Cave air and hydrological controls on prior calcite precipitation and stalagmite growth rates: Implications for palaeoclimate reconstructions using speleothems

Hourly resolved cave air P_CO2 and cave drip water hydrochemical data illustrate that calcite deposition on stalagmites can be modulated by prior calcite precipitation (PCP) on extremely short timescales. A very clear second-order covariation between cave air P_CO2 and drip water Ca²⁺ concentrations during the winter months demonstrates the effects of degassing-induced PCP on drip water chemistry. Estimating the strength of the cave air P_CO2 control on PCP is possible because the PCP signal is so clear; at our drip site a one ppm shift in Ca²⁺ concentrations requires a P_CO2 shift of between 333 and 667 ppm. This value will undoubtedly vary from site to site, depending on drip water flow rate, residence time, drip water-cave air P_CO2 differential, and availability of low P_CO2 void spaces in the vadose zone above the cave. High-resolution cave environmental measurements were used to model calcite deposition on one stalagmite in Crag Cave, SW Ireland, and modelled growth over the study period (222 μm over 171 days) is extremely similar to the amount of actual calcite growth (240 μm) over the same time interval, strongly suggesting that equations used to estimate stalagmite growth rates are valid. Although cave air P_CO2 appears to control drip water hydrochemistry in the winter, drip water dilution caused by rain events may have played a larger role during the summer, as evidenced by a series of sudden drops in Ca²⁺ concentrations (dilution) followed by much more gradual increases in drip water Ca²⁺ concentrations (slow addition of diffuse water). This research demonstrates that PCP on stalactites, cave ceilings, and void spaces within the karst above the cave partially controls drip water chemistry, and that thorough characterisation of this process at individual caves is necessary to most accurately interpret climate records from those sites.     

Far field effects of Alpine plate tectonism in the Iberian microplate recorded by fault-related denudation in the Spanish Central System

Apatite fission track analysis was performed on 56 samples from central Spain to unravel the far field effects of the Alpine plate tectonic history of Iberia. The modelled thermal histories reveal complex cooling in the Cenozoic, indicative of intermittent denudation. Accelerated cooling events occurred across the Spanish Central System (SCS) from the Middle Eocene to Recent. These accelerated cooling events resulted in up to 2.8±0.9 km of denudation in the western Sierra de Gredos and 3.6±1.0 km in the central and eastern Gredos (assuming a paleogeothermal gradient of 28±5 °C and a surface temperature of 10 °C). The greatest amount of denudation (5.0±1.6 km) occurred in the Sierra de Guadarrama. Accompanying rock uplift was 4.7±1.0 and 5.9±1.6 km in the eastern Gredos and Guadarrama, respectively. Most denudation in the Gredos occurred from the Middle Eocene to the Early Miocene and can be related to the N–S stress field, induced by the Pyrenean compression. In the Guadarrama, the greatest denudation was Pliocene to Recent of age and seems related to the ongoing NW–SE Betic compression. The fact that the formation of the E–W trending Gredos coincides with the N–S Pyrenean compression and the creation of the present day morphology of the NE–SW trending Guadarrama with the younger NW–SE Betic compression, indicates that they record the far field effects of Alpine plate tectonics on Iberia. The trend of pre-existing lineaments was of major importance in influencing the style and magnitude of these of far field effects.     

Stratigraphic architecture of the fluvio-lacustrine deposits, Bathan Formation, Al-Rehaili area, North Jeddah, Saudi Arabia

A siliciclastic-dominated succession (～11 m thick) underlying Harrat Rahat, belonging to the Miocene–Pliocene Bathan Formation is recently exposed at Al-Rehaili area, North Jeddah, Saudi Arabia. It covers a wide spectrum of grain sizes varying from clay-rich mudstones to cobble grade conglomerate and consists of a variety of facies vary from fluvial to marginal and open lacustrine deposited in a half-graben basin formed along the eastern margin of the extensional Red Sea Basin. Field-based sedimentologic investigation enables to identify ten facies grouped into three facies associations (A–C). The depositional history is subdivided into two stages. The first stage represents deposition in gravel to sand-dominated fluvial system sourced from a southern source and grade northward into lacustrine delta and open lacustrine setting. The second stage on the other hand includes deposition of fluvial channels running in E–W direction with attached bank sand bar. Sequence stratigraphic interpretations of the lacustrine deposits enable to identify three unconformity-bounded sequences (SQ_1–3). The basal sequence is incomplete, consisting of three aggradationally to progradationally stacked delta plain and delta front parasequences. The second sequence is sharply and erosively overlying a red paleosol bed that defines the upper boundary of the first sequence. It includes two system tracts; upward-fining and deepening lacustrine offshore mudstones of the transgressive system tracts unconformably overlain by red paleosol of the regressive systems tracts. The top of this sequence is delineated at the sharp transgressive surface of erosion at the base of delta mouth bar deposits of sequence 3. Changes in the accommodation and sedimentation rates by basin subsidence under the influence of tectonics and sediment compaction and loading as well as climatic oscillation between semi-arid to arid conditions were the major controls on the fluvio-lacustrine sedimentation and their facies distribution. Tectonic reorganization of the drainage system resulted in the formation of E–W flowing fluvial streams in the second stage.     

Spectral characteristics of magnetogravity waves generated by high-energy mass source in the equatorial region of the atmosphere,Part I

The possibility of magnetogravity wave (MGW) propagation in the equatorial ionosphere taking into account the finite conductivity is analyzed. The dispersion relation shows the existence of two propagating MGW modes in ionospheric layer F2: high-frequency (HF MGW) and low frequency (LF MGW). The dispersion relations for them are executed and the characteristic frequencies and propagation velocities are determined. In this part of research the spectral features of disturbances in components of environment displacement for HF MGW, generated by a mass source, is carried out. The results are applied to estimate the values of density, pressure and magnetic field spectral components of magnetogravity disturbances caused by horizontal meteor sweep. They may be useful in the analysis of ionospheric disturbances excited by high energy geophysical sources.     

Hydrological regime of the Rhône Delta and dynamics of its coastline

Specific features of the hydrological regime of the Rhône River and the nearshore zone of its mouth are discussed. The processes of seawater intrusion into the delta branches are described. The information on the history of the delta evolution and development is presented along with the reconstruction of the Holocene evolution of the Rhône Delta and analysis of formation peculiarities of the present-day delta. Channel processes in the Rhône Delta and the dynamics of the delta coastline are described; characteristics of the deep-water fan are discussed, and the data on sediment balance are given.     

Challenges associated with pre-border management of biofouling on oil rigs

The potential for oil rigs to transport diverse, reef-like communities around the globe makes them high risk vectors for the inadvertent spread of non-indigenous species (NIS). This paper describes two case studies where a suite of pre-border management approaches was applied to semi-submersible drilling rigs. In the first case study, a drilling rig was defouled in-water prior to departure from New Zealand to Australia. Risk mitigation measures were successful in reducing biosecurity risks to the recipient region, but they resulted in the unintentional introduction of the non-indigenous brown mussel (Perna perna) to New Zealand when the rig was defouled in-water by divers. In the second case study, lessons learned from this high-profile incursion resulted in a more structured approach to pre-border management, and this serves as a useful template for future rig transfers.     

Discontinuity controlled probabilistic slope failure risk maps of the Altindag (settlement) region in Turkey

The evaluation of potential rock slope problems using stereographic projection techniques known as kinematic analysis is one of the most important parts of a slope stability investigation to be carried out in jointed rock media. In conventional stereoprojection techniques for the assessment of possible rock slope failures, the peak orientations of joints together with the slope geometry and the friction angle of the weakness planes are used. Other possible joint orientations which may be encountered in the rock media are ignored, although they belong to the group of joint peak orientations. In this study, nearly vertical jointed andesites cropped out at the Altindag settlement region in Ankara were studied in order to evaluate the relevance of this ignored discontinuity orientation data on slope stability. As a result, probabilistic risk maps for planar, toppling and wedge failures were produced using the kinematic rules and digital elevation model of the study area. The comparison of the distribution of the actual failures in the area and the probabilistic risk maps prepared for the study area revealed that all of the identified failures are found to be located in the higher risk zones on the probabilistic risk maps.     

Current trends in Great Lakes shipping

Shipping on the Great Lakes has changed rapidly in recent years. Internal Great Lakes traffic consists almost entirely of bulk movements, primarily of iron ore, coal, limestone, and grain. Ore shipments are mainly of taconite concentrate. Low-sulfur coal from the western areas of the United States is now moving downbound through the lakes, a movement in the opposite direction from the predominantly upbound movement of Appalachian coal. Opening of a larger lock in 1970 between lakes Superior and Huron has initiated a new generation of lake vessels, which are three times the size of the previous lake ships, and are too large to transit the Welland Canal and the St. Lawrence Seaway; for the first time since 1959 the largest “lakers” are land-locked. General cargo traffic between the Great Lakes and overseas has been declining rapidly since 1970, largely as the result of the rapid development of container ships, and the Interstate highway system, which increases the competitive advantages of salt-water ports.