveld

McFadden and Merrill (1995) suggested that the paleosecular variation (PSV) measured by the angular scatter of the virtual geomagnetic pole is minimal at the equator and should be smaller during a superchron than during the last 5 Myr. We revisited a key site of the 0–5 Ma database, the Galapagos archipelago, studied by Allan Cox in the early sixties. We obtained 79 sites with reliable mean directions on four islands (San Cristobal, Floreana, Santa Cruz and Pinzon), showing a larger proportion of transitional data than Cox (16 instead of 6%), because the sampling was concentrated on the Brunhes-Matuyama transition as delimited by Cox. This dataset allowed us to test the statistical method of Vandamme (1994) to separate PSV from transitional data. We obtained an angular scatter value of 11.2° (9.9–12.9°), instead of 16.8° for an a-priori rejection angle of 40°, compared with the 12.7° predicted from the global compilation (McFadden et al. 1991). Studies of sequences of lava flows are quite scarce in the Permian Kiaman Superchron, and the Esterel volcanics with their subequatorial paleolatitude are a good candidate to test the above prediction. We confirm the quality of the original data of Zijderveld (1975) and we improved the mean direction from one site. We also used new geological and geochronological data: Ar/Ar ages point to the period 264–278 Ma for a totally reversed volcanic sequence, in agreement with an ending of the Kiaman Superchron at 262–268 Ma. The extremely low angular scatter obtained (4 to 8°, depending on data selection) confirms the prediction, but an alternative interpretation invoking a post-volcanic Permian remagnetization is discussed.     

Optical and radiative properties of aerosols over Abu Dhabi in the United Arab Emirates

The present study is on the aerosol optical and radiative properties in the short-wave radiation and its climate implications at the arid city of Abu Dhabi (24.42 ^°N, 54.61 ^°E, 4.5 m MSL), in the United Arab Emirates. The direct aerosol radiative forcings (ARF) in the short-wave region at the top (TOA) and bottom of the atmosphere (BOA) are estimated using a hybrid approach, making use of discrete ordinate radiative transfer method in conjunction with the short-wave flux and spectral aerosol optical depth (AOD) measurements, over a period of 3 years (June 2012–July 2015), at Abu Dhabi located at the south-west coast of the Arabian Gulf. The inferred microphysical properties of aerosols at the measurement site indicate strong seasonal variations from the dominance of coarse mode mineral dust aerosols during spring (March–May) and summer (June–September), to the abundance of fine/accumulation mode aerosols mainly from combustion of fossil-fuel and bio-fuel during autumn (October–November) and winter (December–February) seasons. The monthly mean diurnally averaged ARF at the BOA (TOA) varies from ?13.2 Wm^?2 (～?0.96 Wm^?2) in November to ?39.4 Wm^?2 (?11.4 Wm^?2) in August with higher magnitudes of the forcing values during spring/summer seasons and lower values during autumn/winter seasons. The atmospheric aerosol forcing varies from + 12.2 Wm^?2 (November) to 28.2 Wm^?2 (June) with higher values throughout the spring and summer seasons, suggesting the importance of mineral dust aerosols towards the solar dimming. Seasonally, highest values of the forcing efficiency at the surface are observed in spring (?85.0 ± 4.1 W m^?2 τ ^?1) followed closely by winter (?79.2 ± 7.1 W m^?2 τ ^?1) and the lowest values during autumn season (?54 ± 4.3 W m^?2 τ ^?1). The study concludes with the variations of the atmospheric heating rates induced by the forcing. Highest heating rate is observed in June (0.39 K day ^?1) and the lowest in November (0.17 K day ^?1) and the temporal variability of this parameter is linearly associated with the aerosol absorption index.     

Rapid,high-resolution detection of environmental change over continental scales from satellite data – the Earth Observation Data Cube

The effort and cost required to convert satellite Earth Observation (EO) data into meaningful geophysical variables has prevented the systematic analysis of all available observations. To overcome these problems, we utilise an integrated High Performance Computing and Data environment to rapidly process, restructure and analyse the Australian Landsat data archive. In this approach, the EO data are assigned to a common grid framework that spans the full geospatial and temporal extent of the observations – the EO Data Cube. This approach is pixel-based and incorporates geometric and spectral calibration and quality assurance of each Earth surface reflectance measurement. We demonstrate the utility of the approach with rapid time-series mapping of surface water across the entire Australian continent using 27 years of continuous, 25?m resolution observations. Our preliminary analysis of the Landsat archive shows how the EO Data Cube can effectively liberate high-resolution EO data from their complex sensor-specific data structures and revolutionise our ability to measure environmental change.