The Serra Pelada Au-PGE deposit, Serra dos Carajás (Pará State, Brazil): geological and geochemical indications for a composite mineralising process

The Serra Pelada Au-PGE-rich deposit is located in the Serra dos Carajás, a leading mining area in Brazil. This region is characterised by a complex geological and structural framework and is affected by deep lateritisation which has lasted for more than 70 Ma. The Serra Pelada deposit is emplaced in a late-Archean low-grade metasedimentary sequence (Rio Fresco/Águas Claras Formation) which is host to other gold deposits in the region (Igarapé Bahia, Águas Claras). The Rio Fresco/Águas Claras sequence was deposited in tectonic basins developed on Archean basement and Au-bearing greenstone terranes which were intruded by PGE-rich layered mafic complexes (e.g. Luanga). The Serra Pelada mineralisation is located along a regional, complex system of strike-slip faults (Cinzento-Carajás systems) which were active during the late Archean to early Proterozoic. The mineralisation appears to be concentrated along a faulted hinge zone of a fold. Ore zone rock facies are dominated by low-grade ferruginous to carbonaceous metasiltstones and minor sandstones, locally brecciated and cemented by quartz (-sulphide) stockwork. Supergene alteration led to partial to total transformation into friable aggregates of kaolinite, Fe oxide-hydroxides, silica and secondary phosphate-sulphates even at depths exceeding 200 m. Precious metals are exceptionally enriched, with up to more than 1,000 ppm Au+PGE in some peculiar ferruginous-graphitic zones locally called "hidrotermalito". Geochemistry shows complex patterns of major and trace elements, particularly rare-earth elements (REE), in mineralised vs. nonmineralised samples. These patterns are interpreted in terms of variable degree of superposition of hydrothermal and supergene alteration. Precious metals show progressive increase from samples with hydrothermal imprint to samples with supergene imprint. The geological evolution of the Carajás region and the characteristics of mineralisation at Serra Pelada may suggest a composite mineralising process: hydrothermal activity (by fluids likely originated from granitoids) was followed by supergene alteration during long-lasting lateritisation to develop extreme precious metal enrichments in a geological context probably already anomalous for Au and PGE.     

A comparison of approximate techniques for non-linear seismic soil response

Some equivalent linearization techniques, applicable to problems dealing with non-linear seismic amplification of layered soils, are systematically treated and critically compared in this paper. The discussion concerns, in particular, the theoretical consistency, the operative modalities, the computational complexity and the numerical reliability of these methods. A comparison is made between the results furnished by some techniques among those examined and the results obtained through a step-by-step integration of the non-linear equations of motion, assuming as a test-problem the one-dimensional amplification of a horizontally stratified soil deposit characterized by the Ramberg-Osgood constitutive model.     

Carbon isotopes and geochemical processes in CO2-rich cold mineral water,N-Portugal

This paper summarizes a new outlook on the conceptual model of Melgaço–Messegães CO₂-rich cold (≈18 °C) mineral water systems, issuing in N of Portugal, based on their isotopic (²H, ³H, ¹³C, ¹⁴C and ¹⁸O) and geochemical features. Stable isotopes indicate the meteoric origin of these CO₂-rich mineral waters. Based on the isotopic fractionation with the altitude, a recharge altitude between 513 up to 740 m a.s.l. was estimated, corroborating the tritium results. The lowest ³H content (0 TU) is found in the groundwater samples with the highest mineralization. The mineral waters circulation are mainly related to a granitic and granodioritic environment inducing two different groundwater types (Ca/Na–HCO₃ and Na/Ca–HCO₃), indicating different underground flow paths. Calcium dissolution is controlled by hydrolysis of rock-matrix silicate minerals (e.g. Ca-plagioclases) and not associated to anthropogenic sources. The shallow dilute groundwaters exhibit signatures of anthropogenic origins (e.g. NO₃) and higher Na/Ca ratios. The stable isotopes together with the geochemistry provided no indication of mixing between the regional shallow cold dilute groundwater and mineral water systems. The heavy isotopic signatures identified in the δ¹³C data (δ¹³C = 4.7 ‰, performed on the total dissolved inorganic carbon (TDIC) of CO₂-rich mineral waters) could be derived from a deep-seated (upper mantle) source or associated to methanogenesis (CH₄ source). The negligible ¹⁴C content (≈2 pmC) determined in the TDIC of the mineral waters, corroborates the hypothesis of a mantle-derived carbon source to the mineral groundwater systems or dissolution of carbonate layers at depth.     

The role of the lowermost boundary conditions in the hydrological response of shallow sloping covers

In many areas of the world, slopes covered by shallow unsaturated non-plastic soil layers experience rainfall-induced landslides causing heavy damage and casualties every year. Landslide occurrence depends on the amount of water infiltrated and stored. Among the contributing factors are the hydraulic conditions at the lowermost boundary, a feature that is often disregarded. The paper focuses on this topic, presenting the results of some laboratory and numerical experiments on ash-pumice interfaces. A strategy is then proposed for selecting the lowermost boundary condition, and some studies are carried out to compare the results obtained with the proposed solution and other more popular ones.     

Cooling and exhumation history of deep‐seated and shallow level,late Hercynian granitoids from Calabria

The thermal and exhumation history of late Hercynian granitoids from Calabria (Sila and Serre massifs) has been studied using thermobarometry and radiometric age determinations. The uplift and erosion which followed contractional tectonics of Tertiary age exposed in Calabria a nearly complete section of the Hercynian crust. Field data, constrained by igneous thermobarometrical data, have enabled us to draw simplified crustal profiles. In both the Sila and Serre massifs, granitoids make up the intermediate portions of the crustal sections and are stacked as tabular intrusions for up to 13 km cumulative thickness. Shallow granitoids are characterized by a weak fabric, mostly developed in the magmatic stage, whereas deep‐seated granitoids display a strong fabric developed in the magmatic state and, with decreasing temperatures, in the subsolidus state. The intrusive bodies were emplaced at 300–290 Ma, at a time when the Calabrian crust was undergoing extensional tectonics and crustal thinning. The subsequent post‐Hercynian evolution is recorded by Rb‐Sr dates of micas and fission track ages of zircon and apatite obtained from granitoids emplaced at different depths. A decrease in Rb‐Sr and fission track ages is observed as depth of emplacement increases. Data on the post‐Hercynian geological evolution of Calabria were used to model in three stages the cooling and exhumation history of deep‐seated and shallow granitoids. The first stage, in Permian to Triassic times, was characterized by slow erosion. It was followed by a second stage of extensional tectonics in Jurassic times. The third stage was exhumation during the Apenninic Orogeny. The model has generated two P–T–t arrays, one for deep‐seated and the other for shallow granitoids of the Serre massif. The T–t paths suggest that the dates of micas, zircon and apatite are cooling ages. They also show that deep‐seated granitoids remained at temperatures above the brittle–plastic transition for a long time, whereas shallow granitoids cooled rapidly. Distinct P–T–t paths explain why deep‐seated and shallow granitoids display different fabric and microstructural features. Copyright © 2000 John Wiley & Sons, Ltd.