Laser Ablation In Situ Silicon Stable Isotope Analysis of Phytoliths

Silicon is a beneficial element for many plants and is deposited in plant tissue as amorphous bio‐opal called phytoliths. The biochemical processes of silicon uptake and precipitation induce isotope fractionation: the mass‐dependent shift in the relative abundances of the stable isotopes of silicon. At the bulk scale, δ³⁰Si ratios span from ?2 to +6‰. To further constrain these variations in situ, at the scale of individual phytolith fragments, we used femtosecond laser ablation multi‐collector inductively coupled plasma‐mass spectrometry (fsLA‐MC‐ICP‐MS). A variety of phytoliths from grasses, trees and ferns were prepared from plant tissue or extracted from soil. Good agreement between phytolith δ³⁰Si ratios obtained by bulk solution MC‐ICP‐MS analysis and in situ isotope ratios from fsLA‐MC‐ICP‐MS validates the method. Bulk solution analyses result in at least twofold better precision for δ³⁰Si (2s on reference materials ≤ 0.11‰) over that found for the means of in situ analyses (2s typically ≤ 0.24‰). We find that bushgrass, common reed and horsetail show large internal variations up to 2‰ in δ³⁰Si, reflecting the various pathways of silicon from soil to deposition. Femtosecond laser ablation provides a means to identify the underlying processes involved in the formation of phytoliths using silicon isotope ratios.     

The Mg-carbonate-Fe interaction:Implication for the fate of subducted carbonates and formation of diamond in the lower mantle

The fate of subducted carbonates in the lower mantle and at the core-mantle boundary was modelled via experiments in the MgCO3-Fe^0 system at 70-150 GPa and 800-2600 Kin a laser-heated diamond anvil cell.Using in situ synchrotro n X-ray diffraction and ex situ transmission electron microscopy we show that the reduction of Mg-carbonate can be exemplified by:6 MgCO3+19 Fe=8 FeO+10(Mg0.6Fe^0.4)O+Fe7 C3+3 C.The presented results suggest that the interaction of carbonates with Fe^0 or Fe^0-bearing rocks can produce Fe-carbide and diamond,which can accumulate in the D"region,depending on its carbon to Fe ratio.Due to the sluggish kinetics of the transformation,diamond can remain metastable at the core-mantle boundary(CMB)unless it is in a direct contact with Fe-metal.In addition,it can be remobilized by redox melting accompanying the generation of mantle plumes.     

Multimodal reliability analysis of 3D slopes with a genetic algorithm

Acta Geotechnica - This paper presents a genetic algorithm (GA) to solve the multimodal optimisation problem resulting from 3D slopes prone to multiple regions of failure. A probabilistic approach...     

Thermal evolution of an ancient subduction interface revealed by Lu–Hf garnet geochronology,Halilbağı Complex (Anatolia)

The thermal structure of subduction zones exerts a major influence on deep-seated mechanical and chemical processes controlling arc magmatism, seismicity, and global element cycles. Accretionary complexes exposed inland may comprise tectonic blocks with contrasting pressure–temperature (P–T) histories, making it possible to investigate the dynamics and thermal evolution of former subduction interfaces. With this aim, we present new Lu–Hf geochronological results for mafic rocks of the Halilba?? Complex (Anatolia) that evolved along different thermal gradients. Samples include a lawsonite–epidote blueschist, a lawsonite–epidote eclogite, and an epidote eclogite (all with counter-clockwise P–T paths), a prograde lawsonite blueschist with a “hairpin”-type P–T path, and a garnet amphibolite from the overlying sub-ophiolitic metamorphic sole. Equilibrium phase diagrams suggest that the garnet amphibolite formed at ～0.6–0.7 GPa and 800–850 °C, whereas the prograde lawsonite blueschist records burial from 2.1 GPa and 420 °C to 2.6 GPa and 520 °C. Well-defined Lu–Hf isochrons were obtained for the epidote eclogite (92.38 ± 0.22 Ma) and the lawsonite–epidote blueschist (90.19 ± 0.54 Ma), suggesting rapid garnet growth. The lawsonite–epidote eclogite (87.30 ± 0.39 Ma) and the prograde lawsonite blueschist (ca. 86 Ma) are younger, whereas the garnet amphibolite (104.5 ± 3.5 Ma) is older. Our data reveal a consistent trend of progressively decreasing geothermal gradient from granulite-facies conditions at ～104 Ma to the epidote-eclogite facies around 92 Ma, and the lawsonite blueschist-facies between 90 Ma and 86 Ma. Three Lu–Hf garnet dates (between 92 Ma and 87 Ma) weighted toward the growth of post-peak rims (as indicated by Lu distribution in garnet) suggest that the HP/LT rocks were exhumed continuously and not episodically. We infer that HP/LT metamorphic rocks within the Halilba?? Complex were subjected to continuous return flow, with “warm” rocks being exhumed during the tectonic burial of “cold” ones. Our results, combined with regional geological constraints, allow us to speculate that subduction started at a transform fault near a mid-oceanic spreading centre. Following its formation, this ancient subduction interface evolved thermally over more than 15 Myr, most likely as a result of heat dissipation rather than crustal underplating.     

Geometrical considerations in imaging the solar corona

X-ray observations of the solar corona show that it is comprised of three-dimensional magnetic structures which appear to be primarily in the form of fluxtubes or loops. Imaging the X-ray corona has led to a greater understanding of the dynamical behaviour of and the energy distribution in these magnetic structures. However, imaging observations, by their very nature, integrate along the line of sight resulting in a two-dimensional representation of the actual three-dimensional distribution. The optically thin nature of the solar corona to X-ray radiation makes the integrated images particularly difficult to interpret. The analysis of the two-dimensional observations must, therefore, inlcude the effect of the orientation of the coronal structure to the line-of-sight direction; a fact which is almost always ignored. In this paper we discuss the effect of loop orientation on the two-dimensional representation and argue that these effects may lead to a misinterpretation of the physics occurring in the structures observed. In particular, we discuss observations taken by the Soft X-ray Telescope (SXT) on board the Yohkoh satellite, taking account of the instrumental thermal response, spatial resolution, and point-spread-function.We test the effect of geometry on the determination of the loop pressure by considering equatorial loops at various longitudes and discuss the implications of this for studies of coronal soft X-ray loops.     

Origin of fayalitic olivine rims and lath-shaped matrix olivine in the CV3 chondrite Allende and its dark inclusions

Abstract— We have studied an Allende dark inclusion by optical microscopy, scanning electron microscopy, electron microprobe analysis and transmission electron microscopy. The inclusion consists of chondrules, isolated olivines and matrix, which, as in the Allende host, is mainly composed of 5–20 μm long lath-shaped fayalitic grains with a narrow compositional range (Fa_{42 ± 2}) and nepheline. Olivine phenocrysts in chondrules and isolated olivine grains show various degrees of replacement by 5–10 μm wide fayalitic rims (Fa_{39 ± 2}) and 100–1000 μm wide translucent zones, which consist of 5–20 μm long lath-shaped fayalitic grains (Fa_{41 ± 1}) intergrown with nepheline. These fayalitic olivines, like those in the matrix of the dark inclusion, contain 10–20 nm sized inclusions of chromite, hercynite, and Fe-Ni sulfides. The fayalitic rims around remnant olivines are texturally and compositionally identical to those in Allende host, suggesting that they have similar origins. Chondrules are surrounded by opaque rims consisting of tiny lath-shaped fayalitic olivines (<1–3 μm long) intergrown with nepheline. As in the Allende host, fayalitic olivine veins may crosscut altered chondrules, fine-grained chondrule rims and extend into the matrix, indicating that alteration occurred after accretion. We infer that fayalitic olivine rims and lath-shaped fayalites in Allende and its dark inclusions formed from phyllosilicate intermediate phases. This explanation accounts for (1) the similarity of the replacement textures observed in the dark inclusion and Allende host to aqueous alteration textures in CM chondrites; (2) the anomalously high abundances of Al and Cr and the presence of tiny inclusions of spinels and sulfides in fayalitic olivines in Allende and Allende dark inclusions; (3) abundant voids and defects in lath-shaped fayalites in the Allende dark inclusion, which may be analogous to those in partly dehydrated phyllosilicates in metamorphosed CM/CI chondrites. We conclude that the matrix and chondrule rims in Allende were largely converted to phyllosilicates and then completely dehydrated. The Allende dark inclusions experienced diverse degrees of aqueous/hydrothermal alteration prior to complete dehydration. The absence of low-Ca pyroxene in the dark inclusion and its significant replacement by fayalitic olivine in Allende is consistent with the lower resistance of low-Ca pyroxene to aqueous alteration relative to forsteritic olivine. Hydro-thermal processing of Allende probably also accounts for the low abundance of planetary noble gases and interstellar grains, and the formation of nepheline, sodalite, salite-hedenbergite pyroxenes, wollastonite, kirschsteinite and andradite in chondrules and Ca,Al-rich inclusions.     

Thirty-Element Active Antenna Array as a Prototype of a Huge Low-Frequency Radio Telescope

An effective wide-band (10 to 60 MHz) active antenna element has been developed. The cost of one short (3 m), thin dipole with built-in amplifier and metal construction is less than 45 euro. It was shown both theoretically and experimentally that the upper limiting frequency is at least 60 MHz, the dynamic range is 90 dB/V and the share of the amplifier noise to the background antenna temperature is about 10%. The developed active dipole was tested by building a 30-element antenna array and comparing its parameters with one of the subpart of the UTR-2 radio telescope having passive dipoles of 8.6 m in length and 1.8 m in diameter. The 3C461 ionospheric scintillation spectra observed in the experiments show that the sensitivities and noise-immunities of both antennas are close. This proves the availability using of a short cheap active dipole in new generation giant radio telescopes.     

Vertical Dynamics of the Energy Release Process in a Simple two-Ribbon Flare

Observations of the quiescent filament eruption and the spotless two-ribbon flare of 12 September 2000 are presented. A simple flare morphology, large spatial scales, and a suitable viewing angle provide insight into characteristics of the energy release process which is attributed to the reconnection process in the current sheet formed below the eruptive filament. The flare ribbons appeared and started to expand laterally while the filament was still recognizable, enabling simultaneous measurements of the ribbon separation w and the height of the lower edge of the filament, h. The ratio w/h estimated for the expanding portions of ribbons indicates that the width-to-length ratio of the current sheet at the onset of the fast reconnection ranges between and . The ribbon elements characterized by w/h> remained stationary. The Nançay radioheliograph data in the decimeter–meter wavelengths show one group of radio bursts ahead of the filament (moving type IV burst) and another group behind the filament. The centroids of the radio sources behind the filament were confined to the region outlined by the lower edge of the filament and the magnetic inversion line, suggestive of emission from the current sheet. Sources were preferably located close to the lower edge of the filament and some appeared close to the magnetic inversion line. Two possible explanations are discussed: one in terms of the fast-mode bow shocks in the reconnection outflow jets, and another in terms of a multiple tearing of the current sheet and subsequent coalescence of plasmoids.