Using distributed temperature sensing (DTS) technology in acid gas injection design

The use of slickline distributed temperature sensing (SL-DTS) technology is becoming widespread due to its ease of operation and ability to acquire real-time multiple temperature traces inside the wellbore. Injection of treated acid gas (TAG)—a mixture of CO₂ and H₂S—into geologic formations has become an attractive technical and economic option for oil and gas producers and processors who are faced with regulations concerning excess sulfur and greenhouse gas emissions. Acid gas injection (AGI) into geologic formations is more economical and more flexible in dealing with varying TAG compositions than sulfur recovery units (SRUs) using the Claus process. SRUs do not achieve air quality standards and have high operation and maintenance costs. In addition, there is low demand for sulfur and sulfur disposal costs are high. The results of the analysis of SL-DTS data acquired in conjunction with step rate and pressure falloff (PFO) tests are presented in this paper. These tests were conducted to evaluate the injection potential of geologic formations. The injection zone consisted of a carbonate formation characterized by Karst features, vugs, and natural fractures. The SL-DTS data during the initial injection flow rate for the step rate test (SRT) indicated that high permeability zones accepted fluid at lower injection rates. An increasing number of discrete zones began to accept fluid as the injection rate was increased. The results of the SRT provided the fracture pressure of the formation. This information was used to design an AGI program that would avoid fracturing the formation while allowing for the required volume of TAG to be injected. The results of the PFO test provided information on the reservoir pressure and permeability and also indicated the presence of one or more hydraulic fractures. This case study of SL-DTS measurements made during a SRT and a PFO test for the design of an AGI well provides valuable insights into the potential of DTS technology and its use in AGI and carbon capture/sequestration (CCS) operations. Its findings could be applied to analyze injection potential of geological formations not only for AGI projects but also for CCS, and CO₂ enhanced oil recovery opportunities.     

An effective stress-based DSC model for predicting the coefficient of lateral soil pressure in unsaturated soils

Acta Geotechnica - In this study, an analytical model is developed to establish a framework for predicting the coefficient of lateral soil pressure in unsaturated soils. To this end, the disturbed...     

Collapse behavior of a brick masonry house using a shaking table and numerical simulation based on the extended distinct element method

Damage caused by devastating earthquakes has occurred in many developing countries. In order to mitigate such damage by promoting the study of adequate seismic design strategies, the authors conducted a dynamic collapse test on 3 m × 3 m × 3 m brick masonry house constructed with Pakistani bricks, using a one-direction horizontal large-scale shaking table. In order to analyze and simulate seismic performance of the masonry structures, the authors applied a new numerical simulating method based on the Extended Distinct Element Method (EDEM) and conducted collapse simulations of the brick masonry house behavior during the shaking table tests. In the numerical simulation model, bricks were assumed to be rigid bodies, and mortar was modeled using a mortar spring that consists of a normal spring and a shear spring. The parameters of each mortar spring were defined based on the results of material tests. Simulated results showed various collapsing processes, and the simulated aspects were found to be similar to the results of the shaking table tests.     

Effective impervious area for runoff in urban watersheds

Effective impervious area (EIA), or the portion of total impervious area (TIA) that is hydraulically connected to the storm sewer system, is an important parameter in determining actual urban runoff. EIA has implications in watershed hydrology, water quality, environment, and ecosystem services. The overall goal of this study is to evaluate the application of successive weighted least square (WLS) method to urban catchments with different sizes and various hydrologic conditions to determine EIA fraction. Other objectives are to develop insights on the data selection issues, EIA fraction, EIA/TIA ratio, and runoff source area patterns in urban catchments. The successive WLS method is applied to 50 urban catchments with different sizes from less than 1 ha to more than 2000 ha in Minnesota, Wisconsin, Texas, USA as well as Europe, Canada, and Australia. The average, median, and standard deviation of EIA fractions for the 42 catchments with residential land uses are found to be 0.222, 0.200, and 0.113, respectively. These values for the EIA/TIA ratio in the same 42 catchments are 0.50, 0.48, and 0.21, respectively. While the EIA/TIA results indicate the importance of EIA, 95% prediction interval of the mean EIA/TIA is found to be 0.07 to 0.93, which shows that using an average value for this ratio in each land use to determine EIA from TIA in ungauged urban watersheds can be misleading. The successive WLS method was robust and is recommended for determining EIA in gauged urban catchments. Copyright © 2016 John Wiley & Sons, Ltd.     

Modeling Seismic Attributes of Pn Waves using the Spectral-Element Method

To investigate the nature of Pn propagation, we have implemented the spectral-element method (SEM) for vertically and laterally varying media with and without attenuation. As a practical measure, essential features of the Pn waves are distilled into seismic attributes including arrival times, amplitudes and pulse frequencies. To validate the SEM simulations, we first compare the SEM results with reflectivity calculations of Braile and Smith (Geophys. J.R. Astr. Soc. 40, 145–176, 1975) and then to the asymptotic results of ?erveny and Ravindra (Theory of Seismic Headwaves, University of Toronto Press, pp. 235–250, 1971). Models with random, laterally varying Moho structures are then simulated, where the amplitude and pulse frequency characteristics are found to be stable to small Moho interface perturbations. SEM calculations for models with different upper-mantle velocity gradients are next performed where it is found that interference effects can strongly influence the Pn amplitudes and pulses frequencies. For larger-scale, laterally varying structures, SEM models similar to that found along the Hi-CLIMB array in Tibet are then performed. It is observed that large-scale structures, along with small-scale structures, upper-mantle velocity gradients and attenuation, can all significantly affect the Pn attributes. Ambiguities between upper-mantle velocity gradients and attenuation are also found when using Pn amplitudes and pulse frequency attributes. These ambiguities may be resolved, to some degree, by using the curvature of the travel times at longer regional distance, however, this would also be complicated by lateral variability.     

Speciation and Determination of Inorganic Mercury and Methylmercury by Headspace Single Drop Microextraction and Electrothermal Atomic Absorption Spectrometry in Water and Fish

In this study, headspace single drop microextraction (HS‐SDME) method in combination with electrothermal atomic absorption spectrometry (ETAAS) method was developed and validated for the speciation and determination of inorganic mercury (iHg) and methylmercury (MeHg). MeHg and iHg species were reduced to volatile methylmercury hydride (CH₃HgH) and elemental mercury, respectively, in the presence of NaBH₄ and trapped onto a drop of acceptor phase in the tip of a microsyringe. Thiourea and ammonium pyrrolydinedithiocarbamate (APDC) were tested as the acceptor phase. The experimental parameters of the method such as microextraction time, temperature, NaBH₄ concentration, acceptor phase concentration, and pH of the medium were investigated to obtain distinctive conditions for mercury species. Possible interference effects have also been investigated. In order to validation of the method, analytical figures of merits such as accuracy, precision, limit of detection (LOD), limit of quantitation (LOQ), and linear working range have been evaluated. Accuracy of the method has been verified by analyzing certified reference materials (BCR 453 Tuna fish) and spiked samples. The proposed method was applied for the speciation and determination of mercury species in water and fish samples. Mercury species (MeHg and iHg) have been determined in the real samples with a relative error less than 10%.     

Spatial distribution and temporal variation of reference evapotranspiration in arid and semi‐arid regions of Iran

Analysis of spatial and temporal variations of reference evapotranspiration (ET_o) is important in arid and semi‐arid regions where water resources are limited. The main aim of this study was to analyse the spatial distribution and the annual, seasonal and monthly trends of the Penman–Monteith ET_o for 21 stations in the arid and semi‐arid regions of Iran. Three statistical tests the Mann‐Kendall, Sen's slope estimator and linear regression were used for the analysis. The analysis revealed that ET_o increased from January to July and deceased from July to December at almost all stations. Additionally, higher annual ET_o values were found in the southeast of the study region and lower values in the northwest of the region. Although the results showed both positive and negative trends in annual ET_o series, ET_o generally increased, significantly so in six (～30%) of the stations. Analysis of the impacts of meteorological variables on the temporal trends of ET_o indicated that the increasing trend of ET_o was most likely due to a significant increase in minimum air temperature, while decreasing trend of ET_o was mainly caused by a significant decrease in wind speed. At the sites where increasing ET_o trends were statistically significant, the rate of increase varied from (+)8·36 mm/year at Mashhad station to (+)31·68 mm/year at Iranshahr station. On average, an increasing trend of (+)4·42 mm/year was obtained for the whole study area during the last four decades. Seasonal and monthly ET_o have also tended to increase at the majority of the stations. The greatest numbers of significant trends were observed in winter on the seasonal time‐scale and in September on the monthly time‐scale. Copyright © 2011 John Wiley & Sons, Ltd.     

Review of water and soil contamination in and around Salihli geothermal field (Manisa,Turkey)

The town of Salihli is situated in Gediz Graben in the western Anatolia. This region is important in terms of industry, mining, geothermal energy, water sources, and agricultural production. Geothermal flow and anthropogenic activities in Salihli threaten the surrounding environment due to the contamination of cold groundwater, surface water, and soil. The goal of the present study is to determine the environmental effects of the geothermal and anthropogenic activities in Salihli on soil, stream sediments, and water. Stream sediments and farm soil have been contaminated by substances derived from geothermal and industrial effluents. To this end, the quality review of the water was completed and the heavy metal levels in stream sediment samples were measured to determine the extent of contamination. The elements As, B, Br, Fe, and Ni are the major contaminants present in surface water and groundwater in the study area. The concentrations of these elements excess tolerance limits of international water standards. Gibbsite, K-mica, kaolinite, sepiolite, halite, sulfur, willemite, and Pb(OH)₂ might be precipitated as scales at low temperatures on the soil; this could be interpreted as a resultant from soil contamination. The concentrations of 17 elements (As, Ba, B, Cd, Co, Cr, Cu, Fe, Hg, Li, Mo, Mn, Ni, Pb, Sb, Sr, and Zn) were measured in samples from stream sediments and surface soils. In the study area, especially geothermal and anthropogenic activities give rise to environmental pollution.