Formation of Thetis Deep metal-rich sediments in the absence of brines,Red Sea

Almost all Red Sea deeps contain metal-rich sediments covered by brine pools. It is generally agreed that these metal-rich deposits precipitated from overlying metal-rich brines that originated from migrating hydrothermal fluids. No brine pool has ever been reported in Thetis Deep, inciting us to evaluate if such a brine layer ever occurred in the deep during the past. In order to address that questioning, a study combining mineralogical, geochemical (major-, minor-, rare-earth elements) and isotopic (Sr, Nd, Pb) approaches was completed on cored sediments and extracted interstitial waters from inside and outside the deep.The sediments have an overall hydrothermal origin, as shown by the REE concentrations and patterns, metal contents, and Pb–Nd isotopic data, all pointing to a mantle signature. The intensity of the hydrothermal activity varied with time in the deep; the most intense episode resulting in an almost pure Fe-oxi-hydroxide layer. Varied chemical arguments, especially the Zr and REE data of the sediments, favor the fact that the whole sedimentation in Thetis Deep occurred in the absence of a stable, salt-rich and mineralized brine pool, and that no brine layer ever existed. This conclusion is supported by the constant Sr isotope composition of the sediment and its interstitial waters that are almost identical to that of the Red Sea seawater. The study also suggests that hydrothermal activity monitored fluid supplies that interacted differently with seawater in the different Red Sea deeps, resulting in an overall formation of metal-rich sediments, but along varied local conditions.     

A case study of land cover change (1950-2003) and runoff in a Mediterranean catchment

Mediterranean environments have been subject to major land cover change since the end of the second world war. Housing, agricultural activities, forests, green spaces and other land uses have shifted due to urbanisation and tourism. These changes influence runoff, and municipal authorities often cannot estimate the net impact of complex land cover transitions. During this period, elected representatives have become increasingly sensitive to the risks of flooding and have implemented a number of channel management strategies. The main objective of this case study was to analyse the impact of land cover change on total storm runoff between 1950 and 2003 in a Mediterranean catchment near St Tropez, France. A secondary objective was to compare these changes to the impacts of channel management on bankfull discharge. Aerial photographs were used to classify land cover in 3 urban categories, vineyards and bare soil, forests, and green spaces. Stream discharge was estimated using a distributed event based total runoff approach. After validating the model for a large winter event (114 mm) for 1982, runoff was calculated for the same event for 1950 and 2003. Land cover changes occurred mainly in the alluvial plain area. Total gauge catchment urban area increased from 30.1 ha to 393.8 between 1950 and 2003 at the expense mainly of agricultural land, but this was compensated in part by an increase in grassed area. Some of the loss in vineyards was replaced by clearing forested land on the first hills close to the plain. Bank stabilisation and channel maintenance since the 1980’s reduced surface roughness and increased channel area, thereby greatly increasing bankfull discharge. While the impact of urbanisation on runoff was small, channel management effects increased bankfull discharge substantially. Flood damage from extreme events was not studied here.     

New methods and selection methods

As the topics of study of Lyα emitters evolve, new selection methods are being developed to find these high redshift galaxies. In this proceedings, three new methods are presented, based on large integral field unit spectrographs, ultradeep slit spectroscopy and serendipitous discoveries.     

HF radar observations of equatorial spread-F over West Africa

New experimental data depicting equatorial spread-F were taken during an HF radar sounding campaign in Korhogo (Ivory Coast, 9°24N, 5°37W, dip 4°S). Range-time-intensity maps of the radar echoes have been analyzed to identify the signatures of density depletions and bottomside spread-F. Density depletions are well known features of equatorial spread-F, and are believed to emerge after the development of a Rayleigh-Taylor instability on the bottomside F-layer. A simple model is developed and used to simulate the flow of density depletions over the radar field of view. The simulation permits an interpretation of the data that yields the zonal flow velocity as a function of local time. Comparisons with previous measurements are undertaken to assess the consistency of the computational results, and qualitative arguments are presented to identify bottomside spread-F. Using the computational results as reference, a morphological study of ionograms showing spread-F is undertaken which reveals the specific signature of bottomside spread-F on ionograms recorded just after sunset.     

Parameters of “Macromaturity” (PMM): novel rank and type related indices from chemical degradation of macromolecular network of coals

Benzene polycarboxylic acids formed upon oxidative degradation of the macromolecular network of a set of French coals with ruthenium tetroxide are proposed as the basis of new coal rank indices. Their distribution probably reflects the degree of condensation of the polyaromatic subunits occurring in the network of the coals. This feature is illustrated in the case of the benzene tetracarboxylic acids. Application of these molecular indices to Gondwana coals, as well as to maceral concentrates indicates that they are also type related. They could prove particularly useful in the case of coals or kerogens having undergone secondary alteration processes.     

Typical influences of moisture on profile measurements in the marine atmospheric surface layer

Under a wide variety of meteorological conditions in a coastal environment, 250 cases were studied to determine the typical influences of moisture in calculating the gradient Richardson number stability and the fluxes of heat, humidity, and momentum with the profile method. Although the stability calculation was altered in some cases up to 95% by the moisture correction, the typical influence in computing the fluxes was found to be less than 10% when the humidity flux was upward and less then 25% when the humidity flux was downward.     

The impact of climate change on cropland productivity: evidence from satellite based products at the river basin scale in Africa

We investigate the effect of climate change on crop productivity in Africa using satellite derived data on land use and net primary productivity (NPP) at a small river basin scale, distinguishing between the impact of local and upper-catchment weather. Regression results show that both of these are determining factors of local cropland productivity. These estimates are then combined with climate change predictions obtained from two general circulation models (GCMs) under two greenhouse gas emissions (GHG) assumptions to evaluate the impact of climate change by 2100. For some scenarios significant decreases are predicted over the northern and southern parts of Africa.     

Thermodynamic properties of chlorite and berthierine derived from calorimetric measurements

In the context of the deep waste disposal, we have investigated the respective stabilities of two iron-bearing clay minerals: berthierine ISGS from Illinois [USA; (Al_0.975FeIII_0.182FeII_1.422Mg_0.157Li_0.035Mn_0.002)(Si_1.332Al_0.668)O₅(OH)₄] and chlorite CCa-2 from Flagstaff Hill, California [USA; (Si_2.633Al_1.367)(Al_1.116FeIII_0.215Mg_2.952FeII_1.712Mn_0.012Ca_0.011)O₁₀(OH)₈]. For berthierine, the complete thermodynamic dataset was determined at 1 bar and from 2 to 310 K, using calorimetric methods. The standard enthalpies of formation were obtained by solution-reaction calorimetry at 298.15 K, and the heat capacities were measured by heat-pulse calorimetry. For chlorite, the standard enthalpy of formation is measured by solution-reaction calorimetry at 298.15 K. This is completing the entropy and heat capacity obtained previously by Gailhanou et al. (Geochim Cosmochim Acta 73:4738–4749, 2009) between 2 and 520 K, by using low-temperature adiabatic calorimetry and differential scanning calorimetry. For both minerals, the standard entropies and the Gibbs free energies of formation at 298.15 K were then calculated. An assessment of the measured properties could be carried out with respect to literature data. Eventually, the thermodynamic dataset allowed realizing theoretical calculations concerning the berthierine to chlorite transition. The latter showed that, from a thermodynamic viewpoint, the main factor controlling this transition is probably the composition of the berthierine and chlorite minerals and the nature of the secondary minerals rather than temperature.