In situ high-temperature X-ray diffraction and spectroscopic study of fibroferrite,FeOH(SO<Subscript>4</Subscript>)·5H<Subscript>2</Subscript>O

The thermal dehydration process of fibroferrite, FeOH(SO₄)·5H₂O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO₄)·4H₂O, appearing at about 80 °C due to release of one interstitial H₂O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals.     

Hierarchical simulation of aquifer heterogeneity: implications of different simulation settings on solute-transport modeling

The fine-scale heterogeneity of porous media affects the large-scale transport of solutes and contaminants in groundwater and it can be reproduced by means of several geostatistical simulation tools. However, including the available geological information in these tools is often cumbersome. A hierarchical simulation procedure based on a binary tree is proposed and tested on two real-world blocks of alluvial sediments, of a few cubic meters volume, that represent small-scale aquifer analogs. The procedure is implemented using the sequential indicator simulation, but it is so general that it can be adapted to various geostatistical simulation tools, improving their capability to incorporate geological information, i.e., the sedimentological and architectural characterization of heterogeneity. When compared with a standard sequential indicator approach on bi-dimensional simulations, in terms of proportions and connectivity indicators, the proposed procedure yields reliable results, closer to the reference observations. Different ensembles of three-dimensional simulations based on different hierarchical sequences are used to perform numerical experiments of conservative solute transport and to obtain ensembles of equivalent pore velocity and dispersion coefficient at the scale length of the blocks (meter). Their statistics are used to estimate the impact of the variability of the transport properties of the simulated blocks on contaminant transport modeled on bigger domains (hectometer). This is investigated with a one-dimensional transport modeling based on the Kolmogorov-Dmitriev theory of branching stochastic processes. Applying the proposed approach with diverse binary trees and different simulation settings provides a great flexibility, which is revealed by the differences in the breakthrough curves.     

Regional deformation of late Quaternary fluvial sediments in the Apennines foreland basin (Emilia,Italy)

International Journal of Earth Sciences - Our research is aimed at estimating the vertical deformation affecting late Quaternary units accumulated into the foreland basin of the Northern Apennines...     

Deformation patterns of upper Quaternary strata and their relation to active tectonics,Po Basin,Italy

Despite increased application of subsurface datasets below the limits of seismic resolution, reconstructing near‐surface deformation of shallow key stratigraphic markers beneath modern alluvial and coastal plains through sediment core analysis has received little attention. Highly resolved stratigraphy of Upper Pleistocene to Holocene (Marine Isotope Stage 5e to Marine Isotope Stage 1) alluvial, deltaic and coastal depositional systems across the southern Po Plain, down to 150 m depth, provides an unambiguous documentation on the deformation of previously flat‐lying strata that goes back in time beyond the limits of morphological, historical and palaeoseismic records. Five prominent key horizons, accurately selected on the basis of their sedimentological characteristics and typified for their fossil content, were used as highly effective stratigraphic markers (M1 to M5) that can be tracked for tens of kilometres across the basin. A facies‐controlled approach tied to a robust chronology (102 radiocarbon dates) reveals considerable deformation of laterally extensive nearshore (M1), continental (M2 and M3) and lagoon (M4 and M5) marker beds originally deposited in a horizontal position (M1, M4 and M5). The areas where antiformal geometries are best observed are remarkably coincident with the axes of buried ramp anticlines, across which new seismic images reveal substantially warped stratal geometries of Lower Pleistocene strata. The striking spatial coincidence of fold crests with the epicentres of historic and instrumental seismicity suggests that deformation of marker beds M1 to M5 might reflect, in part at least, syntectonically generated relief and, thus, active tectonism. Precise identification and lateral tracing of chronologically constrained stratigraphic markers in the ¹⁴C time window through combined sedimentological and palaeoecological data may delineate late Quaternary subsurface stratigraphic architecture at an unprecedented level of detail, outlining cryptic stratal geometries at the sub‐seismic scale. This approach is highly reproducible in tectonically active Quaternary depositional systems and can help to assess patterns of active deformation in the subsurface of modern alluvial and coastal plains worldwide.     

Ephemeral rollover points and clinothem evolution in the modern Po Delta based on repeated bathymetric surveys

Reconstructions of ancient delta systems rely typically on a two-dimensional (2D) view of prograding clinothems but may miss their three-dimensional (3D) stratigraphic complexity which can, instead, be best documented on modern delta systems by integrating high-resolution geophysical data, historical cartography, core data and geomorphological reconstructions offshore. We quantitatively compare three precisely positioned, high-resolution multi-beam bathymetry maps in the delta front and pro delta sectors (0.3 to 10 m water depth) of Po di Pila, the most active of the modern Po Delta five branches. By investigating the detailed morphology of the prograding modern Po Delta, we shed new light on the mechanisms that control the topset to foreset transition in clinothems and show the temporal and spatial complexity of a delta and its pro delta slope, under the impact of oceanographic processes. This study documents the ephemeral nature of the rollover point at the transition between sandy topset (fluvial, delta plain to mouth-bar) and muddy seaward-dipping foreset deposits advancing, in this case, in >20 m of water depth. Three multibeam surveys, acquired between 2013 and 2016, document the complexity in space and time of the topset and foreset regions and their related morphology, a diagnostic feature that could not be appreciated using solely 2D, even very high-resolution, seismic profiles. In addition, the comparison of bathymetric surveys gathered with one-year lapses shows the migration of subaqueous sand dunes on the clinothem topset, the formation of ephemeral cut-and-fill features at the rollover point (few m below mean sea level), the presence of collapse depressions derived by sagging of sediments and fluid expulsion (possibly induced by storm waves) on the foreset, and splays of sand likely reflecting gravity flows on the lower foreset. Though the modern Po Delta is anthropogenic in many respects, its subaqueous clinothem can be studied as a scale model for ancient clinothems that are less resolved geometrically and far less constrained chronologically.     

New developments with design and construction of a thermal/vacuum qualified photogrammetric system

In the frame of the development of a photogrammetric system to be used in thermal/vacuum chambers at the European Space Research and Technology Centre (ESTEC) of European Space Agency (ESA) and other sites across Europe, the design of a network using micro-cameras was specified by ESA-ESTEC. A thermal/vacuum qualified photogrammetric system, which is able to work and acquire images in vacuum and at cryo-temperatures, was constructed by ESA-ESTEC Test Centre Division. The current system uses four space qualified one-mega pixel cameras and is able to measure large space structures in vacuum and at temperatures down to ?170 ^°C with a global accuracy better than 1 part per 100,000 in object space. Several tests aiming at the qualification of the sensors and system in terms of operation and accuracy have been carried out. Special measures have been developed and special attention has been taken into account specifically for the first application of the photogrammetric system. It is to verify the ESA’s Herschel Telescope Flight Model alignment positioning.