Chemical weathering of a marine terrace chronosequence, Santa Cruz, California I: Interpreting rates and controls based on soil concentration-depth profiles

The spatial and temporal changes in element and mineral concentrations in regolith profiles in a chronosequence developed on marine terraces along coastal California are interpreted in terms of chemical weathering rates and processes. In regoliths up to 15 m deep and 226 kyrs old, quartz-normalized mass transfer coefficients indicate non-stoichiometric preferential release of Sr > Ca > Na from plagioclase along with lesser amounts of K, Rb and Ba derived from K-feldspar. Smectite weathering results in the loss of Mg and concurrent incorporation of Al and Fe into secondary kaolinite and Fe-oxides in shallow argillic horizons. Elemental losses from weathering of the Santa Cruz terraces fall within the range of those for other marine terraces along the Pacific Coast of North America.Residual amounts of plagioclase and K-feldspar decrease with terrace depth and increasing age. The gradient of the weathering profile b_s is defined by the ratio of the weathering rate, R to the velocity at which the profile penetrates into the protolith. A spreadsheet calculator further refines profile geometries, demonstrating that the non-linear regions at low residual feldspar concentrations at shallow depth are dominated by exponential changes in mineral surface-to-volume ratios and at high residual feldspar concentrations, at greater depth, by the approach to thermodynamic saturation. These parameters are of secondary importance to the fluid flux q_h, which in thermodynamically saturated pore water, controls the weathering velocity and mineral losses from the profiles. Long-term fluid fluxes required to reproduce the feldspar weathering profiles are in agreement with contemporary values based on solute Cl balances (q_h = 0.025-0.17 m yr⁻¹).During saturation-controlled and solute-limited weathering, the greater loss of plagioclase relative to K-feldspar is dependent on the large difference in their respective solubilities instead of the small difference between their respective reaction kinetics. The steady-state weathering rate under such conditions is defined as

     

Multiscale Edge Detection in the Corona

Coronal Mass Ejections (CMEs) are challenging objects to detect using automated techniques, due to their high velocity and diffuse, irregular morphology. A necessary step to automating the detection process is to first remove the subjectivity introduced by the observer used in the current, standard, CME detection and tracking method. Here we describe and demonstrate a multiscale edge detection technique that addresses this step and could serve as one part of an automated CME detection system. This method provides a way to objectively define a CME front with associated error estimates. These fronts can then be used to extract CME morphology and kinematics. We apply this technique to a CME observed on 18 April 2000 by the Large Angle Solar COronagraph experiment (LASCO) C2/C3 and a CME observed on 21 April 2002 by LASCO C2/C3 and the Transition Region and Coronal Explorer (TRACE). For the two examples in this work, the heights determined by the standard manual method are larger than those determined with the multiscale method by ≈10% using LASCO data and ≈20% using TRACE data.     

Ficus benjamina leaves as indicator of atmospheric pollution: a reconaissance study

We present a diagnostic study to evaluate the suitability of Ficus benjamina tree leaves as a captor of heavy metal particles from atmospheric dusts in urban areas. Leaf samples were taken at 16 localities within three areas in Morelia, state of Michoacán (Mexico??s medium size city, 830000 inhabitants). Measurements of magnetic susceptibility were conducted to determine the magnetic enhancement using samples from green, relatively unpolluted area, as a reference. The samples collected at areas with heavy traffic (main avenues) yielded values almost ten times higher than the values obtained for the unpolluted reference. Isothermal Remanent Magnetization curves are proportional to the degree of pollution. Associations of almost pure magnetite with heavy metals were revealed by scanning electron microscope.     

Seismic damage evaluation in urban areas using the capacity spectrum method: Application to Barcelona

Conceptual aspects related to seismic vulnerability, damage and risk evaluation are discussed first, together with a short review of the most widely used possibilities for seismic evaluation of structures. The capacity spectrum method and the way of obtaining seismic damage scenarios for urban areas starting from capacity and fragility curves are then discussed. The determination of capacity curves for buildings using non-linear structural analysis tools is then explained, together with a simplified expeditious procedure allowing the development of fragility curves. The seismic risk of the buildings of Barcelona, Spain, is analyzed in the paper, based on the application of the capacity spectrum method. The seismic hazard in the area of the city is described by means of the reduced 5% damped elastic response spectrum. The information on the buildings was obtained by collecting, arranging, improving and completing a broad database of the dwellings and current buildings. The buildings existing in Barcelona are mainly of two types: unreinforced masonry structures and reinforced concrete buildings with waffled-slab floors. The ArcView software was used to create a GIS tool for managing the collected information in order to develop seismic risk scenarios. This study shows that the vulnerability of the buildings is significant in Barcelona and, therefore, in spite of the low-to-moderate seismic hazard in the region, the expected seismic risk is considerable.     

Spatio-temporal patterns of throughfall and solute deposition in an open tropical rain forest

The brief interaction of precipitation with a forest canopy can create a high spatial variability of both throughfall and solute deposition. We hypothesized that (i) the variability in natural forest systems is high but depends on system-inherent stability, (ii) the spatial variability of solute deposition shows seasonal dynamics depending on the increase in rainfall frequency, and (iii) spatial patterns persist only in the short-term. The study area in the north-western Brazilian state of Rondônia is subject to a climate with a distinct wet and dry season. We collected rain and throughfall on an event basis during the early wet season (n = 14) and peak of the wet season (n = 14) and analyzed the samples for pH and concentrations of , Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻, , and DOC. The coefficient of variation for throughfall based on both sampling intervals was 29%, which is at the lower end of values reported from other tropical forest sites, but which is higher than in most temperate forests. Coefficients of variation of solute deposition ranged from 29% to 52%. This heterogeneity of solute deposition is neither particularly high nor particularly low compared with a range of tropical and temperate forest ecosystems. We observed an increase in solute deposition variability with the progressing wet season, which was explained by a negative correlation between heterogeneity of solute deposition and antecedent dry period. The temporal stability of throughfall patterns was low during the early wet season, but gained in stability as the wet season progressed. We suggest that rapid plant growth at the beginning of the rainy season is responsible for the lower stability, whereas less vegetative activity during the later rainy season might favor the higher persistence of “hot” and “cold” spots of throughfall quantities. The relatively high stability of throughfall patterns during later stages of the wet season may influence processes at the forest floor and in the soil. Solute deposition patterns showed less clear trends but all patterns displayed a short-term stability only. The weak stability of those patterns is apt to impede the formation of solute deposition-induced biochemical microhabitats in the soil.     

Substrate influence and temporal changes on periphytic biomass accrual and metabolism in a tropical humic lagoon

We performed a field experiment in a tropical humic coastal lagoon to evaluate periphyton biomass accrual and metabolism on three different substrates (1) plastic ribbons, (2) green and (3) senescent leaves of the emergent macrophyte Typha domingensis) over 30 days. The contribution of autotrophic biomass decreased as total biomass increased over the time. Mean periphytic ash free dry weight ranged from 0.8 to 5.6 mg cm⁻², but periphyton chlorophyll a concentrations presented shorter amplitudes, which oscillated from 0.12 to 0.44 μg cm⁻² throughout the experiment. Periphyton metabolism was overall heterotrophic on all substrates, especially on senescent leaves. Our data show that substrate type influenced both biomass accrual and periphyton net productivity and respiration rates throughout periphyton development and highlighted the dominance of heterotrophic metabolism. The periphyton respiration may be subsidized by both water- and substrate-derived allochthonous energy pathways, shedding light on the role of periphytic assemblages to the carbon cycling, as a source of CO₂ to the system.     

The Theses on Feuerbach as a political ecology of the possible

This paper argues that Marx's Theses on Feuerbach offer a tremendous and yet neglected resource for work in political ecology and the production of nature. Whilst not calling for a dramatic shift in the way in which such work is conducted, the paper shows how the Theses offer a firm and concise foundation on which to base the ontological and epistemological claims of work on the politicised environment. Ontologically, nature is a differentiated unity, best understood as sensuous activity or practice. This fits well with Smith's claims that nature is produced, whilst not limiting production to capitalist activity. Environments are thereby made up of everyday activity. Subverting the apparent anthropocentrism of this claim, the paper shows how (as Gramsci recognised) the Theses on Feuerbach have an incipient sense of the socio-natural. Post-humanist critiques of Smith's (humanist) production of nature thesis are thereby disrupted. Production realises a differentiated unity of socio-natural relations. Epistemologically, the paper demonstrates how the Theses push political ecologists to construct knowledge claims from practical activity. An ecological politics thereby emerges from the situated knowledges of different actors. Building on this, the paper argues that Marx's 'notes to himself' give us a sense of possible worlds and possible ecologies beyond the topsy-turvy one we have made in the present. Through the concept of praxis evinced in the Theses , a vision of the engaged scholar activist, committed to learning about the world through changing it (and vice-versa), emerges .