Fitness-for-Purpose of Reference Material Reference Values in Relation to Traceability of Measurement, as Illustrated by USGS BCR-1, NIST SRM 610 and IAEA NBS28

As in all fields of sample analysis, reference materials play a large role in supporting measurements in the geosciences. While a rather large number of materials are in distribution (> 380), not all are equally effective or fit-for-purpose in supporting laboratory data quality and thereby assuring the desired comparability of measurements between laboratories. Equally important, reference values that are not fit-for-purpose cannot be used effectively to establish traceability links between laboratory measurements and national and international standards. The needed fitness-for-purpose is not achieved for reference values either when more than one reference value has been proposed and a consensus does not exist among users as to which should be used by all, or when reference value uncertainties are too large in comparison to those of routine laboratory measurements. The focus of this review will be, first to outline the current reality, and second to suggest ways in which certifications of RMs can be improved to provide reference values that are universally accepted and more fit-for-purpose in general laboratory use. The discussion will be illustrated largely by current uses of USGS BCR-1, NIST SRM 610 and IAEA NBS28, as these three materials are those for which the largest body of newly published data exists, according to recent bibliographies of the geoanalytical literature published annually in Geostandards Newsletter: The Journal of Geostandards and Geoanalysis.     

Variability of theS q focus position in the South American continent

The daily variation of the H component at Pilar (31.7°S, 63–9°W) and Trelew (43.3°S, 65.3°W) in the South American continent indicates a great variability in amplitude from season to season and even from day to day. However, Pilar always remains equatorward of the southern S_q, focus. On the other hand, Trelew is in most cases slightly poleward of the S_q, focus; but the focus has large latitudinal excursions above and near Trelew. A cause of this variability could be the encroachment of polar ionospheric current systems into the low latitude ionospheric S_q, current system.     

Periodicities in sea-level changes at Stockholm

The annual mean sea-level time series for Stockholm (Sweden) for 1825–1984 (160 data points) had a large long-term negative (almost linear, only slightly quadratic) trend. After correcting for the same, the detrended series was subjected to maximum entropy spectral analysis (MESA). Choosing selected periodicities for further multiple regression analysis, series for the first 80 yr (1825–1904) showed periodicities at T = 2.40, 5.0, 6.1, 13.5, 14.8 and 32 yr, significant at a 2 level. The three largest peaks (italicized) had amplitudes of approximately (2.5–3.0) ± 0.8 cm. The latter 80 yr (1905–1984) showed significant periodicities at T= 2.05, 2.7, 3.0, 3.6, 4.4, 5.5, 6.3, 7.7, 9.8, 20.5 and 33 yr. The three largest peaks (italicized) had amplitudes of approximately (2.0–2.5) ± 0.7 cm. The whole period of 160 yr (1825–1984) showed significant periodicities at T = 2.05, 2.9, 3.2, 4.5, 4.9, 5.6, 6.4, 7.8, 11.0, 13.7, 14.8, 29 and 43 yr. The three largest peaks (italicized) had amplitudes of approximately (1.6–1.9) ± 0.6 cm. All these significant peaks explained a variance of only about 30% or less, indicating a large random component of approximately 70%. Peaks at T = 11 yr (sunspot cycle) or T = 18.6 yr (lunar nodal term) were either absent or very weak. Most of the other peaks were transient (present in the first 80 yr or the latter 80 yr) except an uncertain quasibiennial oscillation (QBO) (T = 2–3 yr) and T = 5–6 yr and T 30 yr, which seemed to be persistent throughout the whole period. Some periodicities seem to resemble those seen in the Southern Oscillation (SO) index.     

Simulations for multi-object spectrograph planet surveys

Radial velocity surveys for extrasolar planets generally require substantial amounts of large telescope time in order to monitor a sufficient number of stars. Two of the aspects which can limit such surveys are the single-object capabilities of the spectrograph, and an inefficient observing strategy for a given observing window. In addition, the detection rate of extrasolar planets using the radial velocity method has thus far been relatively linear with time. With the development of various multi-object Doppler survey instruments, there is growing potential to dramatically increase the detection rate using the Doppler method. Several of these instruments have already begun usage in large-scale surveys for extrasolar planets, such as Fibre Large Array Multi Element Spectrograph (FLAMES) on the Very Large Telescope (VLT) and Keck Exoplanet Tracker (ET) on the Sloan 2.5-m wide-field telescope.
In order to plan an effective observing strategy for such a program, one must examine the expected results based on a given observing window and target selection. We present simulations of the expected results from a generic multi-object survey based on calculated noise models and sensitivity for the instrument and the known distribution of exoplanetary system parameters. We have developed code for automatically sifting and fitting the planet candidates produced by the survey to allow for fast follow-up observations to be conducted. The techniques presented here may be applied to a wide range of multi-object planet surveys.     

Detecting the signatures of Uranus and Neptune

With more than 15 years since the first radial velocity discovery of a planet orbiting a Sun-like star, the time baseline for radial velocity surveys is now extending out beyond the orbit of Jupiter analogs. The sensitivity to exoplanet orbital periods beyond that of Saturn orbital radii however is still beyond our reach such that very few clues regarding the prevalence of ice giants orbiting solar analogs are available to us. Here we simulate the radial velocity, transit, and photometric phase amplitude signatures of the Solar System giant planets, in particular Uranus and Neptune, and assess their detectability. We scale these results for application to monitoring low-mass stars and compare the relative detection prospects with other potential methods, such as astrometry and imaging. These results quantitatively show how many of the existing techniques are suitable for the detection of ice giants beyond the snow line for late-type stars and the challenges that lie ahead for the detection true Uranus/Neptune analogs around solar-type stars.     

Relationship between the geomagnetic Dst(min) and the interplanetary Bz(min) during cycle 23

In cycle 23 for geomagnetic storms of ?Dst(min) >50 nT, the plot of ?Dst(min) versus ?Bz(min) for the low ?Bz(min) range 0–10 nT showed erratic variation in Dst(min), (correlation 0.19). Even for ?Bz(min) range 10–20 nT, ?Dst(min) values had considerable scatter (correlation 0.57). For ?Bz(min).>20 nT, the relationship was good (correlation 0.82). For the whole range ?Bz(min) 0–50 nT, the correlation was high (0.88). Thus, if ?Bz(min) is very large (～20 nT), large ?Dst(min) occurs but in a wide range of 100–500 nT.     

Submarine channel levee shape and sediment waves from physical experiments

Submarine channel levees aggrade through repeated overspill events from the channel axis. The shape of the levees may therefore reflect some characteristic(s) of the overspilling flow. It has been noted that basin floor levees typically have a relatively low-relief and taper exponentially to their termination; in contrast slope channel levees may be much steeper close to the channel. A simple physical experiment was performed where a surge-like sediment-laden current flowed through a curved channel. Significant overspill occurred and generated a deposit flanking the channel on either side. The experiment was repeated 25 times to build up low-relief channel-levees. It was found that in proximal areas, levees were steep and characterised by power-law decays, a transitional zone of logarithmically thinning levee was found a little further down-channel, followed by exponential decays in medial to distal areas. The style of levee decay is a function of spatial variation in overbank sedimentation rates. Where flows rapidly lose momentum and deposit across the grain-size spectrum, i.e., in proximal areas, levees tend to be steep; farther down the channel, the steep levee slope gives way to a more gradually tapering deposit. In more distal parts of the channel, deposition is directly related to sediment settling velocity (rather than the suspended load exceeding flow transport capacity as is the case in proximal areas), the deposit reflects this with relatively simple exponential thickness decays. Additionally, small-scale sediment waves developed under lee wave conditions on the inner-bend overbank. The waves initially migrated slightly towards the channel, but as the style of overspill evolved due to intra-channel deposition, flows moved out of the lee wave window and sedimentation became out of phase with the wavelength of the features and the topography was healed.     

Water-poverty relationships in the coastal town of Mbour (Senegal): Relevance of GIS for decision support

Coastal area is always a zone with complex problems. Due to the attraction they exert, are facing many social problems. Therefore, a coastal city is usually a city with problems. Its extension, caused by the influx of people from different backgrounds, creates an increased demand for services. One of the problems frequently encountered, especially in Senegal, is access to water. The problem of access to water is poorly treated, without being correlated with the urban evolution, i.e. with increasing population and demand growth. The water resource is facing numerous complications such as the lack of integrated management, integration issues at the governance level, where the local factor is often forgotten.The town of Mbour, object of our study, does not come out of that lot, being an attractive coastal city, from an African country. This indicates the need for an integrated management oriented from local to a global basis and not vice versa. The study presented in this paper indicates that a large proportion of the population has not access to a verified drinking water system and uses water from wells or standpipes. Half of the surveyed population (50%) has no access to a water supply system. The water poverty map of the town overlaps with that of the general poverty excepting few neighborhoods. This means that even areas that are not affected by poverty have a very low or poor access to water, which so far remains the perverse effect of the reform of the Senegalese water sector in 1995.     

The color of the Kuiper belt Core

Recent dynamical analyses of the Kuiper belt have introduced a rigorous classification scheme, determined the mean orbital plane, and identified “Core” and “Halo” populations as a function of inclination with respect to this plane (Elliot, J.L., Kern, S.D., Clancy, K.B., Gulbis, A.A.S., Millis, R.L., Buie, M.W., Wasserman, L.H., Chiang, E.I., Jordan, A.B., Trilling, D.E., Meech, K.J., 2005. Astron. J. 129, 1117-1162). Here, we use new observations and existing data to investigate the colors of Kuiper belt objects (KBOs) within this framework. With respect to the bulk KBO color distribution (all objects for which we have B-V and V-R colors; median B-R=1.56), we find that the population of objects classified following (Elliot, J.L., Kern, S.D., Clancy, K.B., Gulbis, A.A.S., Millis, R.L., Buie, M.W., Wasserman, L.H., Chiang, E.I., Jordan, A.B., Trilling, D.E., Meech, K.J., 2005. Astron. J. 129, 1117-1162) as Classical tends to be red (B-R>1.56) while the Scattered Near population is mostly neutral (B-R<1.56). Colors of Scattered Extended and Resonant objects are consistent with the bulk distribution. Separating objects into specific resonances demonstrates that the color of the Resonant sample is dominated by KBOs in the 3:2 resonance, which is consistent with previous findings. Unlike the objects in the 3:2 resonance, however, the majority of objects in the 5:2 resonance are neutral and all but one of the objects in the 4:3, 5:3, 7:4, 2:1, and 7:3 resonances are red. In particular, the objects in the 7:4 resonance are remarkably red. We find that the colors of KBOs in the Core (low-inclination) and Halo (high-inclination) are statistically different, with Core objects being primarily red and Halo objects having a slight tendency to be neutral. Notably, virtually all of the non-Resonant Core objects are red. This combination of low inclination, unperturbed orbits and red colors in the Core may be indicative of a relic grouping of objects.