Structures associated with inversion of the Donbas Foldbelt (Ukraine and Russia)

The Donbas Foldbelt is part of the Prypiat–Dnieper–Donets intracratonic rift basin (Belarus–Ukraine–southern Russia) that developed in Late Devonian times and was reactivated in Early Carboniferous. To the southeast, the Donbas Foldbelt joins the contiguous, deformed Karpinsky Swell. Basin “inversions” led first to the uplift of the Palaeozoic series (mainly Carboniferous but also syn-rift Devonian strata in the southwesternmost part of the Donbas Foldbelt, which are deeply buried in the other parts of the rift system), and later to the formation of the fold-and-thrust belt. The general structural trend of the Donbas Foldbelt, formed mainly during rifting, is WNW–ESE. This is the strike of the main rift-related fault zones and also of the close to tight “Main Anticline” of the Donbas Foldbelt that developed along the previous rift axis. The Main Anticline is structurally unique in the Donbas Foldbelt and its formation was initiated in Permian times, during a period of (trans) tensional reactivation, during which active salt movements occurred. A relief inversion of the basin also took place at this time with a pronounced uplift of the southern margin of the basin and the adjacent Ukrainian Shield. Subsequently, Cimmerian and Alpine phases of tectonic inversion of the Donbas Foldbelt led to the development of flat and shallow thrusts commonly associated with folds into the basin. A fan-shaped deformation pattern is recognised in the field, with south-to southeast-vergent compressive structures, south of the Main Anticline, and north- to northwest-vergent ones, north of it. These compressive structures are clearly superimposed onto the WNW–ESE structural grain of the initial rift basin. Shortening structures that characterise the tectonic inversion of the basin are (regionally) orientated NW–SE and N–S. Because of the obliquity of the compressive trends relative to the WNW–ESE strike of inherited structures (major preexisting normal faults and the Main Anticline), in addition to reverse displacements, right lateral movements occurred along the main boundary fault zones and along the faulted hinge of the Main Anticline. The existence of preexisting structures is also thought to be responsible for local deviations in contractional trends (that are E–W in the southwesternmost part of the basin).     

Geomorphological evidence of the influence of pre-volcanic basement structure on emplacement and deformation of volcanic edifices at the Cofre de Perote–Pico de Orizaba chain and implications for avalanche generation

Pre-volcanic structure of the basement influences volcanism distribution and avalanche generation in volcanic edifices. Therefore, systematic studies of basement structure below volcanic chains are necessary to understand the deformation effects observed in the surface and vice versa. Based on a compilation of pre-existing data, interpretation of aerial photographs and satellite images, and a collection of structural data we analyzed morphological and structural features of the Cofre de Perote–Pico de Orizaba (CP–PO) volcanic chain and its basement. We have identified three sets of regional lineaments that are related to basement trends. (1) NW 55° SE fractures are parallel to anticline folds observed in Cretaceous rocks that originated during Laramide shortening. These folds present an abrupt morphology observed only in the eastern flank but that is likely to continue below the volcanic chain. (2) NE 55° SW fractures are parallel to normal faults at the basement. We infer that these basement faults confine the CP–PO chain within a stepped graben with a total normal displacement of about 400 m. These faults have been active through time since they have affected volcanic deposits and induced the emplacement of monogenetic vents. Notably, lineaments of monogenetic vents concentrate where the basement is relatively shallow. (3) Another set of faults, oriented N–S, has been observed affecting the scarce basement outcrops at the western flank of the chain covered by lacustrine deposits. Lineaments measured in the volcanic edifice of Pico de Orizaba correlate with the regional trends.In particular, the NE 55° SW alignment of monogenetic vents and fractures at Pico de Orizaba suggest that the same dike trend exists within the volcanic edifice. A normal fault with similar orientation was documented at the NE continuation of an alignment crossing the volcanic edifice along the Jamapa canyon. In the absence of magmatic activity related to collapses, the displacement of NE 55° SW faults represents a potential triggering mechanism for generating avalanches at Pico de Orizaba volcano. Instability is enhanced by the presence of N–S trending fractures crossing the entire volcanic edifice and E–W fractures affecting only the present day cone. We conclude that mechanical instability of the volcanic chain is influenced by the basement structure heterogeneity, but further detailed studies are necessary at individual volcanoes to evaluate their effects on volcano deformation.     

Organo-colloidal control on major- and trace-element partitioning in shallow groundwaters: Confronting ultrafiltration and modelling

Ultrafiltration experiments using new small ultracentifugal filter devices were performed at different pore size cut-offs to allow the study of organo-colloidal control on metal partitioning in water samples. Two shallow, circumneutral pH waters from the Mercy site wetland (western France) were sampled: one dissolved organic carbon (DOC)- and Fe-rich and a second DOC-rich and Fe-poor. Major- and trace-element cations and DOC concentrations were analysed and data treated using an ascendant hierarchical classification method. This reveals the presence of three groups: (i) a “truly” dissolved group (Na, K, Rb, Ca, Mg, Ba, Sr, Si and Ni); (ii) an inorganic colloidal group carrying Fe, Al and Th; and (iii) an organic colloidal group enriched in Cr, Mn, Co, Cu and U. However, REE and V have an ambivalent behaviour, being alternatively in the organic pool and in the inorganic pool depending on sample. Moreover, organic speciation calculation using Model VI were performed on both samples for elements for which binding constants were available (Ca, Mg, Ni, Fe, Al, Th, Cr, Cu, Dy, Eu). Calculation shows relatively the same partitioning of these elements as ultrafiltration does. However, some limitations appear such as (i) a direct use of ultrafiltration results which tends to overestimate the fraction of elements bound to humic material in the inorganic pool as regards to model calculations as well as, (ii) a direct use of speciation calculation results which tends to overestimate the fraction of elements bound to humic material in the organic pool with regard to ultrafiltration results. Beside these limitations, one can consider that both techniques, ultrafiltration and speciation calculation, give complementary information, especially for more complex samples where inorganic and organic colloids compete.     

Paleostress field reconstruction in the Oslo region

The geodynamic history of a region is archived in its geologic record which, in turn, may reflect deformation patterns that causally can be related to certain configurations of paleostresses. In the Oslo Region, the exposed geological record ranges from Precambrian high-grade metamorphic rocks through Cambro-Silurian sedimentary rocks to Permo-Carboniferous sedimentary and magmatic rocks, the latter being related to the development of the Oslo rift system. We investigate the kinematics of outcrop-scale faults to derive the diversity of paleostress states responsible for the observed strain. For this purpose, we combine different graphical and numerical approaches to separate heterogeneous fault-slip data sets and estimate the associated reduced stress tensors. A reduced stress tensor consists of the directions of the three principal stress axes with σ₁ ≥ σ₂ ≥ σ₃ and the ratio of principal stress differences, R = (σ₂ − σ₃)/(σ₁ − σ₃).     

Colloidal Control on the Distribution of Rare Earth Elements in Shallow Groundwaters

A 7-year monitoring period of rare earth element (REE) concentrations and REE pattern shapes was carried out in well water samples from a 450 m long transect setup in the Kervidy/Coët-Dan experimental catchment, France. The new dataset confirms systematic, topography-related REE signatures and REE concentrations variability but challenges the validity of a groundwater mixing hypothesis. Most likely, this is due to REE preferential adsorption upon mixing. However, the coupled mixing–adsorption mechanism still fails to explain the strong spatial variation in negative Ce anomaly amplitude. A third mechanism—namely, the input into the aquifer of REE-rich, Ce anomaly free, organic colloids—is required to account for this variation. Ultrafiltration results and speciation calculations made using Model VI agree with this interpretation. Indeed, the data reveal that Ce anomaly amplitude downslope decrease corresponds to REE speciation change, downhill groundwaters REE being mainly bound to organic colloids. Water table depth monitoring shows that the colloid source is located in the uppermost, organic-rich soil horizons, and that the colloid input occurs mainly when water table rises in response to rainfall events. It appears that the colloids amount that reaches groundwater increases downhill as the distance between soil organic-rich horizons and water table decreases. Topography is, therefore, the ultimate key factor that controls Ce anomaly spatial variability in these shallow groundwaters. Finally, the <0.2 μm REE fraction ultimately comes from two solid sources in these groundwaters: one located in the deep basement schist; another located in the upper, organic-rich soil horizon.     

Early detection of large eruptions at Piton de La Fournaise volcano (La Réunion Island): Contribution of a distant tiltmeter station

We report a compilation of data recorded at a distant tiltmeter station (RER) during recent episodes of dyke emplacement and eruption (2003–2007) at Piton de La Fournaise volcano (La Réunion Island). This sensitive station provides useful information for evaluating the extent of deformation. Distinct responses of this station were recorded based on the eruption type. Dykes feeding summit eruptions did not significantly influence the RER tiltmeter signals, whereas dykes feeding large distal eruptions (with vents located more than 4 km from the summit) generated up to 1.4 μrad of tilt, an amplitude 2 to 4 times greater than for proximal eruptions (0.3–0.7 μrad) on the flanks of the summit cone. The distinct tilt amplitude is directly linked to the location, depth, and volume of the dyke. Comparison with summit tiltmeters reveals that up to one-third to half of the RER tilt signal associated to dyke propagation is recorded when the dyke is still below the summit crater. Thus, before large distal eruptions, more than 0.5 μrad of tilt is recorded in less than 20 min when the dyke is below the summit crater (i.e. a few minutes/hours before the beginning of the eruption). We can thus propose for the RER station a threshold value of 0.5 μrad which, when reached as a dyke rises beneath the summit crater, suggests a high likelihood of a large distal eruption. The distant RER tiltmeter station thus appears to be a powerful tool for forecasting the type of eruption that is likely to occur, and can contribute to the early detection of large distal eruptions at Piton de La Fournaise, which are the most dangerous to inhabitants. For volcano monitoring, installation of high precision distant tiltmeters along the lower slopes of a volcano may provide warnings of large eruptions with enough lead time to allow for short-term hazards mitigation efforts.     

Adsorption of Cationic Dyes from Aqueous Solution by Termite Feces,a Non‐Conventional Adsorbent

The adsorption of three cationic dyes (rhodamine B, RB; crystal violet, CV; and malachite green, MG) onto termite feces, a low‐cost adsorbent, was investigated. The adsorbent was characterized by IR spectroscopy, point of zero charge measurement, and the Boehm titration method. The adsorption follows the pseudo‐second‐order kinetic model and the Langmuir–Freundlich isotherm with maximum adsorption capacities of 95.53 mg g^?1 (RB), 75.71 mg g^?1 (CV), and 44.78 mg g^?1 (MG). The study of thermodynamics showed that the adsorption is a spontaneous and endothermic process. This works suggest that termite feces can be used as a new low‐cost adsorbent for cationic dye removal.     

Interpretation in terms of gravity waves of structures observed at the mesopause level by photogrammetry and lidar

Experiment data of the vertical distribution of sodium density measured by lidar are compared with the horizontal structures observed by photogrammetry on the sodium emissive layer. The gravity wave induced variations seen in the vertical distribution are used to define a 2-dimensional model of the layer, which is shown to explain the observed horizontal patterns. It is strongly suggested that the structures currently seen on OH can be also related to gravity waves and that their sporadic occurrence in specific angular directions is explained by the wave characteristic and by wave or wind induced chemistry.