First <Superscript>13</Superscript>C/<Superscript>12</Superscript>C isotopic characterisation of volcanic plume CO<Subscript>2</Subscript>

We describe analytical details and uncertainty evaluation of a simple technique for the measurement of the carbon isotopic composition of CO₂ in volcanic plumes. Data collected at Solfatara and Vulcano, where plumes are fed by fumaroles which are accessible for direct sampling, were first used to validate the technique. For both volcanoes, the plume-derived carbon isotopic compositions are in good agreement with the fumarolic compositions, thus providing confidence on the method, and allowing its application at volcanoes where the volcanic component is inaccessible to direct sampling. As a notable example, we applied the same method to Mount Etna where we derived a δ¹³C of volcanic CO₂ between −0.9 ± 0.27‰ and −1.41 ± 0.27‰ (Bocca Nuova and Voragine craters). The comparison of our measurements to data reported in previous work highlights a temporal trend of systematic increase of δ¹³C values of Etna CO₂ from ~ −4‰, in the 1970’s and the 1980’s, to ~ −1‰ at the present time (2009). This shift toward more positive δ¹³C values matches a concurrent change in magma composition and an increase in the eruption frequency and energy. We discuss such variations in terms of two possible processes: magma carbonate assimilation and carbon isotopic fractionation due to magma degassing along the Etna plumbing system. Finally, our results highlight potential of systematic measurements of the carbon isotopic composition of the CO₂ emitted by volcanic plumes for a better understanding of volcanic processes and for improved surveillance of volcanic activity.     

The DEM or Mt. Etna: geomorphological and structural implications

Abstract

A Digital Elevation Model (DEM) of Mt. Etna is presented; it has altimetric and planimetric resolution of 1 m and 5 m, respectively, and covers an area of about 120 km . This 3-D view of Mt. Etna allowed both recognition and location of the main morphostructural and volcano-tectonic features of the volcano. A slope map has been generated from the DEM; on the basis of slope distributions and surface textures, five acclivity domains have been recognized. The largest domain, south of the summit craters, reflects the occurrence of old plateau lavas, distinct from central volcanoes which built the present Etnean volcanic system. Interaction between the central volcanoes, with their summit calderas and failed slopes, produced the other recognised domains. Furthermore, newly identified relevant morphostructural lines are discussed. © Elsevier, Paris     

Response of antioxidant systems to copper in the gills of the clam Ruditapes decussatus

Copper (Cu) is an essential element for biological systems, however, when present in excess, is toxic. Metallothioneins can play an important role in Cu homeostasis and detoxification. Moreover, Cu can catalyse the production of toxic hydroxyl radicals that cause lipid peroxidation but defence systems in the cells can limit the oxidative damage. The present study was performed to investigate the effect of three Cu concentrations (0.5, 2.5 and 25 microg l(-1)) on the response of antioxidant enzyme activities (superoxide dismutase (SOD), catalase (CAT), selenium-dependent glutathion peroxidase and total glutathion peroxidase), total proteins, metallothioneins (MT), malondialdehyde (MDA) concentrations in the gills of the clam, Ruditapes decussatus. The activity of antioxidant enzymes and total proteins, MT and MDA concentrations were measured in the gills of the clams after 1, 3, 7, 14, 21 and 28 days of Cu exposure. Results indicate that Cu only induces an imbalance in the oxygen metabolism during the first week of Cu exposure due to a decrease in mitochondrial SOD and CAT, selenium-dependent and total glutathion peroxidase activities. Cu also causes lipid peroxidation, measured by the MDA formation, that was Cu dependent. In the gills of clams exposed to 25 microg Cu/l, the excess of Cu triggers the induction of MT synthesis after 3 days of exposure.     

Geological evidence for strong historical earthquakes in an “aseismic” region: The Pollino case (Southern Italy)

The Pollino Range is the southernmost segment of the Southern Apennines at the boundary with the Calabrian Arc. While several strong earthquakes (magnitude 6.5–7.0) have occurred in nearby regions, the Pollino area has no known historical record of seismic events of magnitude > 5. We carried out an aerial photograph interpretation and a field survey of the Pollino fault (the major Quaternary normal fault of the area) in order to characterize geologically the seismic potential of this structure. We dug two sets of trenches across fault scarps within the apecies of latest Pleistocene to Holocene alluvial fans at the Masseria Quercia Marina (MQM) and Grotta Carbone (GC) sites, in the central segment of the southern Pollino Range front. At both sites we identified two surface faulting events affecting the alluvial fan deposits and two overlying colluvial units of historical age. The penultimate event produced a vertical offset of 80–90 cm at GC and 50–60 cm at MQM; while the last event produced a vertical offset of 40–50 cm at GC and few centimeters of offset at MQM. Detailed geomorphological field observations suggest that the two historical earthquakes reactivated the entire length of the Masseria Marzano-Civita segment of the Pollino fault (rupture length about 18 km). For events in this range of rupture length and vertical displacement, comparison with surface faulting earthquakes in the Apennines (and abroad) indicates a magnitude of 6.5–7.0. Therefore, the maximum potential earthquake and the seismic hazard of the Pollino area are significantly larger than that suggested by the available historical seismic catalogue.     

Supercontinent evolution and the Proterozoic metallogeny of South America

The cratonic blocks of South America have been accreted from 2.2 to 1.9 Ga, and all of these blocks have been previously involved in the assembly and breakup of the Paleoproterozoic Atlantica, the Mesoproterozoic to Neoproterozoic Rodinia, and the Neoproterozoic to Phanerozoic West Gondwana continents. Several mineralization phases have sequentially taken place during Atlantica evolution, involving Au, U, Cr, W, and Sn. During Rodinia assembly and breakup and Gondwana formation, the crust-dominated metallogenic processes have been overriding, responsible for several mineral deposits, including Au, Pd, Sn, Ni, Cu, Zn, Mn, Fe, Pb, U, P₂O₅, Ta, W, Li, Be and precious stones. During Rodinia breakup, epicontinental carbonate-siliciclastic basins were deposited, which host important non-ferrous base metal deposits of Cu–Co and Pb–Zn–Ag in Africa and South America. Isotope Pb–Pb analyses of sulfides from the non-ferrous deposits unambiguously indicate an upper crustal source for the metals. A genetic model for these deposits involves extensional faults driving the circulation of hydrothermal mineralizing fluids from the Archean/Paleoproterozoic basement to the Neoproterozoic sedimentary cover. These relations demonstrate the individuality of metal associations of every sediment-hosted Neoproterozoic base-metal deposit of West Gondwana has been highly influenced by the mineralogical and chemical composition of the underlying igneous and metaigneous rocks.     

Multiple cosmogenic nuclides document complex Pleistocene exposure history of glacial drifts in Terra Nova Bay (northern Victoria Land, Antarctica)

Geomorphological and glacial geological surveys and multiple cosmogenic nuclide analyses (¹⁰Be, ²⁶Al, and ²¹Ne) allowed us to reconstruct the chronology of variations prior to the last glacial maximum of the East Antarctic Ice Sheet (EAIS) and valley glaciers in the Terra Nova Bay region. Glacially scoured coastal piedmonts with round-topped mountains occur below the highest local erosional trimline. They represent relict landscape features eroded by extensive ice overriding the whole coastal area before at least 6 Ma (pre-dating the build-up of the Mt. Melbourne volcanic field). Since then, summit surfaces were continuously exposed and well preserved under polar condition with negligible erosion rates on the order of 17 cm/Ma. Complex older drifts rest on deglaciated areas above the younger late-Pleistocene glacial drift and below the previously overridden summits. The combination of stable and radionuclide isotopes documents complex exposure histories with substantial periods of burial combined with minimal erosion. The areas below rounded summits were repeatedly exposed and buried by ice from local and outlet glaciers. The exposure ages of the older drift(s) indicate multiple Pleistocene glacial cycles, which did not significantly modify the pre-existing landscape.     

Social acceptability of marine aquaculture: The use of survey-based methods for eliciting public and stakeholder preferences

The social acceptability of aquaculture is linked to its perceived environmental impact, and this clearly poses a challenge to policy makers in deciding what weight to attach to such a concern within a governance framework for the industry. Using salmon farming in Scotland as a case study, we have developed a survey-based approach to evaluating public and stakeholder attitudes towards the environmental performance of aquaculture. The survey of the general public finds marked regional variations in attitudes towards salmon farming, while the results of the stakeholder survey raise issues over how far the preferences of particular interest groups are truly representative of the community as a whole.     

CO2 abatement goals for international shipping

The Paris Agreement, which entered into force in 2016, sets the ambitious climate change mitigation goal of limiting the global temperature increase to below 2°C and ideally 1.5°C. This puts a severe constraint on the remaining global GHG emissions budget. While international shipping is also a contributor to anthropogenic GHG emissions, and CO₂ in particular, it is not included in the Paris Agreement. This article discusses how a share of a global CO₂ budget over the twenty-first century could be apportioned to international shipping, and, using a range of future trade scenarios, explores the requisite cuts to the CO₂ intensity of shipping. The results demonstrate that, under a wide range of assumptions, existing short-term levers of efficiency must be urgently exploited to achieve mitigation commensurate with that required from the rest of the economy, with virtually full decarbonization of international shipping required as early as before mid-century.

Key policy insights

• Regulatory action is key to ensuring the international shipping sector’s long-term sustainability.

• For the shipping industry to deliver mitigation in line with the Paris Agreement, virtually full decarbonization needs to be achieved.

• In the near term, immediate and rapid exploitation of available mitigation measures is of critical importance.

• Any delay in the transition will increase the risk of stranded assets, or diminish the chances of meeting the Paris Agreement's temperature commitments.