Estimation of fault-zone conductance by calibration of a regional groundwater flow model: Desert Hot Springs,California

The hydraulic conductance of a large fault zone has been estimated by calibrating a regional groundwater flow model. Drops in groundwater elevations of over 80 m have been observed along a 15-km length of the Mission Creek fault, California, USA. The large drops in elevation are attributed to the reduced hydraulic conductivity of the fault materials. A conceptual and numerical model of the two hydrologic subbasins in Desert Hot Springs, separated by the Mission Creek fault, was developed. The model was used to estimate the hydraulic conductance along the fault. The parameter estimation involved calibrating the model with observed groundwater elevations from over 40 locations over a 60-year period. The fault hydraulic conductances were estimated assuming a linear trend in the fault length, yielding variations in the fault hydraulic conductance of about an order of magnitude along the fault length (2?×?10^?11–4?×?10^?10 1/s). When an average fault thickness of 35 m is assumed, the fault hydraulic conductivity values are estimated to be from three to five orders of magnitude lower than the surrounding materials. A sensitivity analysis indicated that assumptions made in the conceptual model do not significantly affect estimated fault hydraulic conductances.     

Zirconium isotope evidence for incomplete admixing of r-process components in the solar nebula

Isotopic anomalies in Mo and Zr have recently been reported for bulk chondrites and iron meteorites and have been interpreted in terms of a primordial nucleosynthetic heterogeneity in the solar nebula. We report precise Zr isotopic measurements of carbonaceous, ordinary and enstatite chondrites, eucrites, mesosiderites and lunar rocks. All bulk rock samples yield isotopic compositions that are identical to the terrestrial standard within the analytical uncertainty. No anomalies in ⁹²Zr are found in any samples including high Nb/Zr eucrites and high and low Nb/Zr calcium-aluminum-rich inclusions (CAIs). These data are consistent with the most recent estimates of <10⁻⁴ for the initial ⁹²Nb/⁹³Nb of the solar system. There exists a trace of isotopic heterogeneity in the form of a small excess of r-process ⁹⁶Zr in some refractory CAIs and some metal-rich phases of Renazzo. A more striking enrichment in ⁹⁶Zr is found in acetic acid leachates of the Allende CV carbonaceous chondrite. These data indicate that the r- and s-process Zr components found in presolar grains were well mixed on a large scale prior to planetary accretion. However, some CAIs formed before mixing was complete, such that they were able to sample a population of r-process-enriched material. The maximum amount of additional r-process component that was added to the otherwise well-mixed Zr in the molecular cloud or disk corresponds to ∼0.01%.     

Isotopic exchange of carbon-bound hydrogen over geologic timescales

The increasing popularity of compound-specific hydrogen isotope (D/H) analyses for investigating sedimentary organic matter raises numerous questions about the exchange of carbon-bound hydrogen over geologic timescales. Important questions include the rates of isotopic exchange, methods for diagnosing exchange in ancient samples, and the isotopic consequences of that exchange. This article provides a review of relevant literature data along with new data from several pilot studies to investigate such issues. Published experimental estimates of exchange rates between organic hydrogen and water indicate that at warm temperatures (50-100°C) exchange likely occurs on timescales of 10⁴ to 10⁸ yr. Incubation experiments using organic compounds and D-enriched water, combined with compound-specific D/H analyses, provide a new and highly sensitive method for measuring exchange at low temperatures. Comparison of δD values for isoprenoid and n-alkyl carbon skeletons in sedimentary organic matter provides no evidence for exchange in young (<1 Ma), cool sediments, but strong evidence for exchange in ancient (>350 Ma) rocks. Specific rates of exchange are probably influenced by the nature and abundance of organic matter, pore-water chemistry, the presence of catalytic mineral surfaces, and perhaps even enzymatic activity.Estimates of equilibrium fractionation factors between organic H and water indicate that typical lipids will be depleted in D relative to water by ∼75 to 140‰ at equilibrium (30°C). Thus large differences in δD between organic molecules and water cannot be unambiguously interpreted as evidence against hydrogen exchange. A better approach may be to use changes in stereochemistry as a proxy for hydrogen exchange. For example, estimated rates of H exchange in pristane are similar to predicted rates for stereochemical inversion in steranes and hopanes. The isotopic consequences of this exchange remain in question. Incubations of cholestene with D₂O indicate that the number of D atoms incorporated during structural rearrangements can be far less than the number of C-H bonds that are broken. Sample calculations indicate that, for steranes in immature sediments, the D/H ratio imparted by biosynthesis may be largely preserved in spite of significant structural changes.     

The structure and the phyllosilicates (chemistry, crystallinity and texture) of Talas Ala-Tau (Tien Shan, Kyrgyz Republic): comparison with more recent subduction complexes

Geological mapping and structural analysis of the Talas Ala Tau (Tien Shan, Kyrgyz Republic) have revealed a complex structure composed of folds with axial-plane cleavage and thrust faults verging towards the NE. The main structures of the range correspond to minor Tertiary and Carboniferous–Permian deformation superimposed on the main deformation event that took place during the Baikalian orogeny. The pervasive axial-plane cleavage diminishes in penetrativity from the hinterland to the foreland in both the Uzunakhmat and Karagoin sheets. The main thrusts developed phyllonitic shear-related rocks on the hangingwall immediately above the thrust planes. A crystal-chemical study of the phyllosilicates growth during the Baikalian deformation event along a cross-section revealed changes in the crystallinity, composition and lattice parameters of them. The phyllosilicates present in the Talas Ala Tau rocks were crystallized in very low-grade metamorphic conditions, that is below 300 °C, as indicated by their Kübler Index (KI), which decreases from SW towards the NE. Detailed TEM study of the phyllosilicates reveals a clear textural difference at the lattice level between samples with higher or lower KI parameters. There is also a clear difference in crystal-chemical parameters (KI and b) and composition between the phyllosilicates growth in relation to the axial-plane cleavage and the ones belonging to the thrust-related phyllonites. The first ones are more affected by the ferrimuscovitic vector than the phyllosilicates of phyllonites, closer to the theoretical phengitic component. Huge ranges of values of phengitic content of micas at sample level are interpreted as the result of a decompression path from at least 8 kbar. We propose a subduction geodynamic environment for the regional deformation and the origin of the phyllosilicates, as they are similar to those obtained in more recent accretionary complexes.     

Vertical exchange due to horizontal density gradients in lakes; the case of Lake Lucerne

Recent field investigations have shown that differential mixing causes a significant density driven exchange between the two eastern basins of Lake Lucerne, Gersauersee and Urnersee. The long term vertical mixing characteristics during the winter mixing period and the influence of the resulting exchange flow on water quality are examined through the analysis of ten years (1964 to 1974) of monthly limnological data. Vertical homogenization of the state variables (temperature, electric conductivity and density) occurred on average once every two years in Urnersee, but not once in Gersauersee where the ten year average winter mixed-layer depth extended to 120 m. In Urnersee intense mixing was evident over the whole water column for every year. In contrast intense mixing in the deeper layers of Gersauersee occurred approximately once every four years. A three layer model shows that theT/ ₂₀ signature of the Gersauersee intermediate water correlates best with the Urnersee deep water confirming the regular occurrence of a density driven exchange. For the lower layers the oxygen consumption rate in Urnersee was approximately twice that for Gersauersee. It appears the exchange flow can act either as a source or sink for the oxygen balance of Urnersee deep water. The larger rate in Urnersee hypolimnion might also be associated with the larger sediment input to this system. Density driven exchange resulting from differential mixing is probably an important contribution to the vertical water replenishment in many lakes.     

Chemical weathering of a marine terrace chronosequence, Santa Cruz, California I: Interpreting rates and controls based on soil concentration-depth profiles

The spatial and temporal changes in element and mineral concentrations in regolith profiles in a chronosequence developed on marine terraces along coastal California are interpreted in terms of chemical weathering rates and processes. In regoliths up to 15 m deep and 226 kyrs old, quartz-normalized mass transfer coefficients indicate non-stoichiometric preferential release of Sr > Ca > Na from plagioclase along with lesser amounts of K, Rb and Ba derived from K-feldspar. Smectite weathering results in the loss of Mg and concurrent incorporation of Al and Fe into secondary kaolinite and Fe-oxides in shallow argillic horizons. Elemental losses from weathering of the Santa Cruz terraces fall within the range of those for other marine terraces along the Pacific Coast of North America.Residual amounts of plagioclase and K-feldspar decrease with terrace depth and increasing age. The gradient of the weathering profile b_s is defined by the ratio of the weathering rate, R to the velocity at which the profile penetrates into the protolith. A spreadsheet calculator further refines profile geometries, demonstrating that the non-linear regions at low residual feldspar concentrations at shallow depth are dominated by exponential changes in mineral surface-to-volume ratios and at high residual feldspar concentrations, at greater depth, by the approach to thermodynamic saturation. These parameters are of secondary importance to the fluid flux q_h, which in thermodynamically saturated pore water, controls the weathering velocity and mineral losses from the profiles. Long-term fluid fluxes required to reproduce the feldspar weathering profiles are in agreement with contemporary values based on solute Cl balances (q_h = 0.025-0.17 m yr⁻¹).During saturation-controlled and solute-limited weathering, the greater loss of plagioclase relative to K-feldspar is dependent on the large difference in their respective solubilities instead of the small difference between their respective reaction kinetics. The steady-state weathering rate under such conditions is defined as

     

Determination of the masses of planetary satellites from their mutual gravitational perturbations

We analyze the possibility of determining the masses of outer planetary satellites from their mutual gravitational perturbations via ground-based observations. Such a technique has been applied in (Emelyanov, 2005b) to determine the mass of the Jovian satellite Himalia. In this paper, we use the least-squares method to compute the errors of satellite masses inferred from simulated observations. We analyze several of the most suitable variants of groups of outer satellites of planets with maximum mutual attraction. We found that the mass of the Satumian satellite Phoebe (S9) can be refined by continuing observations of the satellite S25 Mundilfari until 2027. We show that the masses of other known outer planetary satellites cannot be determined from ground-based observations.     

Multiscale Edge Detection in the Corona

Coronal Mass Ejections (CMEs) are challenging objects to detect using automated techniques, due to their high velocity and diffuse, irregular morphology. A necessary step to automating the detection process is to first remove the subjectivity introduced by the observer used in the current, standard, CME detection and tracking method. Here we describe and demonstrate a multiscale edge detection technique that addresses this step and could serve as one part of an automated CME detection system. This method provides a way to objectively define a CME front with associated error estimates. These fronts can then be used to extract CME morphology and kinematics. We apply this technique to a CME observed on 18 April 2000 by the Large Angle Solar COronagraph experiment (LASCO) C2/C3 and a CME observed on 21 April 2002 by LASCO C2/C3 and the Transition Region and Coronal Explorer (TRACE). For the two examples in this work, the heights determined by the standard manual method are larger than those determined with the multiscale method by ≈10% using LASCO data and ≈20% using TRACE data.