Evaluating the use of 3'-(p-Aminophenyl) fluorescein for determining the formation of highly reactive oxygen species in particle suspensions

Background  

Given the importance of highly reactive oxygen species (hROS) as reactants in a wide range of biological, photochemical, and environmental systems there is an interest in detection and quantification of these species. The extreme reactivity of the hROS, which includes hydroxyl radicals, presents an analytical challenge. 3'-(p-Aminophenyl) fluorescein (APF) is a relatively new probe used for measuring hROS. Here, we further evaluate the use of APF as a method for the detection of hydroxyl radicals in particle suspensions.     

A spatially explicit methodology for a priori estimation of field survey effort in environmental observation networks

When establishing environmental monitoring programmes, it crucial to make reliable cost estimates, especially where a field survey is involved. This paper presents a methodology for creating a spatial measure of a field survey effort (SE). A set of relevant variables affecting a SE (e.g. areas with rough terrain, or distant from the main road network) was classified using fuzzy sets and then combined to produce spatially explicit effort indicators, which were integrated to a single measure using an analytic hierarchy process (AHP). To evaluate this approach and identify the limits for its application, three spatially nested case studies were used to test the spatial expression of SE and the scalable capacity of the method itself. The presented methodology could cope with variations in the scale and data resolution, retrieving a coherent estimate of SE across the different case studies. The presented methodology is therefore useful for (i) testing the network designs for sampling bias related to SE, (ii) comparing alternative sampling designs, (iii) assessing the sampling costs and (iv) supporting the human and logistical resource management.     

Canelles landslide: modelling rapid drawdown and fast potential sliding

A large landslide (40 × 10⁶ m³) was reactivated on the left bank of Canelles reservoir, Spain. The instability was made evident after a considerable reduction of the reservoir level. The drawdown took place during the summer of 2006 after several years of high water levels. The drawdown velocity reached values between 0.5 and 1.2 m/day (registered at low elevations). The paper reports the geological and geotechnical investigations performed to define the movement. The geometry of the slip surface was established from the detailed analysis of the continuous cores recovered in deep borings and from limited information provided by inclinometers. Deep piezometric records provided also valuable information on the pore water pressure in the vicinity of the failure surface. These data allowed validating a flow–deformation coupled calculation model, which takes into account the changes in water level that occurred 4  years previous to the failure as well as the average rainfall. The analysis indicates that the most likely reason for the instability is the rapid drawdown that took place during the summer of 2006. The potential sudden acceleration of the slide is also analysed in the paper introducing coupled thermal hydraulic and mechanical effects that may develop at the basal shearing surface of the sliding mass. The results indicate that the slide velocity may reach values around 16 m/s when displacement reaches 250 m.     

Surface changes on crystalline stones due to salt crystallisation

This study assesses the changes on the surface of crystalline stones due to salt crystallisation. Efflorescence was forced to grow on the surface of granite and marbles through 60 cycles of salt crystallisation with sodium sulphate. Changes on surface roughness, gloss and colour were measured every 15 cycles and the specimens were examined with naked eye and SEM. Sodium sulphate produces damage which depends on mineral composition. Results show that granites experience a mechanical decay with an increase in roughness. Peaks of mica can be observed on the surface and cracks widen and grow deeper. Colour and gloss do not show any significant change, although gloss decreases with an increase in surface roughness. In marbles, the decay is mainly chemical. Surface roughness increases due to dissolution of the calcite. White marbles exhibit yellowing. Gloss decreases during the first cycles—as grain boundaries become more visible—but tends to regain almost its initial value as the number of cycles increases. In this case, gloss does not show any relation with surface roughness.     

Water and nutrient fluxes off Northwest Africa

A historical data set is used to describe the coastal transition zone off Northwest Africa during spring 1973 and fall 1975, from 17° to 26°N, with special emphasis on the interaction between subtropical (North Atlantic Central Waters) and tropical (South Atlantic Central Waters) gyres. The near-surface geostrophic circulation, relative to 300 m, is quite complex. Major features are a large cyclonic pattern north of Cape Blanc (21°N) and offshore flow at the Cape Verde front. The large cyclone occurs in the region of most intense winds, and resembles a large meander of the baroclinic southward upwelling jet. The Cape Verde frontal system displays substantial interleaving that may partly originate as mesoscale features at the coastal upwelling front. Property–property diagrams show that the front is an effective barrier to all properties except temperature. The analysis of the Turner angle suggests that the frontal system is characterized by large heat horizontal diffusion as a result of intense double diffusion, which results in the smoothing of the temperature horizontal gradients. Nine cross-shore sections are used to calculate along-shore geostrophic water-mass and nutrient transports and to infer exchanges between the coastal transition zone and the deep ocean (import: deep ocean to transition zone; export: transition zone to deep ocean). These exchanges compare well with mean wind-induced transports and actual geostrophic cross-shore transport estimates. The region is divided into three areas: southern (18–21°N), central (21–23.5°N), and northern (23.5–26°N). In the northern area geostrophic import is roughly compensated with wind-induced export during both seasons. In the central area geostrophic import is greater than wind-induced export during spring, resulting in net import of both water (0.8 Sv) and nitrate (14 kmol s⁻¹), but during fall both factors again roughly cancel. In the southern area geostrophy and wind join to export water and nutrients during both seasons, they increase from 0.6 Sv and 3 kmol s⁻¹ during fall to 2.9 Sv and 53 kmol s⁻¹ during spring.     

Modeling fluvial response to in‐stream woody vegetation: implications for stream corridor restoration

River restoration and bank stabilization programs often use vegetation for improving stream corridor habitat, aesthetic and function. Yet no study has examined the use of managed vegetation plantings to transform a straight, degraded stream corridor into an ecologically functional meandering channel. Experimental data collected using a distorted Froude‐scaled flume analysis show that channel expansion and widening, thalweg meandering and riffle and pool development are possible using discrete plantings of rigid, emergent vegetation, and the magnitudes of these adjustments depend on the shape of the vegetation zone and the density of the vegetation. These experimental results were verified and validated using a recently developed numerical model, and model output was then used to discuss mechanistically how rivers respond to the introduction of in‐stream woody vegetation. Finally, a hybrid method of meander design is proposed herein where managed vegetation plantings are used to trigger or force the desired morphologic response, transforming a straight, degraded reach into a more functional meandering corridor. It is envisioned that such numerical models could become the primary tool for designing future stream restoration programs involving vegetation and assessing the long‐term stability of such activities. Copyright © 2007 John Wiley & Sons, Ltd.     

Abiotic ammonium formation in the presence of Ni-Fe metals and alloys and its implications for the Hadean nitrogen cycle

Experiments with dinitrogen-, nitrite-, nitrate-containing solutions were conducted without headspace in Ti reactors (200°C), borosilicate septum bottles (70°C) and HDPE tubes (22°C) in the presence of Fe and Ni metal, awaruite (Ni₈₀Fe₂₀) and tetrataenite (Ni₅₀Fe₅₀). In general, metals used in this investigation were more reactive than alloys toward all investigated nitrogen species. Nitrite and nitrate were converted to ammonium more rapidly than dinitrogen, and the reduction process had a strong temperature dependence. We concluded from our experimental observations that Hadean submarine hydrothermal systems could have supplied significant quantities of ammonium for reactions that are generally associated with prebiotic synthesis, especially in localized environments. Several natural meteorites (octahedrites) were found to contain up to 22 ppm N_tot. While the oxidation state of N in the octahedrites was not determined, XPS analysis of metals and alloys used in the study shows that N is likely present as nitride (N^3-). This observation may have implications toward the Hadean environment, since, terrestrial (e.g., oceanic) ammonium production may have been supplemented by reduced nitrogen delivered by metal-rich meteorites. This notion is based on the fact that nitrogen dissolves into metallic melts.     

Physiography and deposition on a distal deep-sea system: The Valencia Fan (Northwestern Mediterranean)

The Valencia Fan developed as the distal fill of a deep-sea valley, detached from the continental slope and the main sedimentary source. A survey of side-scan sonar, Sea Beam and reflection seismics shows that the sediment is largely fed through the Valencia Valley. The upper fan comprises large channels with low-relief levees, and the middle fan has sinuous distributary channels. Depositional bedforms predominate on the valley floor and levees, and erosional bedforms are common in the valley walls. A change to slope on the fan apex and the presence of volcanoes on the upper fan are the main factors influencing fan-growth pattern.