Dynamics and mass balance of the 2007 Cima Una rockfall (Eastern Alps, Italy)

On October 12th, 2007 about 40,000 m³ of dolomitic rock detached from the northern wall of the peak known as “Cima Una” (Val Fiscalina, Sesto Dolomites, Bolzano, Italy), and fell 900 m to Fiscalina Valley below. The event generated a dense dust cloud, which traveled up to 4 km from the source area. The failure surface was formed by two near-vertical surfaces, almost perpendicular to each other. The orientation of these surfaces is consistent with two of the main regional tectonic sets. Only a small portion of the fallen material appeared to be preserved as blocks deposited at the base of the rock wall. About a fifth of the fallen mass was deposited on a colluvial cone. The missing mass, estimated to be about 80 %, may be represented by highly fragmented rock in part deposited as sand on the valley floor and in part dispersed as a dense dust cloud generated during the rockfall. There appears to be a deficit of deposited material, which could lead underestimation in the calculation of rock–cliff recession rates. The dynamics of the rockfall, strongly conditioned by the local topography, partially explains the intense rock breakage and the generation of the dust cloud. The rockfall was not caused by an external trigger, such as an earthquake or heavy rainfall; the failure was most likely progressive due to mechanical and physical degradation along highly stressed failure surfaces, possibly promoted by permafrost degradation and freeze and thaw processes.     

A single vs. double spike approach to improve the accuracy of Th measurements in small-volume seawater samples

²³⁴Th is a particle-reactive radionuclide widely used to trace biogeochemical oceanic processes occurring over short timescales. During the last few years, small-volume techniques based on the co-precipitation of ²³⁴Th with MnO₂ coupled with beta-counting have been developed as an alternative to large volume gamma-spectrometric techniques. Here a procedure has been developed to enhance quantitative measurement of ²³⁴Th in MnO₂ precipitates. The main objectives were to obtain a purified Th fraction for beta-counting and to determine the chemical recovery of ²³⁴Th using Th spikes and alpha-spectrometry as an alternative to ICP-MS based methods. Two variations of the procedure are presented. In the first “1 spike” method a ²³⁰Th tracer is added to the sample prior to precipitation of MnO₂, and UTEVA® extraction chromatography is used to obtain a NdF₃(Th) purified source that can be used for both beta-counting of ²³⁴Th and alpha-spectrometry of ²³⁰Th. In the “2 spike” method a ²³⁰Th spike is added and the MnO₂(Th) precipitate is directly beta-counted for ²³⁴Th and subsequently spiked with ²²⁸Th or ²²⁹Th prior to UTEVA® purification and alpha-spectrometry. The results confirm the need to process small-volume seawater samples for ²³⁴Th measurement in presence of a yield tracer, and show that both the 1 spike and 2 spike methods allow an accurate and precise determination of ²³⁴Th (relative percent difference, RPD, between expected and mean measured value < 1%; CV between replicate samples < 3%). Our work also suggests that, although the combined analytical uncertainty on total ²³⁴Th measurements accomplished with both versions of the NdF₃ procedure is promising (6% for 2-L samples), the precision of the ²³⁴Th flux estimation will ultimately depend on the degree of disequilibrium between ²³⁴Th and ²³⁸U.     

A review of present techniques and methodological advances in analyzing Th in aquatic systems

The short-lived thorium isotope ²³⁴Th (half-life 24.1 days) has been used as a tracer for a variety of transport processes in aquatic systems. Its use as a tracer of oceanic export via sinking particles has stimulated a rapidly increasing number of studies that require analyses of ²³⁴Th in both marine and freshwater systems. The original ²³⁴Th method is labor intensive. Thus, there has been a quest for simpler techniques that require smaller sample volumes. Here, we review current methodologies in the collection and analysis of ²³⁴Th from the water column, discuss their individual strengths and weaknesses, and provide an outlook on possible further improvements and future challenges. Also included in this review are recommendations on calibration procedures and the production of standard reference materials as well as a flow chart designed to help researchers find the most appropriate ²³⁴Th analytical technique for a specific aquatic regime and known sampling constraints.     

Cryptic metasomatic agent measured in situ in Variscan mantle rocks: Melt inclusions in garnet of eclogite,Granulitgebirge, Germany

Garnet of eclogite (formerly termed garnet clinopyroxenite) hosted in lenses of orogenic garnet peridotite from the Granulitgebirge, NW Bohemian Massif, contains unique inclusions of granitic melt, now either glassy or crystallized. Analysed glasses and re-homogenized inclusions are hydrous, peraluminous, and enriched in highly incompatible elements characteristic of the continental crust such as Cs, Li, B, Pb, Rb, Th, and U. The original melt thus represents a pristine, chemically evolved metasomatic agent, which infiltrated the mantle via deep continental subduction during the Variscan orogeny. The bulk chemical composition of the studied eclogites is similar to that of Fe-rich basalt and the enrichment in LILE and U suggest a subduction-related component. All these geochemical features confirm metasomatism. In comparison with many other garnet+clinopyroxene-bearing lenses in peridotites of the Bohemian Massif, the studied samples from Rubinberg and Klatschmühle are more akin to eclogite than pyroxenites, as reflected in high jadeite content in clinopyroxene, relatively low Mg, Cr, and Ni but relatively high Ti. However, trace elements of both bulk rock and individual mineral phases show also important differences making these samples rather unique. Metasomatism involving a melt requiring a trace element pattern very similar to the composition reported here has been suggested for the source region of rocks of the so-called durbachite suite, that is, ultrapotassic melanosyenites, which are found throughout the high-grade Variscan basement. Moreover, the Th, U, Pb, Nb, Ta, and Ti patterns of these newly studied melt inclusions (MI) strongly resemble those observed for peridotite and its enclosed pyroxenite from the T-7 borehole (Staré, České Středhoři Mountains) in N Bohemia. This suggests that a similar kind of crustal-derived melt also occurred here. This study of granitic MI in eclogites from peridotites has provided the first direct characterization of a preserved metasomatic melt, possibly responsible for the metasomatism of several parts of the mantle in the Variscides.     

Characteristics of topographic submesoscale eddies off the Crimea coast from high-resolution satellite optical measurements

Ocean Dynamics - Long-term arrays of satellite optical measurements of Landsat-5,7,8 and Sentinel-2 were used to describe the characteristics of submesoscale eddy (SE) dynamics in different parts...     

Multimode surface waveform tomography of the Pacific Ocean: a closer look at the lithospheric cooling signature

We present a regional surface waveform tomography of the Pacific upper mantle, obtained using an automated multimode surface waveform inversion technique on fundamental and higher mode Rayleigh waves, to constrain the   V_SV   structure down to ∼400 km depth. We have improved on previous implementations of this technique by robustly accounting for the effects of uncertainties in earthquake source parameters in the tomographic inversion. We have furthermore improved path coverage in the South Pacific region by including Rayleigh wave observations from the French Polynesian Pacific Lithosphere and Upper Mantle Experiment deployment. This improvement has led to imaging of vertical low-velocity structures associated with hotspots within the South Pacific Super-Swell region. We have produced an age-dependent average cross-section for the Pacific Ocean lithosphere and found that the increase in   V_SV   with age is broadly compatible with a half-space cooling model of oceanic lithosphere formation. We cannot confirm evidence for a Pacific-wide reheating event. Our synthetic tests show that detailed interpretation of average   V_SV   trends across the Pacific Ocean may be misleading unless lateral resolution and amplitude recovery are uniform across the region, a condition that is difficult to achieve in such a large oceanic basin with current seismic stations.     

Cs baseline levels in the Mediterranean and Black Sea: A cross-basin survey of the CIESM Mediterranean Mussel Watch programme

The common mussel Mytilus galloprovincialis was selected as unique biomonitor species to implement a regional monitoring programme, the CIESM Mediterranean Mussel Watch (MMW), in the Mediterranean and Black Seas. As of today, and upon standardization of the methodological approach, the MMW Network has been able to quantify ¹³⁷Cs levels in mussels from 60 coastal stations and to produce the first distribution map of this artificial radionuclide at the scale of the entire Mediterranean and Black Seas. While measured ¹³⁷Cs levels were found to be very low (usually <1 Bq kg⁻¹ wet wt) ¹³⁷Cs activity concentrations in the Black Sea and North Aegean Sea were up to two orders of magnitude higher than those in the western Mediterranean Basin. Such effects, far from representing a threat to human populations or the environment, reflect a persistent signature of the Chernobyl fallout in this area.     

Evaluation of liquefaction potential in an intermountain Quaternary lacustrine basin (Fucino basin,central Italy)

In this study, we analyse the susceptibility to liquefaction of the Pozzone site, which is located on the northern side of the Fucino lacustrine basin in central Italy. In 1915, this region was struck by a M 7.0 earthquake, which produced widespread coseismic surface effects that were interpreted to be liquefaction-related. However, the interpretation of these phenomena at the Pozzone site is not straightforward. Furthermore, the site is characterized by an abundance of fine-grained sediments, which are not typically found in liquefiable soils. Therefore, in this study, we perform a number of detailed stratigraphic and geotechnical investigations (including continuous-coring borehole, CPTu, SDMT, SPT, and geotechnical laboratory tests) to better interpret these 1915 phenomena and to evaluate the liquefaction potential of a lacustrine environment dominated by fine-grained sedimentation. The upper 18.5 m of the stratigraphic succession comprises fine-grained sediments, including four strata of coarser sediments formed by interbedded layers of sand, silty sand and sandy silt. These strata, which are interpreted to represent the frontal lobes of an alluvial fan system within a lacustrine succession, are highly susceptible to liquefaction. We also find evidence of paleo-liquefaction, dated between 12.1–10.8 and 9.43–9.13 kyrs ago, occurring at depths of 2.1–2.3 m. These data, along with the aforementioned geotechnical analyses, indicate that this site would indeed be liquefiable in a 1915-like earthquake. Although we found a broad agreement among CPTu, DMT and shear wave velocity “simplified procedures” in detecting the liquefaction potential of the Pozzone soil, our results suggest that the use and comparison of different in situ techniques are highly recommended for reliable estimates of the cyclic liquefaction resistance in lacustrine sites characterized by high content of fine-grained soils. In geologic environments similar to the one analysed in this work, where it is difficult to detect liquefiable layers, one can identify sites that are susceptible to liquefaction only by using detailed stratigraphic reconstructions, in situ characterization, and laboratory analyses. This has implications for basic (Level 1) seismic microzonation mapping, which typically relies on the use of empirical evaluations based on geologic maps and pre-existing sub-surface data (i.e., age and type of deposits, prevailing grain size, with particular attention paid to clean sands, and depth of the water table).