Earth and Venus: A comparative study

The observed density of Venus is about 2% smaller than would be expected if Venus were a twin planet of the Earth, possessing an identical internal composition and structure. In principle, this could be explained by a process of physical segregation of metal particles from silicate particles in the solar nebula prior to accretion, so that Venus accreted from relatively metal-depleted material. However, this model encounters severe difficulties in explaining the nature of the physical segregation process and also the detailed chemical composition of the Earth's mantle. Two alternative hypotheses are examined, both of which attempt to explain the density difference in terms of chemical fractionation processes. Both of these hypotheses assume that the relative abundances of the major elements Fe, Si, Mg, Al, and Ca are similar in both planets. According to the first hypothesis, a larger proportion of the total iron in Venus is present as iron oxide in the mantle, so that the core-to-mantle ratio is smaller than in the Earth. This model implies that Venus is more oxidized than the Earth, with its lower intrinsic density (i.e., corrected to equivalent pressures and temperatures) due to the larger amount of oxygen present. The difference between oxidation states is attributed to differing degrees of accretional heating arising from the relatively smaller mass of Venus. On the other hand, the second hypothesis maintains that Venus is more reduced than the Earth, with its mantle essentially devoid of oxidized iron. The difference intrinsic densities is attributed to the Earth accreting at a lower temperature than Venus as a result of the Earth's greater distance from the center of the nebula. As a result, large amounts of sulfur accreted on the Earth but not on Venus. The sulfur, which entered the core, is believed to have increased the mean density of the Earth because of its relatively high atomic weight. The hypothesis also implies that most of the Earth's potassium, because of its chalcophile properties, entered the core.These hypotheses are evaluated in the light of existing data. The second hypothesis leads to an intrinsic density for Venus which is only 0.4% smaller than that of the Earth. This difference is much smaller than is believed to exist. A wide range of chemical evidence is found to be unfavorable to this second hypothesis, but to be consistent with the interpretation that Venus is more oxidized than the Earth, as required by the first hypothesis.     

Stable isotope (O and C) and pollen trends in eastern Lake Erie,evidence for a locally-induced climatic reversal of Younger Dryas age in the Great Lakes basin

A cool period from about 11000 to 10 500 BP (11 to 10.5 ka) is recognized in pollen records from the southern Great Lakes area by the return of Picea and Abies dominance and by the persistence of herbs. The area of cooling appears centred on the Upper Great Lakes. A high-resolution record (ca. 9 mm/y) from a borehole in eastern Lake Erie reveals, in the same time interval, this pollen anomaly, isotope evidence of meltwater presence (a — 3 per mil shift in ¹⁸O and a +1.1 per mil shift in ¹³C), increased sand, and reduced detrital calcite content, all suggesting concurrent cooling of Lake Erie. The onset of cooling is mainly attributed to the effect of enhanced meltwater inflow on the relatively large upstream Main Lake Algonquin during the first eastward discharge of glacial Lake Agassiz. Termination of the cooling coincides with drainage of Lake Algonquin, and is attributed to loss of its cooling effectiveness associated with a substantial reduction in its surface area. It is hypothesized that the cold extra inflow effectively prolonged the seasonal presence of lake ice and the period of spring overturn in Lake Algonquin. The deep mixing would have greatly increased the thermal conductive capacity of this extensive lake, causing suppression of summer surface lakewater temperatures and reduction of onshore growing-degree days. Alternatively, a rapid flow of meltwater, buoyed on sediment-charged (denser) lakewater, may have kept the lake surface cold in summer. Other factors such as wind-shifted pollen deposition and possible effects from the Younger Dryas North Atlantic cooling could have contributed to the Great Lakes climatic reversal, but further studies are needed to resolve their relative significance.Contribution to Climo Locarno — Past and Present Climate Dynamics; Conference September 1990, Swiss Academy of Sciences — National Climate ProgramGeological Survey of Canada Contribution 58 890     

The chemistry of orthophosphate uptake from seawater on to calcite and aragonite

The chemistry of orthophosphate uptake from synthetic seawater onto the surfaces of synthetic calcite, aragonite and low-magnesium biogenic calcite has been studied, in order to elucidate the kinetics of the process (generally believed to be the major control of dissolved reactive phosphate in carbonate-rich marine sediments). Our results differ from those obtained by others, who have studied orthophosphate uptake in low ionic strength solutions and at much higher supersaturations relative to apatite.In both ‘free drift’ and chemostat experiments, Mg and F have only a minor effect on the reaction rate. Even at constant solution composition the rate of orthophosphate uptake was found to decrease by 10⁶ over a two week period. The data from the ‘free drift’ experiments can be fitted to the Elovich equation. This indicates that the kinetics observed for this reaction can be explained by an exponential decrease in available surface reaction sites and/or a linear increase in the activation energy associated with chemisorption as the reaction proceeds.     

Water vapor adsorption by sodium montmorillonite at −5°C

A large amount of interest has recently been expressed pertaining to the quantity of physically adsorbed water by the Martian regolith. Thermodynamic calculations based on experimentally determined adsorption and desorption isotherms and extrapolated to subzero temperatures indicate that physical adsorption of more than one or two monomolecular layers is highly unlikely under Martian conditions. Any additional water would find ice to be the state of lowest energy and therefore the most stable form. To test the validity of the thermodynamic calculations we have measured adsorption and desorption isotherms of sodium montmorillonite at ?5°C. To a first approximation it was found to be valid.     

The appearance of Mars from 1907 to 1971: Graphic synthesis of photographs from the I.A.U. center at Meudon

Using selected high quality plates collected at the I.A.U. Planetary Data Center in Meudon (Paris), the author has drawn 32 Mercator charts of the planet Mars for every opposition from 1907 to 1971. This graphic synthesis of albedo distribution may be used in the study of major surface changes over the years.     

Elucidation of different forms of organic carbon in marine sediments from the Atlantic coast of Spain using thermal analysis coupled to isotope ratio and quadrupole mass spectrometry

Analysis of river, estuary and marine sediments from the Atlantic coast of Spain using thermogravimetry–differential scanning calorimetry–quadrupole mass spectrometry–isotope ratio mass spectrometry (TG–DSC–QMS–IRMS) was used to (a) distinguish bulk chemical hosts for C within a sediment and humic acid fraction, (b) track C pools with differing natural C isotope ratios and (c) observe variation with distance from the coast. This is the first application of such a novel method to the characterisation of organic matter from marine sediments and their corresponding humic acid fractions. Using thermal analysis, a labile, a recalcitrant and a refractory carbon pool can be distinguished. Extracted humic fractions are mainly of recalcitrant nature. The proportion of refractory carbon is greatest in marine sediments and humic acid fractions. Quadrupole mass spectrometry confirmed that the greatest proportion of m/z 44 (CO₂) and m/z 18 (H₂O) were detected at temperatures associated with recalcitrant carbon (510–540 °C). Isotope analysis detected progressive enrichment in δ¹³C for the sediment samples with an increase in marine influence. Isotopic heterogeneity in the refractory organic matter in marine sediments could be due to products of anthropogenic origin or natural combustion products. Isotope homogeneity of humic acids confirms the presence of terrigenous C in marine sediments, allowing the terrestrial input to be characterised.     

Comparative study of sampling methods and in situ and laboratory analysis for shallow-water submarine hydrothermal systems

A primary aim for sampling of submarine hydrothermal vents is to minimize inclusion of ambient seawater. Here, we compare the results of three different sampling methods (air displacement, two-valve bottle, and syringes) for shallow submarine systems. Mixing of hydrothermal fluid with seawater is unavoidable; however, calculations based on linear mixing models allow estimation of the hydrothermal fluid end-member composition. The results show that sampling with a two-valve bottle and syringes are the best options because they allow collection of samples with a large proportion of hydrothermal fluid. Additionally, we compare the results of in situ and laboratory analyses of the fluid samples, and demonstrate that determination of chemical composition in situ is the best option for some components, as re-equilibration affects some component concentrations (i.e. bicarbonate). Conversely, silica determination in situ usually underestimates the concentration in the fluid, as it does not account for polymeric silica. Other components can be measured either in the field or in the laboratory.