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Palynological and geochemical analyses provide valuable information about modern and past climatic regimes and vegetation. The impact of climate and humans on past vegetation in the semi-arid areas of northwestern Iran has received increased interest in the wake of warming temperatures in the Middle East. Palynological and down-core XRF elemental abundances from a peat core from Lake Neor enabled a reconstruction of vegetational changes of the past 7000 years over the highlands of northwestern Iran. Periods of increased arboreal pollen (AP) types and high (Artemisia + Poaceae)/Chenopodiaceae ratios along with low titanium abundances, high percentages of total organic carbon, more negative δD values, and higher carbon accumulation rates suggest a relatively wet climate. These conditions have persisted during the periods 6700–6200, 5200–4450 and 3200–2200 cal a bp. The overall low AP values, substantial rise of Chenopodiaceae, high Ti abundances and low values of palaeo-redox proxies, are all evidences of a drier climate, as has been reconstructed for the periods 6200–5200 and 4030–3150 cal a bp and the last 2200 years. An important feature of the last centuries is the increase of anthropogenic and pastoral indicator pollen types. Our results may provide basic data to predict future trends in vegetation dynamics under future climate change in western Asia.  相似文献   
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Groundwater arsenic (As) presents a public health risk of great magnitude in densely populated Asian delta regions, most acutely in the Bengal Basin (West Bengal, India and Bangladesh). Research has focused on the sources, mobilisation, and heterogeneity of groundwater As, but a consistent explanation of As distribution from local to basin scale remains elusive. We show for the Bengal Aquifer System that the numerous, discontinuous silt‐clay layers together with surface topography impose a hierarchical pattern of groundwater flow, which constrains As penetration into the aquifer and controls its redistribution towards discharge zones, where it is re‐sequestered to solid phases. This is particularly so for the discrete periods of As release to groundwater in the shallow subsurface associated with sea level high‐stand conditions of Quaternary inter‐glacial periods. We propose a hypothesis concerning groundwater flow ( S ilt‐clay layers I mpose H ierarchical groundwater flow patterns constraining A rsenic progression [SIHA]), which links consensus views on the As source and history of sedimentation in the basin to the variety of spatial and depth distributions of groundwater As reported in the literature. SIHA reconciles apparent inconsistencies between independent, in some cases contrasting, field observations. We infer that lithological and topographic controls on groundwater flow, inherent to SIHA, apply more generally to deltaic aquifers elsewhere. The analysis suggests that groundwater As may persist in the aquifers of Asian deltas over thousands of years, but in certain regions, particularly at deeper levels, As will not exceed low background concentrations unless groundwater flow systems are short‐circuited by excessive pumping.  相似文献   
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We compared the interannual variability of annual daily maximum and minimum extreme water levels in Lake Ontario and the St Lawrence River (Sorel station) from 1918 to 2010, using several statistical tests. The interannual variability of annual daily maximum extreme water levels in Lake Ontario is characterized by a positive long‐term trend showing two shifts in mean (1929–1930 and 1942–1943) and a single shift in variance (in 1958–1959). In contrast, for the St Lawrence River, this interannual variability is characterized by a negative long‐term trend with a single shift in mean, which occurred in 1955–1956. As for annual daily minimum extreme water levels, their interannual variability shows no significant long‐term change in trend. However, for Lake Ontario, the interannual variability of these water levels shows two shifts in mean, which are synchronous with those for maximum water levels, and a single shift in variance, which occurred in 1965–1966. These changes in trend and stationarity (mean and variance) are thought to be due to factors both climatic (the Great Drought of the 1930s) and human (digging of the Seaway and construction of several dams and locks during the 1950s). Despite this change in means and variance, the four series are clearly described by the generalized extreme value distribution. Finally, annual daily maximum and minimum extreme water levels in the St Lawrence and Lake Ontario are negatively correlated with Atlantic multidecadal oscillation over the period from 1918 to 2010. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
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We measured the concentrations of dissolved inorganic carbon (DIC) and major ions and the stable carbon isotope ratios of DIC (δ13CDIC) in two creeks discharging from carbonate‐rich sulphide‐containing mine tailings piles. Our aim was to assess downstream carbon evolution of the tailings discharge as it interacted with the atmosphere. The discharge had pH of 6.5–8.1 and was saturated with respect to carbonates. Over the reach of one creek, the DIC concentrations decreased by 1.1 mmol C/l and δ13CDIC increased by ~4.0‰ 200 m from the seep source. The decrease in the DIC concentrations was concomitant with decreases in the partial pressure of CO2(aq) because of the loss of excess CO2(aq) from the discharge. The corresponding enrichment in the δ13CDIC is because of kinetic isotope fractionation accompanying the loss of CO2(g). Over the reach of the other creek, there was no significant decrease in the DIC concentrations or notable changes in the δ13CDIC. The insignificant change in the DIC concentrations and the δ13CDIC is because the first water sample was collected 160 m away from the discharge seep, not accessible during this research. In this case, most of the excess CO2(aq) was lost before our first sampling station. Our results indicate that neutral discharges from tailings piles quickly lose excess CO2(aq) to the atmosphere and the DIC becomes enrich in 13C. We suggest that a significant amount of carbon cycling in neutral discharges from tailings piles occur close to the locations where the discharge seeps to the surface. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
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