Geochemistry and Sr–Nd–Pb isotopic composition of the Harrat Al-Madinah Volcanic Field,Saudi Arabia

Whole-rock geochemical and Sr, Nd and Pb isotope data are presented for the Harrat Al-Madinah volcanic field, in the north western part of the Arabian plate, aiming to understand their origin and the composition of their mantle source. This area is an active volcanic field characterized by the occurrence of two historic eruptions approximately in 641 and 1256 A.D. Field investigation of the main volcanic landforms indicates dominantly monogenetic strombolian eruptions, in addition to local phreatomagmatic eruption style. The lavas consist mainly of alkali olivine basalt, olivine transitional basalt, and hawaiite with ocean island basalt (OIB)-like characteristics. Evolved rocks, represented by mugearites, benmoreites, and trachytes, occur mainly as domes, tuff cones and occasionally as lava flows. Chemical variations in the evolved rocks indicated their evolution by low pressure crystal fractionation of olivine, plagioclase, clinopyroxene, and Fe–Ti oxides from the relatively primitive basalts. The isotopic compositions of ¹⁴³Nd/¹⁴⁴Nd (0.512954–0.512995), ⁸⁷Sr/⁸⁶Sr (0.702899 to–0.702977) and Pb (²⁰⁶Pb/²⁰⁴Pb = 18.5515–18.7446, ²⁰⁷Pb/²⁰⁴Pb = 15.5120–15.5222, ²⁰⁸Pb/²⁰⁴Pb = 38.1347–38.4468), show restricted variations suggesting only minor crustal contamination. They defined an array consistent with mixing of two geochemically distinct components of depleted MORB-mantle (DMM) and high ²³⁸U/²⁰⁴Pb ratio (HIMU). The variations in Tb/Yb, La/Yb and Sm/Yb ratios in the relatively primitive basalts (MgO > 6 wt.%) indicated garnet peridotite source. However, the positive Nb, Sr, Ba and Ti anomalies in the primitive mantle-normalized incompatible element patterns and the significant variation between Zr/Nb vs. Ce/Y and La/Yb vs. Yb suggest contribution of an amphibole-bearing spinel lherzolite source. Moreover, the negative correlations between SiO₂ vs. ⁸⁷Sr/⁸⁶Sr and Th vs. ¹⁴³Nd/¹⁴⁴Nd are interpreted as an indication of mixing melts derived from two end-members; one is garnet bearing asthenospheric source with OIB characteristic and the other is amphibole-bearing spinel lherzolite. The Harrat Al-Madinah volcanic field occurs near the Red Sea Rift System and its origin reflects a strong lithospheric control on the loci of partial melting. The dominantly NNW alignment patterns of the volcanoes, which is similar to the regional Red Sea trend, may suggest that the magmas were produced by decompression partial melting triggered by lithospheric extension related to the Red Rift.     

Adsorption of BTEX on Surfactant Modified Granulated Natural Zeolite Nanoparticles: Parameters Optimizing by Applying Taguchi Experimental Design Method

In this paper, a novel adsorbent developed by means of granulating of natural zeolite nanoparticles (i.e., clinoptilolite) was evaluated for possible removal of the petroleum monoaromatics (i.e., benzene, toluene, ethylbenzene, and xylene, BTEX). To do this, the natural zeolite was ground to produce nanosized particulate, then modified by two cationic surfactants and granulated. The effect of various parameters including temperature, initial pH of the solution, total dissolved solids (TDS), and concentration of a competitive substance (i.e., methyl tert‐butyl ether, MTBE) were studied and optimized using a Taguchi statistical approach. The results ascertained that initial pH of the solution was the most effective parameter. However, the low pH (acidic) was favorable for BTEX adsorption onto the developed adsorbents. In this study, the experimental parameters were optimized and the best adsorption condition by determination of effective factors was chosen. Based on the S/N ratio, the optimized conditions for BTEX removal were temperature of 40°C, initial pH of 3, TDS of 0 mg/L, and MTBE concentration of 100 µg/L. At the optimized conditions, the uptake of each BTEX compounds reached to more than 1.5 mg/g of adsorbents.     

Simulating precipitation in the Northeast United States using a climate-informed K-nearest neighbour algorithm

Decadal prediction using climate models faces long-standing challenges. While global climate models may reproduce long-term shifts in climate due to external forcing, in the near term, they often fail to accurately simulate interannual climate variability, as well as seasonal variability, wet and dry spells, and persistence, which are essential for water resources management. We developed a new climate-informed K-nearest neighbour (K-NN)-based stochastic modelling approach to capture the long-term trend and variability while replicating intra-annual statistics. The climate-informed K-NN stochastic model utilizes historical data along with climate state information to provide improved simulations of weather for near-term regional projections. Daily precipitation and temperature simulations are based on analogue weather days that belong to years similar to the current year's climate state. The climate-informed K-NN stochastic model is tested using 53 weather stations in the Northeast United States with an evident monotonic trend in annual precipitation. The model is also compared to the original K-NN weather generator and ISIMIP-2b GFDL general circulation model bias-corrected output in a cross-validation mode. Results indicate that the climate-informed K-NN model provides improved simulations for dry and wet regimes, and better uncertainty bounds for annual average precipitation. The model also replicates the within-year rainfall statistics. For the 1961–1970 dry regime, the model captures annual average precipitation and the intra-annual coefficient of variation. For the 2005–2014 wet regime, the model replicates the monotonic trend and daily persistence in precipitation. These improved modelled precipitation time series can be used for accurately simulating near-term streamflow, which in turn can be used for short-term water resources planning and management.     

Plant functional types in Lake Nubia in relation to physicogeographic factors

The shoreline vegetation of Lake Nubia in Sudan was studied by means of morphological characteristics and functional traits of plants established-phase as published in literature reviews. The 57 species recorded in 83 sampling sites were classified according to 15 morphological traits into six Plant Functional Types (PFTs), using Two Way Indicator Species Analysis (TWINSPAN). Principal component analysis (PCA) was used to evaluate the homogeneity of these groups in terms of their traits. The resulting PFTs were related to the physicogeographical variables measured (soil texture, soil moisture, soil thickness and elevation) using canonical correspondence analysis (CCA). The ratios in occurrences of the functional types were calculated per each moisture segment, and can be used as an indicator of the shoreline dynamics.     

Improvement of a location-aware recommender system using volunteered geographic information

Abstract

Recommender systems (RS), as supportive tools, filter information from a massive amount of data based on the determined preferences. Most of the RS require information about the context of users such as their locations. In such cases, location-aware recommender systems (LARS) can be employed to suggest more personalized items to the users. The most current research projects on LARS focus on the development of algorithms, evaluation methods and applications. However, the role of up-to-date spatial databases in LARS is not a well-researched area. The up-to-date spatial information would potentially improve the accuracy of items which are recommended by LARS. Volunteered geographic information (VGI) could be a low-cost source of up-to-date spatial information for LARS. This article proposes an approach to enrich spatial databases of LARS by VGI. Since not all records of VGI are fitted for use in LARS, a mechanism is developed to identify useful information. Some VGI data sets refer to existing spatial data in the database while other VGI data sets are shared for the first time. Therefore, the proposed method assessed the quality of VGI with reference source (for VGI which is existed in the database) and VGI without reference source (for VGI which is shared for the first time). To demonstrate the feasibility of the proposed approach, a mobile application has been developed to recommend suitable restaurants to the users based on their geospatial locations. The evaluation of the method indicates that VGI can potentially enhance the functionality of the LARS in predicting the users’ interests.     

模糊证据权方法在镇沅(老王寨)地区金矿资源评价中的应用

采用模糊证据权方法和GeoDASGIS技术开展了镇沅(老王寨)及其邻区的金矿资源潜力评价.分别采用GeoDASGIS软件提供的局部奇异性分析技术、S-A异常分解技术、主成分分析技术、证据权、模糊证据权等技术对相关地球化学元素进行了系统的处理和分析.应用主成分分析方法确定了可能的2种不同成矿类型,并采用主成分得分确定了组合异常点,在此基础上分别采用普通证据权和模糊证据权方法编制了成矿后验概率图,圈定了有利成矿地段.对比普通证据权方法与模糊证据权方法所得结果表明,模糊证据权方法可减小图层离散化造成的有用信息损失,提高预测结果精度.     

Late Cenozoic surface uplift,basaltic volcanism,and incision by the River Tigris around Diyarbakır,SE Turkey

We document the staircase of terraces of the River Tigris in the Diyarbakır area of SE Turkey, in the northern Arabian Platform, and improve control on the ages of these terrace deposits by dating of overlying basalt flows using the unspiked K–Ar technique. These fluvial terraces are formed of polymict gravel, including clasts derived from the Anatolian metamorphic terrane farther north as well as of local basalt. At least 9 Tigris terraces have been recognised so far, the highest of which, ∼200 m above present river level, marks the local transition from stacked deposition to fluvial incision, the timing of which is bounded between the mid Late Miocene and the Middle Pliocene. Our K–Ar dating indicates a hiatus in fluvial incision in the late Early Pleistocene, as basalts dated to 1.22 ± 0.02 and 1.07 ± 0.03 Ma overlie Tigris gravels at very similar levels, ∼60–70 m above the present river. The lower terraces record the subsequent entrenchment of the modern Tigris valley following an increase in incision rates in the early Middle Pleistocene, evident from the disposition of younger basalt, dated to 0.43 ± 0.02 Ma, capping fluvial gravel only ∼21–22 m above the present river level. Numerical modelling can account for the observed uplift history, as the response to coupling between surface processes and induced flow in the lower crust, with the mobile lower-crust thin (∼5–7 km thick), consistent with the known presence of a thick layer of mafic underplating at the base of the crust beneath the Arabian Platform. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Intermittent Behaviour in Axisymmetric Mean-Field Dynamo Models in Spherical Shells

Axisymmetric mean-field dynamo models in spherical shells are shown to be capable of producing temporally intermittent behaviour. This is of potential importance since (i) it is, as far as we are aware, the first time such behaviour has been produced internally by a mean-field dynamo model in a spherical shell, without requiring any additional assumptions or truncations, and (ii) it may be characteristic of the type of behaviour observed in the long-term record of solar activity, such as Maunder minima. We also show that these types of behaviour persist when the functional form of the alpha quenching is altered and also occur over intervals of the shell thickness and the dynamo number.     

Temperature and precipitation trend analysis of the Iraq Region under SRES scenarios during the twenty-first century

Theoretical and Applied Climatology - Iraq is classified as the fifth most vulnerable country in the world to decreased water and food availability, extreme temperatures, and associated health...