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161.
Brian L. Phillips Pamela C. Burnley Karen Worminghaus Alexandra Navrotsky 《Physics and Chemistry of Minerals》1997,24(3):179-190
We present NMR spectroscopic data, obtained by 1H MAS, 1H static spin-echo, and 29Si{1H} CP-MAS techniques, for a series of hydrous magnesium silicate samples synthesized at high pressure. This series includes chondrodite, β-Mg2SiO4, and phases A, B, superhydrous B, and E. Phases B and superhydrous B give very narrow 29Si NMR peaks and display the most de-shielded SiVI chemical shifts yet reported: ?170.4?ppm for B and ?166.6 for superhydrous B. The 1H NMR spectra of B and superhydrous B confirm the presence of paired hydroxyls, as determined from refinement of the H positions from X-ray diffraction data. The 1H MAS NMR spectra of phase B contain peaks for the two distinct hydrogen positions, with chemical shifts of +4.7 and +3.3?ppm. The static 1H spectrum contains a powder pattern characteristic of a strongly coupled hydrogen pair, from which a dipolar coupling constant of 18.6(4)?kHz and inter-hydrogen distance of d(H–H)=1.86(2)?Å were obtained. Superhydrous B appears to give two poorly resolved 1H MAS peaks, consistent with the presence of two distinct hydrogen pairs in the P21 mn crystal structure. Analysis of its spin-echo spectrum gives d(H–H)=1.83(3)?Å, slightly shorter than for phase B. β-Mg2SiO4, coexisting with phases B and superhydrous B, appears to give 29Si{1H} CP-MAS signal, indicating that it contains significant H concentration. The 29Si chemical shifts for phases B, superhydrous B, and chondrodite, together with those reported previously for other Mg-silicates, show a good correlation with structural parameters. 相似文献
162.
Klaus-Dieter Grevel Mirko Schoenitz Volker Skrok Alexandra Navrotsky Werner Schreyer 《Contributions to Mineralogy and Petrology》2001,142(3):298-308
The enthalpy of drop-solution in molten 2PbO·B2O3 of synthetic and natural lawsonite, CaAl2(Si2O7)(OH)2·H2O, was measured by high-temperature oxide melt calorimetry. The enthalpy of formation determined for the synthetic material is (fHOxides=-168.7Dž.4 kJ mol-1, or (fH0298=-4,872.5dž.0 kJ mol-1. These values are in reasonable agreement with previously published data, although previous calorimetric work yielded slightly more exothermic data and optimisation methods resulted in slightly less exothermic values. The equilibrium conditions for the dehydration of lawsonite to zoisite, kyanite and quartz/coesite at pressures and temperatures up to 5 GPa and 850 °C were determined by piston cylinder experiments. These results, other recent phase equilibrium data, and new calorimetric and thermophysical data for lawsonite and zoisite, Ca2Al3(SiO4)(Si2O7)O(OH), were used to constrain a mathematical programming analysis of the thermodynamic data for these two minerals in the chemical system CaO-Al2O3-SiO2-H2O (CASH). The following data for lawsonite and zoisite were obtained: (fH0298 (lawsonite)=-4,865.68 kJ mol-1 , S0298 (lawsonite)=229.27 J K-1 mol-1 , (fH0298 (zoisite)=-6,888.99 kJ mol-1 , S0298 (zoisite)=297.71 J K-1 mol-1 . Additionally, a recalculation of the bulk modulus of lawsonite yielded K=120.7 GPa, which is in good agreement with recent experimental work. 相似文献
163.
Short and high frequency internal waves, propagating through horizontal gradients of temperature formed by long and low-frequency
waves, induce vertical transferof heat with effective coefficients 10−4 – 10−3 m2/s and lead to a fine structure formation. Horizontal turbulence with seals of order 100 m produce the same effect in the
presence of internal waves. The same is true for other substances, such as salt, oxygen, organic matter. It is suggested that
this augmenting of vertical transports due to internal waves is an essential factor for high biological productivity in shelf
zones. 相似文献
164.
A new determination, using high temperature drop-solution calorimetry, of the enthalpy of transformation of MgSiO3 pyroxene to ilmenite gives H
298 = 59.03 ±4.26 kJ/mol. The heat capacity of the ilmenite and orthopyroxene phases has been measured by differential scanning calorimetry at 170–700 K; Cp of MgSiO3 ilmenite is 4–10 percent less than that of MgSiO3 pyroxene throughout the range studied. The heat capacity differences are consistent with lattice vibrational models proposed by McMillan and Ross (1987) and suggest an entropy change of -18 ± 3 J-K-1 ·mol-1, approximately independent of temperature, for the pyroxene-ilmenite transition. The unit cell parameters of MgSiO3 ilmenite were measured at 298–876 K and yield an average volume thermal expansion coefficient of 2.44 × 10-5 K-1. The thermochemical data are used to calculate phase relations involving pyroxene, -Mg2SiO4 plus stishovite, Mg2SiO4 spinel plus stishovite, and ilmenite in good agreement with the results of high pressure studies. 相似文献
165.
With increasing pressure, MnSiO3 rhodonite stable at atmospheric pressure transforms to pyroxmangite, then to clinopyroxene and further to tetragonal garnet, which finally decomposes into MnO (rocksalt) plus SiO2 (stishovite). High temperature solution calorimetry of synthetic rhodonite, clinopyroxene and garnet forms of MnSiO3 was used to measure the enthalpies of these transitions. ΔH 974 0 for the rhodonite-clinopyroxene and ΔH 298 0 for the clinopyroxene-garnet transition are 520±490 and 8,270±590 cal/mol, respectively. The published data on the enthalpy of the rhodonite-pyroxmangite transition, phase equilibrium boundaries, compressibility and thermal expansion data are used to calculate entropy changes for the transitions. The enthalpy, entropy and volume changes are very small for all the transitions among rhodonite, pyroxmangite and clinopyroxene. The calculated boundary for the clinopyroxene-garnet transition is consistent with the published experimental results. The pyroxene-garnet transition in several materials, including MnSiO3, is characterized by a relatively small negative entropy change and large volume decrease, resulting in a small positiveP – T slope. The disproportionation of MnSiO3 garnet to MnO plus stishovite and of Mn2SiO4 olivine to garnet plus MnO are calculated to occur at about 17–18 and 14–15 GPa, respectively, at 1,000–1,500 K. 相似文献
166.
An Upper Maastrichtian horizon rich in Loftusia is for the first time described in situ in Greece in the province of Boeotia. It is found in a continuous undisturbed carbonate sequence of the eastern Greece platform (Subpelagonian zone) of Maastrichtian–Paleocene age followed by flysch sedimentation. Loftusia is found in a facies reflecting an outer shelf environment, associated with debris of rudists, Orbitoides spp., Siderolites calcitrapoides, Omphalocyclus macroporus, Hellenocyclina beotica, Sulcoperculina sp., and echinoderms. Similar fauna, but without Loftusia, is found in the surrounding levels of Late Maastrichtian age as well. This recovery of the genus in the western part of its distribution area, where it is not as abundant as in the eastern part, is considered significant for the palaeobiogeography of the genus in Tethys Ocean during Late Cretaceous. To cite this article: A. Zambetakis-Lekkas, A. Kemeridou, C. R. Geoscience 338 (2006). 相似文献
167.
Combining geographic information system, multicriteria evaluation techniques and fuzzy logic in siting MSW landfills 总被引:2,自引:0,他引:2
Alexandra Gemitzi Vassilios A. Tsihrintzis Evangelos Voudrias Christos Petalas George Stravodimos 《Environmental Geology》2007,51(5):797-811
This study presents a methodology for siting municipal solid waste landfills, coupling geographic information systems (GIS),
fuzzy logic, and multicriteria evaluation techniques. Both exclusionary and non-exclusionary criteria are used. Factors, i.e.,
non-exclusionary criteria, are divided in two distinct groups which do not have the same level of trade off. The first group
comprises factors related to the physical environment, which cannot be expressed in terms of monetary cost and, therefore,
they do not easily trade off. The second group includes those factors related to human activities, i.e., socioeconomic factors,
which can be expressed as financial cost, thus showing a high level of trade off. GIS are used for geographic data acquisition
and processing. The analytical hierarchy process (AHP) is the multicriteria evaluation technique used, enhanced with fuzzy
factor standardization. Besides assigning weights to factors through the AHP, control over the level of risk and trade off
in the siting process is achieved through a second set of weights, i.e., order weights, applied to factors in each factor
group, on a pixel-by-pixel basis, thus taking into account the local site characteristics. The method has been applied to
Evros prefecture (NE Greece), an area of approximately 4,000 km2. The siting methodology results in two intermediate suitability maps, one related to environmental and the other to socioeconomic
criteria. Combination of the two intermediate maps results in the final composite suitability map for landfill siting. 相似文献
168.
Alexandra M.F. Rao Mark J. McCarthy Wayne S. Gardner Richard A. Jahnke 《Continental Shelf Research》2007
Nitrogen (N) cycling and respiration rates were measured in sediment columns packed with southeastern United States continental shelf sands, with high permeability (4.66×10−11 m2) and low organic carbon (0.05%) and nitrogen (0.008%). To simulate porewater advection, natural shelf seawater was pumped through columns of different lengths to achieve fluid residence times of approximately 3, 6, and 12 h. Experiments were conducted seasonally at in situ temperature. Fluid flow was uniform in nearly all columns, with minimal dead zones and channeling. Significant respiration (O2 consumption and ∑CO2 production) occurred in all columns, with highest respiration rates in summer. Most (78–100%) remineralized N was released as N2 in the majority of cases, including columns with oxic porewater throughout, with only a small fraction released as NO3− from some oxic columns. A rate of 0.84–4.83×1010 mol N yr−1, equivalent to 1.06–6.09×10−6 mmol N cm−2 h−1, was calculated for benthic N2 production in the South Atlantic Bight, which can account for a large fraction of new N inputs to this shelf region. Metal and sulfate reduction occurred in long residence time columns with anoxic outflow in summer and fall, when respiration rates were highest. Because permeable sediments dominate continental shelves, N2 production in high permeability coastal sediments may play an important role in the global N cycle. 相似文献
169.
V. V. Navrotsky E. D. Kholodkevich E. P. Pavlova S. A. Smirnov 《Izvestiya Physics of the Solid Earth》2007,43(6):517-523
Based on experimental data and numerical modeling, the possible mechanisms of the effect of internal gravitational waves within the range of periods from tidal values to a few tens of minutes on crustal microdeformations in the coastal zone of the Sea of Japan are examined. The spectral analysis of oscillations in the sea level and microdeformations recorded in various seasons reveals common maximums of energy at diumal and semidiurnal periods, but the coincidence of the maximums at shorter periods is random and varies with time. The phase shifts between the surface tide and crustal deformations are also unstable in time. To explain the observed interrelations between the processes at sea and in the Earth’s crust, we modeled numerically the generation of internal tides, bores, and packets of short internal waves in terms of a nonlinear model of shallow water. It is shown that the observed effects can be caused (1) by the resonance between the wavelength of the internal tide and the shelf width and (2) by the reflection of bores and internal wave packets from a steep bottom and rocky shores or by their collapse. 相似文献
170.
Efraín Ovando-Shelley Alexandra Ossa Miguel P. Romo 《Soil Dynamics and Earthquake Engineering》2007,27(4):333-343
Extensive pumping to extract water from Mexico City's subsoil has caused regional sinking. Water pumping produces regional consolidation which increases effective stresses acting on the subsoil modifying its static and dynamic properties. As the soil properties change, so does their dynamic response. Approximate expressions to estimate the future changes in soil properties are proposed. Also, this paper puts forth new evidence to illustrate these changes and presents estimates of future settlements in central Mexico City, using a soil consolidation model that overcomes some of the limitations of Terzaghi's theory. Results of an analysis to estimate the effects of the evolution of the subsoil's dynamic properties are illustrated by means of seismic analyses performed on a couple of sites in an old lake bed in Mexico City. 相似文献