塔里木地块二叠纪古地磁结果及二叠纪中国大陆的重建

在塔里木盆地西北缘下二叠统的三个剖面中采集的标本,获得了两个古地磁极:一个获自灰岩剖面(λ=65°N,φ=163°E,K=128,A_(?5)=4°,n=11).另一个获自两个玄武岩剖面(λ=55°N,φ=172°E,K=66,A_(95)=4°,n=21).结合原先已发表的数据,塔里木地块二叠纪古地磁场为λ=61°N,φ=177°E.K=98.A_(95)=9°,N=4.塔里木地块古纬度比中朝、扬子地块高得多,认为这些地块是分开的大陆地块.晚二叠世.塔里木、西伯利亚、中朝、扬子地块之间发生过重要的相对运动表明.地质上推断的晚古生代碰撞、并合作用在中亚及东亚的复合构造演变才刚刚开始.     

紫硫镍矿交代镍黄铁矿的水热反应机理及动力学

本工作首次在实验室条件下对浅生区紫硫镍矿(Ni,Fe)3S4交代镍黄铁矿(Ni,Fe)9S8水热反应的机理及动力学进行了研究。起始反应矿物采用高纯自然镍黄铁矿,合成纯镍黄铁矿或合成镍黄铁矿-磁黄铁矿集合体。反应pH值采用0.2M醋酸-醋酸纳缓冲溶液控制在3～5的范围内。反应进程由X-射线衍射物相定量分析及扫描电镜观察进行跟踪。结果表明,当反应温度恒定在80℃时,交代20(4)%的镍黄铁矿需792h。相同条件下加入少量H2S可将反应速率提高一倍。当反应在125℃饱和蒸汽压水热环境下进行时,完全交代纯镍黄铁矿需约168h。此过程由于磁黄铁矿的存在而被催化,交代集合体中的镍黄铁矿仅需68h,进一步反应磁黄铁矿被交代成白铁矿。磁黄铁矿的催化作用可能源于溶解产生的微裂纹加速了流体的传质过程。当反应温度升高至145℃时,速率反而下降,不遵循Arrhenius经验规律。动力学分析得80℃速率常数介于5.8×10-8～3.0×10-7/s之间,125℃及145℃速率常数分别介于2.8×10-6～2.08×10-5/s及1×10-6～5.1×10-6/s之间,远高于同温度下固相扩散反应的速率常数,表明该反应在地质时标上为一快速反应。此外,用背散射电子显微技术对矿物表面形貌进行了分析,发现交代产物紫硫镍矿具有颗粒细小及存在微裂纹等特征,与自然界浅生矿床中的紫硫镍矿非常相似;电镜实验还表明该交代作用是一个典型的耦合溶解-再沉淀反应。其耦合机制的驱动力可能与反应界面处微空隙对流体饱和度的控制有关。     

Same as it Ever Was? Stability and Change Over 15 Years in a Rural District in Southeastern Australia

Using longitudinal survey data, this paper explores stability and change in values, beliefs, attitudes, and knowledge among rural landholders. Existing theories predict varying degrees of stability in these constructs. This paper tests these assumptions through data collected by four cross-sectional surveys of rural landowners (>10?ha), completed in one region between 2002 and 2016. The study area includes a mix of social landscapes but agriculture is the dominant land use. Results reveal significant change in measured constructs over time. Nearly all of the items assessing values changed significantly across the study period (seven of eight held values, ten of eleven assigned values). Most belief items (three of five), half of the attitude items (two of four), and all eleven knowledge items also experienced change. While statistically significant, most of the identified changes were relatively modest in scope. Findings suggest the value of longitudinal research to better understand dynamic psychological and social constructs.     

Subduction-modified pelagic sediments as the enriched component in back-arc basalts from the Japan Sea: Ocean Drilling Program Sites 797 and 794

Ocean Drilling Program Legs 127 and 128 in the Yamato Basin of the Japan Sea, a Miocene-age back-arc basin in the western Pacific Ocean, recovered incompatible-element-depleted and enriched tholeiitic dolerites and basalts from the basin floor, which provide evidence of a significant sedimentary component in their mantle source. Isotopically, the volcanic rocks cover a wide range of compositions (e.g., ⁸⁷Sr/⁸⁶Sr=0.70369–0.70503, ²⁰⁴Pb/²⁰⁴Pb=17.65–18.36) and define a mixing trend between a depleted mantle (DM) component and an enriched component with the composition of EM II. At Site 797, the combined isotope and trace element systematics support a model of two component mixing between depleted, MORB-like mantle and Pacific pelagic sediments. A best estimate of the composition of the sedimentary component has been determined by analyzing samples of differing lithology from DSDP Sites 579 and 581 in the western Pacific, east of the Japan arc. The sediments have large depletions in the high field strength elements and are relatively enriched in the large-ion-lithophile elements, including Pb. These characteristics are mirrored, with reduced amplitudes, in Japan Sea enriched tholeiites and northeast Japan arc lavas, which strengthens the link between source enrichment and subducted sediments. However, Site 579/581 sediments have higher LILE/REE and lower HFSE/REE than the enriched component inferred from mixing trends at Site 797. Sub-arc devolatilization of the sediments is a process that will lower LILE/REE and raise HFSE/REE in the residual sediment, and thus this residual sediment may serve as the enriched component in the back-arc basalt source. Samples from other potential sources of an enriched. EM II-like component beneath Japan, such as the subcontinental lithosphere or crust, have isotopic compositions which overlap those of the Japan Sea tholeiites and are not enriched enough to be the EM II end-member.     

The mineralogy of the Yaringie Hill meteorite—A new H5 chondrite from South Australia

Abstract— The Yaringie Hill meteorite is a new H5 ordinary chondrite found in the Gawler Ranges, South Australia. The meteorite, which shows only minor signs of terrestrial weathering, is predominantly composed of olivine (Fa_17.2), orthopyroxene (Fs_15.1Wo_1.1), and three distinct phases of nickeliferous iron metal (kamacite, taenite, tetrataenite). Other minerals include troilite, plagioclase (Ab₈₁An₁₆Or₃), clinopyroxene (En₅₂Wo₄₂Fs₆), chlorapatite, merrillite, ilmenite, and native copper. Three types of spinel with distinctive textures (coarse, skeletal aggregates, rounded aggregates) and with compositions close to the join MgAl₂O₄‐FeCr₂O₄ are also present. Chondrules within the Yaringie Hill meteorite, which often have poorly defined boundaries, are placed in a recrystallized matrix. Shock indicators suggest that the meteorite experienced only weak shock metamorphism (S3).     

Circulation dynamics and its influence on European and Mediterranean January–April climate over the past half millennium: results and insights from instrumental data, documentary evidence and coupled climate models

We use long instrumental temperature series together with available field reconstructions of sea-level pressure (SLP) and three-dimensional climate model simulations to analyze relations between temperature anomalies and atmospheric circulation patterns over much of Europe and the Mediterranean for the late winter/early spring (January–April, JFMA) season. A Canonical Correlation Analysis (CCA) investigates interannual to interdecadal covariability between a new gridded SLP field reconstruction and seven long instrumental temperature series covering the past 250 years. We then present and discuss prominent atmospheric circulation patterns related to anomalous warm and cold JFMA conditions within different European areas spanning the period 1760–2007. Next, using a data assimilation technique, we link gridded SLP data with a climate model (EC-Bilt-Clio) for a better dynamical understanding of the relationship between large scale circulation and European climate. We thus present an alternative approach to reconstruct climate for the pre-instrumental period based on the assimilated model simulations. Furthermore, we present an independent method to extend the dynamic circulation analysis for anomalously cold European JFMA conditions back to the sixteenth century. To this end, we use documentary records that are spatially representative for the long instrumental records and derive, through modern analogs, large-scale SLP, surface temperature and precipitation fields. The skill of the analog method is tested in the virtual world of two three-dimensional climate simulations (ECHO-G and HadCM3). This endeavor offers new possibilities to both constrain climate model into a reconstruction mode (through the assimilation approach) and to better asses documentary data in a quantitative way.     

The importance of ship log data: reconstructing North Atlantic, European and Mediterranean sea level pressure fields back to 1750

Local to regional climate anomalies are to a large extent determined by the state of the atmospheric circulation. The knowledge of large-scale sea level pressure (SLP) variations in former times is therefore crucial when addressing past climate changes across Europe and the Mediterranean. However, currently available SLP reconstructions lack data from the ocean, particularly in the pre-1850 period. Here we present a new statistically-derived 5° × 5° resolved gridded seasonal SLP dataset covering the eastern North Atlantic, Europe and the Mediterranean area (40°W–50°E; 20°N–70°N) back to 1750 using terrestrial instrumental pressure series and marine wind information from ship logbooks. For the period 1750–1850, the new SLP reconstruction provides a more accurate representation of the strength of the winter westerlies as well as the location and variability of the Azores High than currently available multiproxy pressure field reconstructions. These findings strongly support the potential of ship logbooks as an important source to determine past circulation variations especially for the pre-1850 period. This new dataset can be further used for dynamical studies relating large-scale atmospheric circulation to temperature and precipitation variability over the Mediterranean and Eurasia, for the comparison with outputs from GCMs as well as for detection and attribution studies.     

Temporal rainfall variability in the Lake Victoria Basin in East Africa during the twentieth century

Water resources systems are designed and operated on assumption of stationary hydrology. Existence of trends and other changes in the data invalidates this assumption, and detection of the changes in hydrological time series should help us revise the approaches used in assessing, designing and operating our systems. In addition, trend and step change studies help us understand the impact of man’s activities (e.g. urbanisation, deforestation, dam construction, agricultural activities, etc.) on the hydrological cycle. Trends and step changes in the seasonal and annual total rainfall for 20 stations in the Lake Victoria basin were analysed. The seasonal rainfall for any station in a given year was defined in two ways: (1) fixed time period where the rainy seasons were taken as occurring from March–May (long rains) and from October–December (short rains); and (2) variable periods where the rainy seasons were taken as the three consecutive months with maximum total rainfall covering the period of January–June (long rains) and July–December (short rains), to take into account the fact that the onset of rainy seasons within the basin varies from year to year and from one station to the next. For each station, sub datasets were derived covering different periods (all available data at the station, 1941–1980, 1961–1990, 1971–end of each station’s time series). The trends were analysed using the Mann-Kendall method, while the step changes were analysed using the Worsley Likelihood method. The results show that positive trends predominate, with most stations showing trend being located in the northern part of the basin, though this pattern is not conclusive. In all, 17% of the cases have trends, of which 67% are positive. The 1960s represent a significant upward jump in the basin rainfall. Seasonal rainfall analysis shows that the short rains tend to have more trends than the long rains. The impact of the varying month of onset of the rainy season is that the results from analyzing the fixed-period and variable-period time series are rarely the same, meaning the two series have different characteristics. It may be argued that the variable-period time series are more reliable as a basis for analysing trends and step changes, since these time series reflect more closely the actual variability in rainy seasons from one year to the next. The fixed-period analysis would, on the other hand, find more practical use in planning.