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221.
Sally Thompson Gabriel Katul Alexandra KoningsLuca Ridolfi 《Advances in water resources》2011,34(8):1049-1058
Lateral redistribution of surface water in patchy arid ecosystems has been hypothesized to contribute to the maintenance of vegetation patches through the provision of a water subsidy from bare sites to vegetated sites. Such runon-runoff processes occur during Hortonian runoff events on topographically sloping ground. Surface flow redistribution may also occur on topographically flat ground if the presence of the vegetation patch creates a contrast in infiltration rate, leading to a free-surface gradient in ponded water. The precise dynamics and the eco-hydrologic role of this process has resisted complete theoretical treatment to date. Here the overland flow equations are modified to account for the presence of vegetation situated over a flat surface. The resulting model is solved numerically to determine whether this mechanism could influence the spatial partitioning of water in patchy arid ecosystems. Assumptions made about infiltration processes and overland flow in existing eco-hydrologic models of patchy and patterned arid ecosystems are evaluated in comparison to the solution of the ‘full’ coupled Saint-Venant equations with various infiltration models. The results indicate that the optimization of vegetation spatial patch scales with respect to water redistribution may be determined by the size of the infiltration redistribution length L over which the presence of an infiltration contrast perturbs baseline infiltration behavior. 相似文献
222.
Marta Rodrigues Anabela Oliveira Martha Guerreiro André Bustorff Fortunato José Menaia Luís Mesquita David Alexandra Cravo 《Ocean Dynamics》2011,61(6):841-856
This study aims at understanding the fecal contamination behavior in a small coastal stream (Aljezur, Portugal), which has
significant economic and ecological values. Like in most small coastal systems, circulation and water renewal in the Aljezur
stream exhibit a strong variability due to their dependence on tides, waves, intermittent river flows, and a highly variable
morphology. Hence, the problem was approached through a combination of field surveys and the development and application of
a hard-coupled three-dimensional hydrodynamic and fecal contamination model. Salinity and temperature results have shown that
mixing and transport in the stream are very sensitive to the river flow and wind forcing. The model is able to represent the
main patterns and trends observed in Escherichia coli and fecal enterococcus concentrations along the stream, for different environmental and contamination conditions, suggesting
die-off rates on the order of 0.50–0.55 day−1. Die-off rate and the representation of the sediment-associated processes were identified as the major remaining sources
of uncertainty in the model. Results show that, owing to the processes that occur along the stream, fecal bacteria reach the
beaches water in numbers that comply with the European Bathing Waters Directive, even during the summer periods when the upstream
concentrations are larger. In particular, results suggest a direct relation between the tidal propagation upstream and the
reduction of the fecal bacteria concentrations along the stream that can be relevant for the development of a strategy for
the management of the system’s water safety. 相似文献
223.
224.
Ivan Petrovic Peter J. Heaney Alexandra Navrotsky 《Physics and Chemistry of Minerals》1996,23(2):119-126
Samples of microcrystalline silica varieties containing variable amounts of the new silica polymorph moganite (up to R~82 wt.%) have been studied by a combination of high temperature solution calorimetry using lead borate (2 PbO · B2O3) solvent and transposed temperature drop calorimetry near 977 K, in order to investigate the thermochemical stability of this new silica mineral. The enthalpy of solution at 977 K and the heat content (H977 — H298) of “pure” moganite phase were estimated to be -7.16 ± 0.35 kJ/mol and 43.62 ± 0.50 kJ/mol, respectively. The standard molar enthalpy of formation is-907.3 ± 1.2 kJ/mol. Thus, calorimetry strongly supports results of previous X-ray and Raman spectroscopic studies that moganite is a distinct silica polymorph. Its thermochemical instability relative to quartz at 298 K of 3.4 ± 0.7 kJ/mol is marginally higher than those of cristobalite and tridymite. Structurally, this instability may be related to the presence of distorted 4-membered rings of SiO4 tetrahedra, which are not found in the quartz structure. The metastability relative to quartz may also explain the apparent scarcity of moganite in altered rocks and in rocks that are older than 130 my. 相似文献
225.
Larry W. Finger Robert M. Hazen Jinmin Zhang Jaidong Ko Alexandra Navrotsky 《Physics and Chemistry of Minerals》1993,19(6):361-368
Single crystals of five wadsleyite compositions, β-(Mg,Fe)2SiO4 with Fe/(Fe+Mg)=0.00, 0.08, 0.16, 0.25 and 0.40, have been synthesized at high temperature and pressure in a uniaxial, split-sphere apparatus. Crystal structures of these samples, determined by x-ray diffraction techniques, reveal that iron is significantly ordered: Fe is depleted in the M2 octahedron, while it is enriched in M1 and M3. The most iron-rich synthetic sample, which falls well outside previous estimates of wadsleyite stability, raises questions regarding published Mg2SiO4-Fe2SiO4 phase diagrams at transition zone conditions. 相似文献
226.
As a contribution to the systematic study of iron oxide thermodynamics, this work reports enthalpies of formation of green rust, a double layered (FeII, FeIII) hydroxide with the ideal stoichiometry , with sulfate as the anion in the interlayer. Samples were characterized by X-ray powder diffraction, thermogravimetric analysis, infrared spectroscopy, and Mössbauer spectroscopy. Full chemical analysis was performed. Contents of FeII, FeIII, water, and sulfate were obtained. We report standard enthalpies of formation for green rust with different FeII/FeIII ratios. Enthalpies of formation from single cation compounds, namely, Fe(OH)2, Fe(OH)3, FeSO4 and H2O show reasonable agreement with Gibbs free energies of formation from single cation compounds recalculated from the reported literature values. These values show that green rust has little stabilization over a mechanical mixture of these single cation compounds and there is no thermodynamic preference for any particular FeII/FeIII ratio. 相似文献
227.
de Guenni Lelys B. García Mariangel Muñoz Ángel G. Santos José L. Cedeño Alexandra Perugachi Carlos Castillo José 《Theoretical and Applied Climatology》2017,129(3-4):1059-1073
Theoretical and Applied Climatology - It is well known that El Niño-Southern Oscillation (ENSO) modifies precipitation patterns in several parts of the world. One of the most impacted areas is... 相似文献
228.
Modern Guaymas Basin (Gulf of California, Mexico) is a region of high diatom productivity where exceptional preservation factors maintain biannually alternating sediment deposition as annual varves. New sediment cores from Guaymas Basin (MD02‐2512 and MD02‐2515) present the opportunity to construct climate records from below the last glacial period. A low‐resolution age model has been constructed from oxygen isotope analysis, correlation with other dated short piston cores from Guaymas Basin and an estimate of sedimentation rate. MD02‐2512 from eastern Guaymas Basin has an age range from the Holocene to late marine isotope stage 6 (MIS 6); MD02‐2515 from western Guaymas Basin has an age range from ~8000 to 40 000 yr. Shipboard analyses of colour reflectance, magnetic susceptibility and sediment density are combined with continuous X‐ray fluorescence scans to reconstruct a picture of glacial climate in the Gulf of California. Eastern Guaymas Basin is affected by glacial sea level fall, which results in a drastic change in productivity rates and sediment type. The laminated record of MIS 5 allows comparison with the Holocene, showing a similarity of sedimentation patterns during deglaciation and a series of very rapid variations just prior to the last glaciation. In western Guaymas Basin there are a series of Younger Dryas‐like events during the glacial, typified by low productivity and high terrigenous input. Long‐term climate and productivity changes appear to be caused by the southward displacement of the Subtropical High pressure zone. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
229.
The present study investigates the possible hydrologic effects of the proposed lignite open‐cast mining in Drama lignite field (north Greece). Recent years have seen a rapid increase in surface mining. This activity has generated a growing concern for the potential environmental impacts associated with large scale surface mining. In order to achieve a safe mine operation and allow extraction of lignite to considerable depths, extensive dewatering by pumping will be necessary, while at the same time it is desirable to avoid presence of overpumping conditions in the broader area. Based on stratigrafic, hydrologic and hydrogeologic data, a three‐dimensional finite difference model was developed in order to simulate the dewatering process of the western part of the lignite open‐cast mine in Drama and to predict both spatially and temporally the decline of ground water level down to the lignite surface. The dewatering of the part of the aquifer which underlies the mine area will influence the hydrological conditions of the broader region. The most important anticipated effects will be the abandonment of shallow wells as well as the decrease of ground water pumping rates of deep wells. Aquifer discharge towards the ditches of the study area will cease and there will be an inversion of ground water flow from the ditches towards the underlying aquifer. Dewatering activities will probably result in minor subsidence of the nearby peat deposits of Drama Philippi marshes. Moreover, sand pumping as well as the presence of gasses is likely to cause local subsidence phenomena, mainly in the pit slopes. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
230.