Spatial and temporal variation of organic carbon in the northern South China Sea revealed by sedimentary records

Three sediment cores were taken from the Pearl River estuary and adjacent northern South China Sea (SCS). These sediment cores span the time interval 1900–2000 AD. The stratigraphy of the concentration, the ratio of total organic carbon (TOC) to total nitrogen (TN) and stable isotope (δ¹³C_org) of organic carbon (OC) from three high-resolution sediment cores were analyzed. The stratigraphic profiles of OC concentration, TOC/TN ratios and δ¹³C_org for the near past 100 yrs indicate that terrestrial organic matter decreases from 68.3% to 27.4% of the TOC in the Pearl River estuary, while Dapeng Bay (offshore east of Hong Kong) apparently had throughout little terrestrial organic matter input. The highest deposited OC occurs at the Humen River mouth and the OC concentrations are higher in the outer estuary than in the inner shelf of the northern SCS. The deposited OC at the River mouth increased with time, which could be caused by the high precipitation of land-derived organic matter and the high input of terrestrial organic matter, which is likely related to the rapid urbanization and industrial development in the Pearl River Delta since the 1970s. The OC concentrations did not exhibit an obvious increase with time in most areas of the Pear River estuary and adjacent inner shelf of the SCS, but the algal-derived OC concentration inferred from the δ¹³C_org values increased with time especially from 1980 to 2000 in the outer Pearl River estuary and Dapeng Bay. This increase is presumably caused by enhanced primary marine productivity supported by higher anthropogenic nutrient inputs.     

Late Quaternary climatic history of the Chilean Channels based on fossil pollen and beetle analyses,with an analysis of the modern vegetation and pollen rain

Fossil beetles and pollen were examined from an intermorainal bog at Puerto Edén, Isla Wellington, Chile (latitude 49°08'S, longitude 74°25'W). Wood from near the base of the section has an age of 12 960 ± 150 yr BP. Occurrence of flightless beetle species in the basal peat sample is evidence that some members of the biota survived the last glacial maximum in refugia. The assumption that the Chilean Channels were entirely ice-covered is incorrect. Plants and insects that invaded the deglaciated terrain were those of an Empetrum heathland in which patches of Nothofagus forest were restricted to sheltered locations. The climate supporting the heathland is inferred to have been windier and probably drier than that of the present day. From 13 000 yr BP to 9500 yr BP Nothofagus forest expanded, possibly in response to less windiness and more available moisture. Neither the fossil beetle nor pollen data support a return to significantly colder conditions between 11 000 and 10 000 yr BP at the time of the Younger Dryas Stade. From 9500 to 5500 yr BP the climate was as wet as that of the present day, based on an increased representation of the pollen of moorland plants and of aquatic beetle species. From 5500 to 3000 yr BP the climate was drier, as indicated by the expansion of Empetrum heath and the reduction in mesic habitats. From 3000 yr BP to the present-day mesic habitats dominated as the climate returned to a wetter mode. The alternatively wetter and drier episodes are attributed to latitudinal shifts in the position of storm tracks in the belt of Southern Westerlies.     

Variations in the content and distribution of n-alkanes in a series of carboniferous vitrinites and sporinites of bituminous rank

n-Alkanes in the soluble organic matter extracted from a series of vitrinite and sporinite concentrates have been analysed by gas chromatography. The macerals were isolated from coals ranging in rank from 77.1% to 86.6% carbon (vitrinite: dry, ash-free), and yields of n-alkanes ranged from 10 to 580 ppm for vitrinites and from 20 to 970 ppm for sporinites. The maximum yields were found at a rank of 85.4% C from vitrinites and 86.6% C from sporinites.Distribution maxima of the n-alkanes, as shown by gas chromatography, range from C₂₇ and C₂₉ at lower ranks to as low as C₁₆ at higher ranks. The distributions also show a progressive decrease in the preference of odd-carbon-number homologues with increasing rank. Virtually smooth distributions were attained in high-volatile bituminous A coals. Quantitative data show that the loss of the odd-carbon-number preference occurred, for the most part, while individual long-chain homologues increased in concentration.There is a progressive increase in the amounts of shorter-chain n-alkanes with increasing rank. It is suggested that sequential processes may have occurred whereby the rate of formation of long-chain n-alkanes in high-volatile bituminous A rank macerals becomes slower than their rate of subsequent fragmentation to shorter chain lengths. Consequently, assuming derivation from the insoluble maceral matrices, the chain-length distributions of parent n-alkyl structures within the insoluble material may retain characteristics pertaining more to the nature of the source organic matter at the time of deposition than do the extractable n-alkane patterns, especially at higher ranks.     

Geochemical characteristics of Cocos Plate seamount lavas

A wide compositional continuum of basalts has been erupted from near-ridge seamounts constructed on the Cocos Plate between the Clipperton and Orozco Francture Zones. They range from highly evolved to moderately primitive (3.0–7.8% MgO), LREE-enriched alkali basalts, to moderately evolved to near-primary (5.2–9.5% MgO) tholeiites indistinguishable from N-type MORB. The data set of 159 quench glass analyses exhibits a remarkably consistent variation in both major and trace element composition that is keyed to variations in (La/Sm). Modeling of potential liquid lines of descent at pressures ranging from 1 bar to 8 kbar shows that this covariation is partially due to systematic differences in liquid lines of descent, where the alkaline lavas have undergone substantially more high pressure clinopyroxene fractionation and substantially less low pressure plagioclase fractionation than the tholeiites. In addition, systematic variation in the composition of the more primitive glasses indicates that they were derived from mixing of discrete enriched and depleted melts in the heterogenous seamount mantle source at pressures of 8–10 kbar and greater, and that clinopyroxene may be a residual phase during partial melting. These results show that porous media flow in the seamount mantle source is minor and that melt transport is accomplished primarily through cracking and diking. This study supports suggestions that the general homogeneity of basalt along the EPR is due to mixing in sub-axial magma chambers and mush zones, with additional mixing during partial mantle melting and melt segregation.     

A discrete particle representation of hillslope hydrology: hypothesis testing in reproducing a tracer experiment at Gårdsjön,Sweden

Despite the long history of the continuum equation approach in hydrology, it is not a necessary approach to the formulation of a physically based representation of hillslope hydrology. The Multiple Interacting Pathways (MIPs) model is a discrete realization that allows hillslope response and transport to be simultaneously explored in a way that reflects the potential occurrence of preferential flows and lengths of pathways. The MIPs model uses random particle tracking methods to represent the flow of water within the subsurface alongside velocity distributions that acknowledge preferential flows and transition probability matrices, which control flow pathways. An initial realization of this model is presented here in application to a tracer experiment carried out in Gårdsjön, Sweden. The model is used as an exploratory tool, testing several hypotheses in relation to this experiment. Copyright © 2011 John Wiley & Sons, Ltd.     

Holocene displacement along branch and secondary faults in the San Andreas fault zone, southern California

Detailed geologic mapping of the San Andreas fault zone in Los Angeles County since 1972 has revealed evidence for diverse histories of displacement on branch and secondary faults near Palmdale. The main trace of the San Andreas fault is well defined by a variety of physiographic features. The geologic record supports the concept of many kilometers of lateral displacement on the main trace and on some secondary faults, especially when dealing with pre-Quaternary rocks. However, the distribution of upper Pleistocene rocks along branch and secondary faults suggests a strong vertical component of displacement and, in many locations, Holocene displacement appears to be primarily vertical. The most recent movement on many secondary and some branch faults has been either high-angle (reverse and normal) or thrust. This is in contrast to the abundant evidence for lateral movement seen along the main San Andreas fault. We suggest that this change in the sense of displacement is more common than has been previously recognized.The branch and secondary faults described here have geomorphic features along them that are as fresh as similar features visible along the most recent trace of the San Andreas fault. From this we infer that surface rupture occurred on these faults in 1857, as it did on the main San Andreas fault. Branch faults commonly form “Riedel” and “thrust” shear configurations adjacent to the main San Andreas fault and affect a zone less than a few hundred meters wide. Holocene and upper Pleistocene deposits have been repeatedly offset along faults that also separate contrasting older rocks. Secondary faults are located up to 1500 m on either side of the San Andreas fault and trend subparallel to it. Moreover, our mapping indicates that some portions of these secondary faults appear to have been “inactive” throughout much of Quaternary time, even though Holocene and upper Pleistocene deposits have been repeatedly offset along other parts of these same faults. For example, near 37th Street E. and Barrel Springs Road, a limited stretch of the Nadeau fault has a very fresh normal scarp, in one place as much as 3 m high, which breaks upper Pleistocene or Holocene deposits. This scarp has two bevelled surfaces, the upper surface sloping significantly less than the lower, suggesting at least two periods of recent movement. Other exposures along this fault show undisturbed Quaternary deposits overlying the fault. The Cemetery and Little Rock faults also exhibit selected reactivation of isolated segments separated by “inactive” stretches.Activity on branch and secondary faults, as outlined above, is presumed to be the result of sympathetic movement on limited segments of older faults in response to major movement on the San Andreas fault. The recognition that Holocene activity is possible on faults where much of the evidence suggests prolonged inactivity emphasizes the need for regional, as well as detailed site studies to evaluate adequately the hazard of any fault trace in a major fault zone. Similar problems may be encountered when geodetic or other studies, Which depend on stable sites, are conducted in the vicinity of major faults.     

Bayesian updating revisited

Bayesian updating methods provide an alternate philosophy to the characterization of the input variables of a stochastic mathematical model. Here, a priori values of statistical parameters are assumed on subjective grounds or by analysis of a data base from a geologically similar area. As measurements become available during site investigations, updated estimates of parameters characterizing spatial variability are generated. However, in solving the traditional updating equations, an updated covariance matrix may be generated that is not positive-definite, particularly when observed data errors are small. In addition, measurements may indicate that initial estimates of the statistical parameters are poor. The traditional procedure does not have a facility to revise the parameter estimates before the update is carried out. alternatively, Bayesian updating can be viewed as a linear inverse problem that minimizes a weighted combination of solution simplicity and data misfit. Depending on the weight given to the a priori information, a different solution is generated. A Bayesian updating procedure for log-conductivity interpolation that uses a singular value decomposition (SVD) is presented. An efficient and stable algorithm is outlined that computes the updated log-conductivity field and the a posteriori covariance of the estimated values (estimation errors). In addition, an information density matrix is constructed that indicates how well predicted data match observations. Analysis of this matrix indicates the relative importance of the observed data. The SVD updating procedure is used to interpolate the log-conductivity fields of a series of hypothetical aquifers to demonstrate pitfalls and possibilities of the method.     

A spatially resolved 'inside-out' outburst of IP Pegasi

We present a comprehensive photometric data set taken over the entire outburst of the eclipsing dwarf nova IP Peg in 1997 September/October. Analysis of the light curves taken over the long rise to the peak-of-outburst shows conclusively that the outburst started near the centre of the disc and moved outwards. This is the first data set that spatially resolves such an outburst. The data set is consistent with the idea that long rise times are indicative of such 'inside-out' outbursts. We show how the thickness and the radius of the disc, along with the mass transfer rate, change over the whole outburst. In addition, we show evidence of the secondary and the irradiation thereof. We discuss the possibility of spiral shocks in the disc; however, we find no conclusive evidence of their existence in this data set.     

Virtual water ‘flows’ of the Nile Basin, 1998–2004: A first approximation and implications for water security

This paper interprets an initial approximation of the ‘trade’ in virtual water of Nile Basin states in terms of national water security. The virtual water content (on the basis of weight) of select recorded crop and livestock trade between 1998 and 2004 is provided, and analysed for each state separately, for the Southern Nile and Eastern Nile states as groups, and for the basin states as a whole. To the extent that the datasets allow, the distinction between rainfed and irrigated production is maintained. During the period under study, Nile Basin states ‘exported’ about 14,000 Mm³ of primarily rainfed-derived virtual water outside of the basin annually and ‘imported’ roughly 41,000 Mm³/y. The ‘imports’ are considered to have played a key role in filling the freshwater deficits of Egypt and Sudan, and represent a third of the flow of the Nile River itself. Analysis of food trade within the basin shows that the equivalent of small rivers of water used to raise coffee and tea ‘flow’ from the highlands around Lake Victoria to Egypt and Sudan. Because the bulk of these ‘flows’ derive from rainfed agriculture, the virtual water ‘traded’ annually between the Nile Basin states is not considered to represent a significant demand on the water resources of the basin, nor to significantly remedy the freshwater deficits of the arid basin states. The importance of soil water and rainfed farming is in improving water security is highlighted. The limitations and merits of the inter-state basin-wide approach are also discussed. By highlighting the magnitude of water leaving and entering states in its virtual form, the approach obliges policy-makers to think beyond the basin and reconsider the concept of water security within broader political, environmental, social and economic forces.     

Classification of Streaky Bay,Mangalo, Ethiudna and Crockers Well: Stony meteorites from South Australia

Abstract— Four meteorites from South Australia are described and classified. Streaky Bay (L4b) and Mangalo (L6e) were received by the South Australian Museum in December, 1989. Ethiudna (L4a) and Crockers Well (LL7) were previously thought to be paired and were previously described only as chondrites.