A subsidiary fast-diffusing substitution mechanism of Al in forsterite investigated using diffusion experiments under controlled thermodynamic conditions

Diffusion of Al in synthetic forsterite was studied at atmospheric pressure from 1100 to 1500 °C in air along [100] with activities of SiO₂, MgO and Al₂O₃ (a_SiO2, a_MgO and a_Al2O3) buffered. At low a_SiO2, the buffer was forsterite + spinel + periclase (fo + sp + per) at all temperatures, while at high a_SiO2 and subsolidus conditions a variety of three-phase assemblages containing forsterite and two other phases from spinel, cordierite, protoenstatite or sapphirine were used at 1100–1350 °C. Experiments at high a_SiO2 and 1400 °C used forsterite + protoenstatite + melt (fo + en + melt), and at 1500 °C, fo + melt. The resulting diffusion profiles were analysed by LA–ICP–MS in scanning mode. Diffusion profiles in the high a_SiO2 experiments were generally several hundred microns in length, but diffusion at low a_SiO2 was three orders of magnitude slower than in high a_SiO2 experiments carried out at the same temperature, producing short profiles only a few microns in length and close to the spatial resolution of the analytical method. Interface concentrations of Al in the forsterite, obtained by extrapolating the diffusion profiles to the crystal/buffer interface, were only a fraction of those expected at equilibrium, and varied among the differing buffer assemblages according to (a_Al2O3)^1/2 and (a_SiO2)^3/4, pointing to the substitution of Al in forsterite by an octahedral-site, vacancy-coupled (OSVC) component with the stoichiometry Al _4/3 ³⁺ vac_2/3SiO₄, whereas the main substitution expected from previous equilibrium studies would be the coupled substitution of 2 Al for Mg + Si, giving the stoichiometry MgAl₂O₄. It is proposed that this latter substitution is not seen on the length scales of the present experiments because it requires replacement of Si by Al on tetrahedral sites, and is accordingly rate-limited by the slow diffusivity of Si. Instead, diffusion of Al by the OSVC mechanism is relatively fast, and at high a_SiO2, even faster than Fe–Mg interdiffusion.     

基于GIS研究南黄海活动断层与地震的关系

基于GIS缓冲区分析和叠加分析的空间分析方法,定量研究南黄海活动断层与地震的关系.通过对震中与10 km和20 km断层缓冲区的叠加分析得出断层缓冲区内地震的数量,从中看出:走向NE～NEE向断裂是控制地震发生的主要活动断裂;通过对断层和震中缓冲区的叠加分析得出对地震发生有影响的断层的数量.     

新疆OLR基本特征及强震前的异常现象

利用美国国家环境监测中心的NOAA卫星长波辐射(OLR)月际资料进行数据的月距平、涡度场计算等处理,总结分析了新疆地区长波辐射场的基本特征.对2003年以来新疆及其周边地区发生的中强震进行研究,发现在部分地震前震中及附近地区出现较明显的高值辐射异常,认为这种现象可能与强震前的地一气系统变化有关.应用OLR资料进行新疆地区的地震趋势预测研究可在一定程度上弥补前兆台网监测能力的不足.     

Urban environments as habitats for rare aquatic species: The case of leeches (Euhirudinea, Clitellata) in Warsaw freshwaters

Reduced biological diversity in freshwater habitats situated in urban areas has been discussed in numerous studies. Certain municipal areas, however, can help save animal diversity of freshwater invertebrates. In the present study animals were collected or observed alive in 13 freshwater environments localized in Warsaw - the second largest city of Central Europe - in a densely populated, urban building complex close to the city, and also in suburban areas. Leech assemblages in all the environments under observation were numerically dominated by a few common species, but on the whole 19 species were collected or observed. The populations of six rare leech species inhabit both flowing and standing waters in Warsaw. Five of these species are on the Polish Red List of Species and one is strictly protected. The shallow Lake Powsinkowskie is the richest freshwater environment in the studied area in terms of species richness and rarity and also one of the richest lakes in Poland. Taxonomic diversity in the environments under study seems not to be directly related to the size of the water body or the level of degradation but rather to the habitat complexity, especially the diversity of the bottom in littoral zone. Certain freshwater habitats located inside this great urban complex still create good conditions for rare, highly specialized species.     

Difference of mercury bioaccumulation in red mullets from the north-western Mediterranean and Black seas

The relationships between total mercury (Hg) concentration and stable nitrogen isotope ratio (δ¹⁵N) were evaluated in Mullus barbatus barbatus and M. surmuletus from the Mediterranean Sea and M. barbatus ponticus from the Black Sea. Mercury concentration in fish muscle was six times higher in the two Mediterranean species than in the Black Sea one for similar sized animals. A positive correlation between Hg concentration and δ¹⁵N occurred in all species. Increase in Hg concentration with δ¹⁵N was high and similar in the two Mediterranean fishes and much lower in the Black Sea species. Since this was neither related to trophic level difference between species nor to methylmercury (MeHg) concentration differences between the north-western Mediterranean and the Black Sea waters, we suggested that the higher primary production of the Black Sea induced a dilution of MeHg concentration at the base of the food webs.     

Monsoonal precipitation variation in the East Asia since A.D. 1840

Three tree-ring rainfall reconstructions from China and Korea are used in this paper to investigate the East Asian summer monsoon-related precipitation variation over the past 160 years. Statistically, there is no linear correlation on a year-by-year basis between Chinese and Korean monsoon rainfall, but region-wide synchronous variation on a decadal-scale was observed. More rainfall intervals were 1860–1890, 1910–1925, and 1940–1960, and dry or even drought periods were 1890–1910, 1925–1940, and 1960–present. Reconstructions also display that the East Asian summer monsoon precipitation suddenly changed from more into less around mid-1920. These tree-ring precipitation records were also confirmed by Chinese historical dryness/wetness index and Korean historical rain gauge data.     

Basic characteristics of active tectonics of China

Active tectonics is inferred to all the structures which have been active since the late Pleisto-cene, 100—120 ka B.P., are still active recently, and will be active in a certain time period in the future, such as active faults, active folds, active basi…     

Differences of granitic weathering at the northern and southern feet of Dabie Mountains,Central China: Implication for tectonic and climatic environments

Previous studies of weathering generally started with geochemistry[1—8] and mineralogy[9—12], and have been focused on chemical weathering rates[1—3], removability-enrichment of elements[3—6] during chemical weathering, and the age of weathering profi…     

Thermal bidirectional gap probability model for row crop canopies and validation

Land surface temperature is a key parameter in monitoring the status of crop water stress by remote sensing, and studying the water and energy balance in cropland ecosystem. The component temperatures of crop and soil are especially significant in remote …