Application of solar max ACRIM data to analysis of solar-driven climatic variability on Earth

Climatic change caused by solar variability has been proposed for at least a century, but could not be assessed reliably in the past because the uncertainty in solar irradiance measured from the Earth's surface is too large. Now satellite measurements by such instruments as the Active Cavity Radiometer Irradiance Monitor (ACRIM) permit a preliminary assessment. The satellite data exhibit irradiance variations over a spectrum of shorter timescales, but the first 5-yr overall trend indicates slightly decreasing luminosity. The global temperature response to monthly-mean ACRIM-measured fluctuations from 1980–1984 was computed from the NYU 1D transient climate model - which includes thermal inertia effects of the world oceans - starting from an assumed pre-existing steady state, and the results compared with observations of recent global temperature trends. The modeled surface temperature evolution exhibited a complex history-dependent behavior whose fluctuations were an order of magnitude smaller than observed, primarily owing to oceanic thermal damping. Thus solar variability appears unlikely to have been an important factor in global-scale climate change over this period. The possibility of using the measurements to develop simple correlations for irradiance with longer term solar activity observable from the surface, and therefore to analyze historical effects, was considered, but is not supported by the satellite data. However, we have used a model of solar irradiance variation with time (Schatten, 1988), covering the period 1976–1997 in order to assess our model's response to forcing whose fluctuation timescale is comparable to the thermal relaxation time of the upper ocean. Continuous monitoring of solar flux by space-based instruments over timescales of 20 yr or more, comparable to timescales for thermal relaxation of the oceans, and of the solar cycle itself, is probably needed to resolve issues of long-term solar variation effects on climate.Presently at Lamont-Doherty Geological Observatory of Columbia University, Palisades, NY 10964.     

Spatial and temporal variations in soil chemistry on the Amazon floodplain

Soil samples were collected on the floodplains of the Amazon River and its principal Brazilian tributaries during dry, early rising water, and early falling water periods. The concentrations of basic cations and pH in these alluvial soils were always higher than those in the more common terra firme soils while the concentrations of aluminum were generally lower. Among the alluvial soils, those from the main channel floodplain were generally higher in basic cations and pH, and lower in aluminum than those from the tribuary floodplains. The concentrations of basic cations in soils along the main channel floodplain decreased downstream. No significant difference was found in the levels of basic cations, pH, or aluminum between sampling periods.     

The heat-capacity of ilmenite and phase equilibria in the system Fe-T-O

Low temperature adiabatic calorimetry and high temperature differential scanning calorimetry have been used to measure the heat-capacity of ilmenite (FeTiO₃) from 5 to 1000 K. These measurements yield S₂₉₈⁰ = 108.9 J/(mol · K). Calculations from published experimental data on the reduction of ilmenite yield Δ₂₉₈⁰(I1) = ?1153.9 kJ/(mol · K). These new data, combined with available experimental and thermodynamic data for other phases, have been used to calculate phase equilibria in the system Fe-Ti-O. Calculations for the subsystem Ti-O show that extremely low values of $\text{?O}{}_2$ are necessary to stabilize TiO, the mineral hongquiite reported from the Tao district in China. This mineral may not be TiO, and it should be re-examined for substitution of other elements such as N or C. Consideration of solid-solution models for phases in the system Fe-Ti-O allows derivation of a new thermometer/oxybarometer for assemblages of ferropseudobrookite-pseudobrookite_ss and hematite-ilmenite_ss. Preliminary application of this new thermometer/oxybarometer to lunar and terrestrial lavas gives reasonable estimates of oxygen fugacities, but generally yields subsolidus temperatures, suggesting re-equilibration of one or more phases during cooling.     

Optical observations of line profile variability in the WN5 star HD 50896

The WN5 star HD 50896 is a well known variable star but the cause of the variations is uncertain. As part of an extensive observing campaign on HD 50896, 68 spectra were obtained with the AAT and UCL echelle spectrograph over three nights in January 1991. The variations seen in the emission line profiles of He II 4686, He II 4860, N V 4945 and N V 4603, 4620, sampling different regions of the wind, are described. Gross night-to-night changes are seen in the tops of all the emission lines, with the pattern of variability being different for each line, as a consequence of the different line formation regions. The edges of the emission line profiles are seen to shift but not in a systematic way, as expected for binary motion. In terms of hourly variations which monitor the propagation of instabilities in the wind, distinct blobs are seen moving outwards through the emission line profiles of the He II lines but are absent in NV 4945. This appears to indicate that, at least for the epoch of these observations, the instabilities develop farther out in the wind than the N V formation region and may well rule out photospheric-induced wind instabilities.     

Comparison of the EMEP, RADM2 and RACM Mechanisms

A comparison of the atmospheric chemistry mechanisms EMEP (Co-operative Programme for Monitoring and Evaluation of the Long-Range Transmission of Air Pollutants in Europe), RADM2 (Regional Acid Deposition Model, version 2) and RACM (Regional Atmospheric Chemistry Mechanism) has been conducted. Each mechanism was used to simulate the PLUME case of Kuhn et al. (1998) and to simulate an additional 150 and 81 scenarios with and without emissions, respectively. These simulations covered scenarios that ranged from relatively clean, through rural and polluted urban conditions. Ozone isopleths and scatter plots were generated from the simulations. The mechanisms were compared primarily on the basis of calculated ozone and ozone precursor concentrations. For the gas-phase ozone precursors the differences between the mechanisms were rather small under clean conditions and more significant under polluted conditions. The differences were especially significant for the concentrations of NO₂ and organic peroxy radicals. In general the EMEP mechanism yielded the most ozone and the RADM2 mechanism yielded the least. Furthermore the results suggest that a broad range simulation conditions should be used to compare mechanisms and not just a few selected scenarios.