The heat-capacity of ilmenite and phase equilibria in the system Fe-T-O

Low temperature adiabatic calorimetry and high temperature differential scanning calorimetry have been used to measure the heat-capacity of ilmenite (FeTiO₃) from 5 to 1000 K. These measurements yield S₂₉₈⁰ = 108.9 J/(mol · K). Calculations from published experimental data on the reduction of ilmenite yield Δ₂₉₈⁰(I1) = ?1153.9 kJ/(mol · K). These new data, combined with available experimental and thermodynamic data for other phases, have been used to calculate phase equilibria in the system Fe-Ti-O. Calculations for the subsystem Ti-O show that extremely low values of $\text{?O}{}_2$ are necessary to stabilize TiO, the mineral hongquiite reported from the Tao district in China. This mineral may not be TiO, and it should be re-examined for substitution of other elements such as N or C. Consideration of solid-solution models for phases in the system Fe-Ti-O allows derivation of a new thermometer/oxybarometer for assemblages of ferropseudobrookite-pseudobrookite_ss and hematite-ilmenite_ss. Preliminary application of this new thermometer/oxybarometer to lunar and terrestrial lavas gives reasonable estimates of oxygen fugacities, but generally yields subsolidus temperatures, suggesting re-equilibration of one or more phases during cooling.     

Optical observations of line profile variability in the WN5 star HD 50896

The WN5 star HD 50896 is a well known variable star but the cause of the variations is uncertain. As part of an extensive observing campaign on HD 50896, 68 spectra were obtained with the AAT and UCL echelle spectrograph over three nights in January 1991. The variations seen in the emission line profiles of He II 4686, He II 4860, N V 4945 and N V 4603, 4620, sampling different regions of the wind, are described. Gross night-to-night changes are seen in the tops of all the emission lines, with the pattern of variability being different for each line, as a consequence of the different line formation regions. The edges of the emission line profiles are seen to shift but not in a systematic way, as expected for binary motion. In terms of hourly variations which monitor the propagation of instabilities in the wind, distinct blobs are seen moving outwards through the emission line profiles of the He II lines but are absent in NV 4945. This appears to indicate that, at least for the epoch of these observations, the instabilities develop farther out in the wind than the N V formation region and may well rule out photospheric-induced wind instabilities.     

Comparison of the EMEP, RADM2 and RACM Mechanisms

A comparison of the atmospheric chemistry mechanisms EMEP (Co-operative Programme for Monitoring and Evaluation of the Long-Range Transmission of Air Pollutants in Europe), RADM2 (Regional Acid Deposition Model, version 2) and RACM (Regional Atmospheric Chemistry Mechanism) has been conducted. Each mechanism was used to simulate the PLUME case of Kuhn et al. (1998) and to simulate an additional 150 and 81 scenarios with and without emissions, respectively. These simulations covered scenarios that ranged from relatively clean, through rural and polluted urban conditions. Ozone isopleths and scatter plots were generated from the simulations. The mechanisms were compared primarily on the basis of calculated ozone and ozone precursor concentrations. For the gas-phase ozone precursors the differences between the mechanisms were rather small under clean conditions and more significant under polluted conditions. The differences were especially significant for the concentrations of NO₂ and organic peroxy radicals. In general the EMEP mechanism yielded the most ozone and the RADM2 mechanism yielded the least. Furthermore the results suggest that a broad range simulation conditions should be used to compare mechanisms and not just a few selected scenarios.     

Glacial erosion and geomorphology in the northwest Sierra Nevada, CA

Pleistocene glacial erosion left a strong topographic imprint in the northwestern Sierra Nevada at many scales, yet the specific landforms and the processes that created them have not been previously documented in the region. In contrast, glaciation in the southern and central Sierra was extensively studied and by the end of the 19th century was among the best understood examples of alpine glaciation outside of the European Alps. This study describes glacially eroded features in the northwest Sierra and presents inferred linkages between erosional forms and Pleistocene glacial processes. Many relationships corroborate theoretical geomorphic principles. These include the occurrence of whalebacks in deep ice positions, roches moutonnées under thin ice, and occurrence of P-forms in low topographic positions where high subglacial meltwater pressures were likely. Some of the landforms described here have not previously been noted in the Sierra, including a large crag and tail eroded by shallow ice and erosional benches high on valley walls thought to be cut by ice-marginal channels.     

Late Pleistocene Glaciations in the Northwestern Sierra Nevada, California

Pleistocene fluvial landforms and riparian ecosystems in central California responded to climate changes in the Sierra Nevada, yet the glacial history of the western Sierra remains largely unknown. Three glacial stages in the northwestern Sierra Nevada are documented by field mapping and cosmogenic radionuclide surface-exposure (CRSE) ages. Two CRSE ages of erratic boulders on an isolated till above Bear Valley provide a limiting minimum age of 76,400±3800 ¹⁰Be yr. Another boulder age provides a limiting minimum age of 48,800±3200 ¹⁰Be yr for a broad-crested moraine ridge within Bear Valley. Three CRSE ages producing an average age of 18,600±1180 yr were drawn from two boulders near a sharp-crested bouldery lateral moraine that represents an extensive Tioga glaciation in Bear Valley. Nine CRSE ages from striated bedrock along a steep valley transect average 14,100±1500 yr and suggest rapid late-glacial ice retreat from lower Fordyce Canyon with no subsequent extensive glaciations. These ages are generally consistent with glacial and pluvial records in east-central California and Nevada.     

Environmental prognostics: an integrated model supporting lysosomal stress responses as predictive biomarkers of animal health status

The potential prognostic use of lysosomal reactions to environmental pollutants is explored in relation to predicting animal health in marine mussels, based on diagnostic biomarker data. Cellular lysosomes are already known to accumulate many metals and organic xenobiotics and the lysosomal accumulation of the carcinogenic polycyclic aromatic hydrocarbon 3-methylcholanthrene (3-MC) is demonstrated here in the hepatopancreatic digestive cells and ovarian oocytes of the blue mussel. Lysosomal membrane integrity or stability appears to be a generic indicator of cellular well-being in eukaryotes; and in bivalve molluscs it is correlated with total oxygen and nitrogen radical scavenging capacity (TOSC), protein synthesis, scope for growth and larval viability; and inversely correlated with DNA damage (micronuclei), as well as lysosomal swelling (volume density), lipidosis and lipofuscinosis, which are all characteristic of failed or incomplete autophagy. Integration of multiple biomarker data is achieved using multivariate statistics and then mapped onto "health status space" by using lysosomal membrane stability as a measure of cellular well-being. This is viewed as a crucial step towards the derivation of explanatory frameworks for prediction of pollutant impact on animal health; and has facilitated the development of a conceptual mechanistic model linking lysosomal damage and autophagic dysfunction with injury to cells, tissues and the whole animal. This model has also complemented the creation and use of a cell-based bioenergetic computational model of molluscan hepatopancreatic cells that simulates lysosomal and cellular reactions to pollutants. More speculatively, the use of coupled empirical measurements of biomarker reactions and modelling is proposed as a practical approach to the development of an operational toolbox for predicting the health of the environment.     

The masses, radii and luminosities of the components of U Geminorum

We present a phase-resolved spectroscopic study of the secondary star in the cataclysmic variable (CV) U Gem. We use our data to measure the radial velocity semi-amplitude, systemic velocity and rotational velocity of the secondary star. Combining this with literature data allows us to determine masses and radii for both the secondary star and white dwarf, which are independent of any assumptions about their structure. We use these to compare their properties to those of field stars and find that both components follow field mass–radius relationships. The secondary star has the mass, radius, luminosity and photometric temperature of an M2 star, but a spectroscopic temperature of M4. The latter may well be due to a high metallicity. There is a troubling inconsistency between the radius of the white dwarf inferred from its gravitational redshift and inclination and that inferred from its temperature, flux and astrometric distance.
We find that there are two fundamental limits to the accuracy of the parameters we can derive. First, the radial velocity curve of the secondary star deviates from a sinusoid, in part because of its asphericity (which can be modelled) and in part because the line flux is not evenly distributed over its surface. Secondly, we cannot be certain which spectral type is the best match for the lines of the secondary star, and the derived rotational velocity is a function of the spectral type of the template star used.     

High resolution polarimetric radar scattering measurements of lowgrazing angle sea clutter

This paper presents fully polarimetric radar scattering measurements of low grazing angle sea clutter. The measurements were obtained at a three degree grazing angle using a high range resolution (1.5 m) X-Band polarimetric radar operated from a shore site overlooking the Chesapeake Bay. The radar employs pulse-to-pulse switching between orthogonal transmitted polarizations and simultaneously measures two orthogonally polarized components of the backscattered wave to obtain full polarimetric information about the scattering process. The complete Stokes matrix, computed by averaging successive realizations of the polarization scattering matrix, is used to obtain polarization signatures and to determine the polarization dependence of the clutter. Sea spike echoes are shown to be weakly polarized and to exhibit polarization signatures indicative of multiple independent scattering mechanisms. Clutter echoes in the absence of sea spikes are shown to be highly polarized and to exhibit polarization signatures indicative of a single dominant scattering mechanism